
Interpretation: The expected boiling point and freezing point of sugar solution are to be calculated, the deviation of boiling point of syrup and boiling point of pure water is to be explained and also the freezing of syrup at
Concept Introduction: Colligative properties of a solution depend upon the amount of solute present in the solution irrespective of its nature.
They are of 4 types, freezing point depression, boiling point elevation, lowering of vapor pressure and osmotic pressure.
On addition of a non-volatile solute, the physical properties of a pure solvent get altered and extends the temperature range over which it can remain a liquid.
The molality of any solution can be given as:
The freezing point depression of a solution is given by the expression:

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Chapter 13 Solutions
Pearson eText -- Introductory Chemistry -- Instant Access (Pearson+)
- Predict major product(s) for the following reactions. Note the mechanism(s) of the reactions (SN1, E1, SN2 or E2).arrow_forwardQ3: Rank the following compounds in increasing reactivity of E1 and E2 eliminations, respectively. Br ca. go do A CI CI B C CI Darrow_forwardQ5: Predict major product(s) for the following reactions. Note the mechanism(s) of the reactions (SN1, E1, SN2 or E2). H₂O דיי "Br KN3 CH3CH2OH NaNH2 NH3 Page 3 of 6 Chem 0310 Organic Chemistry 1 HW Problem Sets CI Br excess NaOCH 3 CH3OH Br KOC(CH3)3 DuckDuckGarrow_forward
- Q4: Circle the substrate that gives a single alkene product in a E2 elimination. CI CI Br Brarrow_forwardPlease calculate the chemical shift of each protonsarrow_forwardQ1: Answer the questions for the reaction below: ..!! Br OH a) Predict the product(s) of the reaction. b) Is the substrate optically active? Are the product(s) optically active as a mix? c) Draw the curved arrow mechanism for the reaction. d) What happens to the SN1 reaction rate in each of these instances: 1. Change the substrate to Br 'CI 2. Change the substrate to 3. Change the solvent from 100% CH3CH2OH to 10% CH3CH2OH + 90% DMF 4. Increase the substrate concentration by 3-fold.arrow_forward
- Q6: Provide the reagents and conditions for the following reactions to make the product with a good yield. Br Br CI она CIarrow_forwardQ2: We would not expect the following primary alkyl halide to go through an SN1 reaction. However, it can go through an SN1 mechanism. Explain why. Hint: Think about what happens when the leaving group leaves. CI NaO EtOH H བྱིས་ Harrow_forwardI performed this experiment, but I'm so confused. How do I find the first two blank columns using the data provided. What is the [I^-] mol/L and [S2O8^-2] mol/L. How do I find this? Please help!arrow_forward
- Example 3 A molecule is achiral if it has a plane of symmetry in any conformation. The given conformation of 2,3-dibromobutane below does not have a plane of symmetry. Will rotation around the C2-C3 bond form a conformation with a plane of symmetry? Draw the conformation to find out. DIY: Do the same for: H3C Brill rotate H CH3 OH HO Brarrow_forward120 100 20 20 bound drug/free drug (%) 60 40 60 80 80 0 0 Scatchard Plot of Drug Binding 20 20 40 60 80 100 120 bound drug (nM)arrow_forwardUsing diethylmalonate and benzyl bromide as your only as your only source of carbon, propose a synthesis for the following compound.arrow_forward
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