CHEMISTRY: AN INTRODUCTION TO GENERAL, O
CHEMISTRY: AN INTRODUCTION TO GENERAL, O
13th Edition
ISBN: 9780137444298
Author: Timberlake
Publisher: PEARSON
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Chapter 13, Problem 13.76CP
Interpretation Introduction

To determine:

Haworth structure for trehalose.

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5. Use the MS data to answer the questions on the next page. 14.0 1.4 15.0 8.1 100- MS-IW-5644 26.0 2.8 27.0 6.7 28.0 1.8 29.0 80 4.4 38.0 1.0 39.0 1.5 41.0 1.2 42.0 11.2 43.0 100.0 44.0 4.3 79.0 1.9 80.0 2.6 Relative Intensity 40 81.0 1.9 82.0 2.5 93.0 8.7 20- 95.0 8.2 121.0 2.0 123.0 2.0 136.0 11.8 0 138.0 11.5 20 40 8. 60 a. Br - 0 80 100 120 140 160 180 200 220 m/z Identify the m/z of the base peak and molecular ion. 2 b. Draw structures for each of the following fragments (include electrons and charges): 43.0, 93.0, 95.0, 136.0, and 138.0 m/z. C. Draw a reasonable a-fragmentation mechanism for the fragmentation of the molecular ion to fragment 43.0 m/z. Be sure to include all electrons and formal charges. 6. Using the values provided in Appendix E of your lab manual, calculate the monoisotopic mass for the pyridinium ion (CsH6N) and show your work.
None
Stereochemistry: Three possible answers- diastereomers, enantiomers OH CH₂OH I -c=0 21108 1101 41745 HOR CH₂OH IL Но CH₂OH TIL a. Compounds I and III have this relationship with each other: enantiomers b. Compounds II and IV have this relationship with each other: c. Compounds I and II have this relationship with each other: d. *Draw one structure that is a stereoisomer of II, but neither a diastereomer nor an enantiomer. (more than one correct answer)

Chapter 13 Solutions

CHEMISTRY: AN INTRODUCTION TO GENERAL, O

Ch. 13.2 - Prob. 13.11PPCh. 13.2 - Prob. 13.12PPCh. 13.2 - Prob. 13.13PPCh. 13.2 - Prob. 13.14PPCh. 13.2 - Prob. 13.15PPCh. 13.2 - Prob. 13.16PPCh. 13.2 - Identify each of the following as D or L: a. b. c.Ch. 13.2 - Identify each of the following as D or L: a. b. c.Ch. 13.2 - Identify the chiral carbon in each of the...Ch. 13.2 - Prob. 13.20PPCh. 13.3 - Prob. 13.21PPCh. 13.3 - Prob. 13.22PPCh. 13.3 - Prob. 13.23PPCh. 13.3 - Prob. 13.24PPCh. 13.3 - Prob. 13.25PPCh. 13.3 - Prob. 13.26PPCh. 13.3 - Prob. 13.27PPCh. 13.3 - Prob. 13.28PPCh. 13.3 - Prob. 13.29PPCh. 13.3 - Prob. 13.30PPCh. 13.4 - What are the kind and number of atoms in the ring...Ch. 13.4 - What are the kind and number of atoms in the ring...Ch. 13.4 - Prob. 13.33PPCh. 13.4 - Prob. 13.34PPCh. 13.4 - Prob. 13.35PPCh. 13.4 - Identify each of the following as the a or ß...Ch. 13.5 - Prob. 13.37PPCh. 13.5 - Prob. 13.38PPCh. 13.5 - Prob. 13.39PPCh. 13.5 - Prob. 13.40PPCh. 13.6 - Prob. 13.41PPCh. 13.6 - Prob. 13.42PPCh. 13.6 - Prob. 13.43PPCh. 13.6 - Prob. 13.44PPCh. 13.6 - Prob. 13.45PPCh. 13.6 - Prob. 13.46PPCh. 13.7 - Describe the similarities and differences in the...Ch. 13.7 - Prob. 13.48PPCh. 13.7 - Prob. 13.49PPCh. 13.7 - Prob. 13.50PPCh. 13.7 - Prob. 13.51PPCh. 13.7 - Prob. 13.52PPCh. 13.7 - Prob. 13.53PPCh. 13.7 - Prob. 13.54PPCh. 13 - Prob. 13.55UTCCh. 13 - Prob. 13.56UTCCh. 13 - Prob. 13.57UTCCh. 13 - Prob. 13.58UTCCh. 13 - Prob. 13.59UTCCh. 13 - Prob. 13.60UTCCh. 13 - Prob. 13.61APPCh. 13 - Prob. 13.62APPCh. 13 - Prob. 13.63APPCh. 13 - Prob. 13.64APPCh. 13 - Prob. 13.65APPCh. 13 - Prob. 13.66APPCh. 13 - Prob. 13.67APPCh. 13 - Prob. 13.68APPCh. 13 - Prob. 13.69APPCh. 13 - Prob. 13.70APPCh. 13 - Prob. 13.71APPCh. 13 - Prob. 13.72APPCh. 13 - Prob. 13.73APPCh. 13 - Prob. 13.74APPCh. 13 - Prob. 13.75CPCh. 13 - Prob. 13.76CPCh. 13 - 13.77 Gentiobiose is found in saffron. (13.4,...Ch. 13 - Prob. 13.78CP
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