General, Organic, And Biological Chemistry, Hybrid (with Owlv2 Quick Prep For General Chemistry Printed Access Card)
General, Organic, And Biological Chemistry, Hybrid (with Owlv2 Quick Prep For General Chemistry Printed Access Card)
7th Edition
ISBN: 9781305253070
Author: STOKER, H. Stephen
Publisher: Cengage Learning
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Chapter 13, Problem 13.74EP

(a)

Interpretation Introduction

Interpretation:

Whether hydration of 2-butene will give one or two products has to be identified based on Markovnikov’s rule.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

General, Organic, And Biological Chemistry, Hybrid (with Owlv2 Quick Prep For General Chemistry Printed Access Card), Chapter 13, Problem 13.74EP , additional homework tip  1

Addition reactions can be classified broadly into two types. They are asymmetrical addition reaction and symmetrical addition reaction.

Symmetrical addition reactions is the one in which the same atom or same group of atoms are added across the carbon‑carbon multiple bonds.

Unsymmetrical addition reactions is the one in which the different atom or different group of atoms are added across the carbon‑carbon multiple bonds.

Markovnikov’s rule:

When an unsymmetrical molecule of formula HQ to an unsymmeterical alkene, the hydrogen atom from HQ gets attached to the unsaturated carbon atom which has the most hydrogen atoms. In other words, it can be said that the hydrogen atom gets attached to the unsaturated carbon atom that is least substituted.

(b)

Interpretation Introduction

Interpretation:

Whether hydration of 2-pentene will give one or two products has to be identified based on Markovnikov’s rule.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

General, Organic, And Biological Chemistry, Hybrid (with Owlv2 Quick Prep For General Chemistry Printed Access Card), Chapter 13, Problem 13.74EP , additional homework tip  2

Addition reactions can be classified broadly into two types. They are asymmetrical addition reaction and symmetrical addition reaction.

Symmetrical addition reactions is the one in which the same atom or same group of atoms are added across the carbon‑carbon multiple bonds.

Unsymmetrical addition reactions is the one in which the different atom or different group of atoms are added across the carbon‑carbon multiple bonds.

Markovnikov’s rule:

When an unsymmetrical molecule of formula HQ to an unsymmeterical alkene, the hydrogen atom from HQ gets attached to the unsaturated carbon atom which has the most hydrogen atoms. In other words, it can be said that the hydrogen atom gets attached to the unsaturated carbon atom that is least substituted.

(c)

Interpretation Introduction

Interpretation:

Whether hydration of cyclobutene will give one or two products has to be identified based on Markovnikov’s rule.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

General, Organic, And Biological Chemistry, Hybrid (with Owlv2 Quick Prep For General Chemistry Printed Access Card), Chapter 13, Problem 13.74EP , additional homework tip  3

Addition reactions can be classified broadly into two types. They are asymmetrical addition reaction and symmetrical addition reaction.

Symmetrical addition reactions is the one in which the same atom or same group of atoms are added across the carbon‑carbon multiple bonds.

Unsymmetrical addition reactions is the one in which the different atom or different group of atoms are added across the carbon‑carbon multiple bonds.

Markovnikov’s rule:

When an unsymmetrical molecule of formula HQ to an unsymmeterical alkene, the hydrogen atom from HQ gets attached to the unsaturated carbon atom which has the most hydrogen atoms. In other words, it can be said that the hydrogen atom gets attached to the unsaturated carbon atom that is least substituted.

(d)

Interpretation Introduction

Interpretation:

Whether hydration of cyclohexene will give one or two products has to be identified based on Markovnikov’s rule.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

General, Organic, And Biological Chemistry, Hybrid (with Owlv2 Quick Prep For General Chemistry Printed Access Card), Chapter 13, Problem 13.74EP , additional homework tip  4

Addition reactions can be classified broadly into two types. They are asymmetrical addition reaction and symmetrical addition reaction.

Symmetrical addition reactions is the one in which the same atom or same group of atoms are added across the carbon‑carbon multiple bonds.

Unsymmetrical addition reactions is the one in which the different atom or different group of atoms are added across the carbon‑carbon multiple bonds.

Markovnikov’s rule:

When an unsymmetrical molecule of formula HQ to an unsymmeterical alkene, the hydrogen atom from HQ gets attached to the unsaturated carbon atom which has the most hydrogen atoms. In other words, it can be said that the hydrogen atom gets attached to the unsaturated carbon atom that is least substituted.

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In the video, we looked at the absorbance of a certain substance and how it varies depending on what wavelength of light we are looking at. Below is a similar scan of a different substance. What color BEST describes how this substance will appear? Absorbance (AU) Violet Blue Green Orange 1.2 1.0- 0.8- 0.6- 0.4- 0.2 0.0 450 500 550 600 650 700 Wavelength (nm) violet indigo blue green yellow orange red Red O Cannot tell from this information In the above graph, what causes -450 nm wavelength of light to have a higher absorbance than light with a -550 nm wavelength? Check all that are true. The distance the light travels is different The different data points are for different substances The concentration is different at different times in the experiment Epsilon (molar absortivity) is different at different wavelengths

Chapter 13 Solutions

General, Organic, And Biological Chemistry, Hybrid (with Owlv2 Quick Prep For General Chemistry Printed Access Card)

Ch. 13.3 - Prob. 4QQCh. 13.4 - Prob. 1QQCh. 13.4 - Prob. 2QQCh. 13.5 - Prob. 1QQCh. 13.5 - Prob. 2QQCh. 13.5 - Prob. 3QQCh. 13.6 - Prob. 1QQCh. 13.6 - Prob. 2QQCh. 13.6 - Prob. 3QQCh. 13.7 - Prob. 1QQCh. 13.7 - Prob. 2QQCh. 13.7 - Prob. 3QQCh. 13.8 - Prob. 1QQCh. 13.8 - Prob. 2QQCh. 13.9 - Prob. 1QQCh. 13.9 - Prob. 2QQCh. 13.10 - Prob. 1QQCh. 13.10 - Prob. 2QQCh. 13.10 - Prob. 3QQCh. 13.10 - Prob. 4QQCh. 13.10 - Prob. 5QQCh. 13.11 - Prob. 1QQCh. 13.11 - Prob. 2QQCh. 13.11 - Prob. 3QQCh. 13.11 - Prob. 4QQCh. 13.11 - Prob. 5QQCh. 13.12 - Prob. 1QQCh. 13.12 - Prob. 2QQCh. 13.12 - Prob. 3QQCh. 13.12 - Prob. 4QQCh. 13.12 - Prob. 5QQCh. 13.13 - Prob. 1QQCh. 13.13 - Prob. 2QQCh. 13.13 - Prob. 3QQCh. 13.14 - Prob. 1QQCh. 13.14 - Prob. 2QQCh. 13.14 - Prob. 3QQCh. 13.14 - Prob. 4QQCh. 13.15 - Prob. 1QQCh. 13.15 - Prob. 2QQCh. 13.15 - Prob. 3QQCh. 13.15 - Prob. 4QQCh. 13.16 - Prob. 1QQCh. 13.16 - Prob. 2QQCh. 13 - Classify each of the following hydrocarbons as...Ch. 13 - Classify each of the following hydrocarbons as...Ch. 13 - Prob. 13.3EPCh. 13 - Prob. 13.4EPCh. 13 - Prob. 13.5EPCh. 13 - Prob. 13.6EPCh. 13 - Prob. 13.7EPCh. 13 - Prob. 13.8EPCh. 13 - Prob. 13.9EPCh. 13 - What is the molecular formula for each of the...Ch. 13 - Prob. 13.11EPCh. 13 - Prob. 13.12EPCh. 13 - What is wrong, if anything, with the following...Ch. 13 - Prob. 13.14EPCh. 13 - Prob. 13.15EPCh. 13 - Prob. 13.16EPCh. 13 - Prob. 13.17EPCh. 13 - Prob. 13.18EPCh. 13 - Draw a condensed structural formula for each of...Ch. 13 - Draw a condensed structural formula for each of...Ch. 13 - The following names are incorrect by IUPAC rules....Ch. 13 - The following names are incorrect by IUPAC rules....Ch. 13 - Prob. 13.23EPCh. 13 - Prob. 13.24EPCh. 13 - Prob. 13.25EPCh. 13 - Classify each of the following compounds as...Ch. 13 - Prob. 13.27EPCh. 13 - How many hydrogen atoms are present in a molecule...Ch. 13 - Prob. 13.29EPCh. 13 - Draw a line-angle structural formula for each of...Ch. 13 - Prob. 13.31EPCh. 13 - Prob. 13.32EPCh. 13 - Prob. 13.33EPCh. 13 - Prob. 13.34EPCh. 13 - Prob. 13.35EPCh. 13 - Prob. 13.36EPCh. 13 - Prob. 13.37EPCh. 13 - Prob. 13.38EPCh. 13 - For each of the following pairs of alkenes,...Ch. 13 - Prob. 13.40EPCh. 13 - Prob. 13.41EPCh. 13 - Prob. 13.42EPCh. 13 - Prob. 13.43EPCh. 13 - Prob. 13.44EPCh. 13 - Prob. 13.45EPCh. 13 - Prob. 13.46EPCh. 13 - For each molecule, indicate whether cistrans...Ch. 13 - For each molecule, indicate whether cistrans...Ch. 13 - Prob. 13.49EPCh. 13 - Prob. 13.50EPCh. 13 - Prob. 13.51EPCh. 13 - Draw a structural formula for each of the...Ch. 13 - Prob. 13.53EPCh. 13 - Prob. 13.54EPCh. 13 - Prob. 13.55EPCh. 13 - Prob. 13.56EPCh. 13 - Prob. 13.57EPCh. 13 - Prob. 13.58EPCh. 13 - Why is the number of carbon atoms in a terpene...Ch. 13 - How many isoprene units are present in a....Ch. 13 - Prob. 13.61EPCh. 13 - Indicate whether each of the following statements...Ch. 13 - Prob. 13.63EPCh. 13 - With the help of Figure 13-7, indicate whether...Ch. 13 - Prob. 13.65EPCh. 13 - Prob. 13.66EPCh. 13 - Prob. 13.67EPCh. 13 - Prob. 13.68EPCh. 13 - Prob. 13.69EPCh. 13 - Prob. 13.70EPCh. 13 - Prob. 13.71EPCh. 13 - Prob. 13.72EPCh. 13 - Prob. 13.73EPCh. 13 - Prob. 13.74EPCh. 13 - Prob. 13.75EPCh. 13 - Write a chemical equation showing reactants,...Ch. 13 - Supply the structural formula of the product in...Ch. 13 - Prob. 13.78EPCh. 13 - What reactant would you use to prepare each of the...Ch. 13 - Prob. 13.80EPCh. 13 - Prob. 13.81EPCh. 13 - Prob. 13.82EPCh. 13 - Prob. 13.83EPCh. 13 - Prob. 13.84EPCh. 13 - Prob. 13.85EPCh. 13 - Prob. 13.86EPCh. 13 - Prob. 13.87EPCh. 13 - Prob. 13.88EPCh. 13 - Prob. 13.89EPCh. 13 - Prob. 13.90EPCh. 13 - Prob. 13.91EPCh. 13 - Prob. 13.92EPCh. 13 - Prob. 13.93EPCh. 13 - What are the bond angles about the triple bond in...Ch. 13 - Prob. 13.95EPCh. 13 - Prob. 13.96EPCh. 13 - Prob. 13.97EPCh. 13 - Prob. 13.98EPCh. 13 - Prob. 13.99EPCh. 13 - Prob. 13.100EPCh. 13 - Prob. 13.101EPCh. 13 - Prob. 13.102EPCh. 13 - Prob. 13.103EPCh. 13 - Prob. 13.104EPCh. 13 - Prob. 13.105EPCh. 13 - Prob. 13.106EPCh. 13 - Prob. 13.107EPCh. 13 - Prob. 13.108EPCh. 13 - Assign each of the compounds in Problem 13-107 an...Ch. 13 - Assign each of the compounds in Problem 13-108 an...Ch. 13 - Prob. 13.111EPCh. 13 - Prob. 13.112EPCh. 13 - Prob. 13.113EPCh. 13 - Prob. 13.114EPCh. 13 - Prob. 13.115EPCh. 13 - Write a structural formula for each of the...Ch. 13 - Eight isomeric substituted benzenes have the...Ch. 13 - Prob. 13.118EPCh. 13 - Prob. 13.119EPCh. 13 - Prob. 13.120EPCh. 13 - Prob. 13.121EPCh. 13 - Prob. 13.122EPCh. 13 - Prob. 13.123EPCh. 13 - Prob. 13.124EPCh. 13 - Prob. 13.125EPCh. 13 - For each of the following classes of compounds,...Ch. 13 - Prob. 13.127EPCh. 13 - Prob. 13.128EPCh. 13 - Prob. 13.129EPCh. 13 - Prob. 13.130EP
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