(a) Interpretation: To design a synthesis successfully, you must become very familiar with a variety of reactions. Therefore, take the time now to assess how familiar you are with the reactions we have learned so far, which appear in the reaction tables at the ends of Chapters 9–12. Go through the tables first to see if you can determine the typical reagents and reaction conditions for each reaction by examining just the reactants and products. Concept introduction: The reaction conditions are written after the reagent for each numbered step. The reaction conditions are typically separated from the reactant or reagent by either a comma or a slash.

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Answer 1

Question

Chapter 13, Problem 13.5YT

Interpretation Introduction

(a)

Interpretation:

To design a synthesis successfully, you must become very familiar with a variety of reactions. Therefore, take the time now to assess how familiar you are with the reactions we have learned so far, which appear in the reaction tables at the ends of Chapters 9–12. Go through the tables first to see if you can determine the typical reagents and reaction conditions for each reaction by examining just the reactants and products.

Concept introduction:

The reaction conditions are written after the reagent for each numbered step. The reaction conditions are typically separated from the reactant or reagent by either a comma or a slash.

Interpretation Introduction

(b)

Interpretation:

To design a synthesis successfully, you must become very familiar with a variety of reactions. Therefore, take the time now to assess how familiar you are with the reactions we have learned so far, which appear in the reaction tables at the ends of Chapters 9–12. Go through the reaction tables again to see if you can determine the reactants for each reaction by examining just the products and the typical reagents and reaction conditions.

Concept introduction:

The reaction conditions are written after the reagent for each numbered step. The reaction conditions are typically separated from the reactant or reagent by either a comma or a slash.

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What are the IUPAC Names of all the compounds in the picture?

1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)

19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+

Answer 2

Question

Chapter 13, Problem 13.5YT

Interpretation Introduction

(a)

Interpretation:

To design a synthesis successfully, you must become very familiar with a variety of reactions. Therefore, take the time now to assess how familiar you are with the reactions we have learned so far, which appear in the reaction tables at the ends of Chapters 9–12. Go through the tables first to see if you can determine the typical reagents and reaction conditions for each reaction by examining just the reactants and products.

Concept introduction:

The reaction conditions are written after the reagent for each numbered step. The reaction conditions are typically separated from the reactant or reagent by either a comma or a slash.

Interpretation Introduction

(b)

Interpretation:

To design a synthesis successfully, you must become very familiar with a variety of reactions. Therefore, take the time now to assess how familiar you are with the reactions we have learned so far, which appear in the reaction tables at the ends of Chapters 9–12. Go through the reaction tables again to see if you can determine the reactants for each reaction by examining just the products and the typical reagents and reaction conditions.

Concept introduction:

The reaction conditions are written after the reagent for each numbered step. The reaction conditions are typically separated from the reactant or reagent by either a comma or a slash.

Expert Solution & Answer

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Answer 3

Question

Chapter 13, Problem 13.5YT

Interpretation Introduction

(a)

Interpretation:

To design a synthesis successfully, you must become very familiar with a variety of reactions. Therefore, take the time now to assess how familiar you are with the reactions we have learned so far, which appear in the reaction tables at the ends of Chapters 9–12. Go through the tables first to see if you can determine the typical reagents and reaction conditions for each reaction by examining just the reactants and products.

Concept introduction:

The reaction conditions are written after the reagent for each numbered step. The reaction conditions are typically separated from the reactant or reagent by either a comma or a slash.

Interpretation Introduction

(b)

Interpretation:

To design a synthesis successfully, you must become very familiar with a variety of reactions. Therefore, take the time now to assess how familiar you are with the reactions we have learned so far, which appear in the reaction tables at the ends of Chapters 9–12. Go through the reaction tables again to see if you can determine the reactants for each reaction by examining just the products and the typical reagents and reaction conditions.

Concept introduction:

The reaction conditions are written after the reagent for each numbered step. The reaction conditions are typically separated from the reactant or reagent by either a comma or a slash.

Expert Solution & Answer

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Answer 4

Question

Chapter 13, Problem 13.5YT

Interpretation Introduction

(a)

Interpretation:

To design a synthesis successfully, you must become very familiar with a variety of reactions. Therefore, take the time now to assess how familiar you are with the reactions we have learned so far, which appear in the reaction tables at the ends of Chapters 9–12. Go through the tables first to see if you can determine the typical reagents and reaction conditions for each reaction by examining just the reactants and products.

Concept introduction:

The reaction conditions are written after the reagent for each numbered step. The reaction conditions are typically separated from the reactant or reagent by either a comma or a slash.

Interpretation Introduction

(b)

Interpretation:

To design a synthesis successfully, you must become very familiar with a variety of reactions. Therefore, take the time now to assess how familiar you are with the reactions we have learned so far, which appear in the reaction tables at the ends of Chapters 9–12. Go through the reaction tables again to see if you can determine the reactants for each reaction by examining just the products and the typical reagents and reaction conditions.

Concept introduction:

The reaction conditions are written after the reagent for each numbered step. The reaction conditions are typically separated from the reactant or reagent by either a comma or a slash.

Expert Solution & Answer

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Answer 5

Chapter 13, Problem 13.5YT

Interpretation Introduction

(a)

Interpretation:

To design a synthesis successfully, you must become very familiar with a variety of reactions. Therefore, take the time now to assess how familiar you are with the reactions we have learned so far, which appear in the reaction tables at the ends of Chapters 9–12. Go through the tables first to see if you can determine the typical reagents and reaction conditions for each reaction by examining just the reactants and products.

Concept introduction:

The reaction conditions are written after the reagent for each numbered step. The reaction conditions are typically separated from the reactant or reagent by either a comma or a slash.

Interpretation Introduction

(b)

Interpretation:

To design a synthesis successfully, you must become very familiar with a variety of reactions. Therefore, take the time now to assess how familiar you are with the reactions we have learned so far, which appear in the reaction tables at the ends of Chapters 9–12. Go through the reaction tables again to see if you can determine the reactants for each reaction by examining just the products and the typical reagents and reaction conditions.

Concept introduction:

The reaction conditions are written after the reagent for each numbered step. The reaction conditions are typically separated from the reactant or reagent by either a comma or a slash.

Answer 6

Chapter 13, Problem 13.5YT

Interpretation Introduction

(a)

Interpretation:

To design a synthesis successfully, you must become very familiar with a variety of reactions. Therefore, take the time now to assess how familiar you are with the reactions we have learned so far, which appear in the reaction tables at the ends of Chapters 9–12. Go through the tables first to see if you can determine the typical reagents and reaction conditions for each reaction by examining just the reactants and products.

Concept introduction:

The reaction conditions are written after the reagent for each numbered step. The reaction conditions are typically separated from the reactant or reagent by either a comma or a slash.

Answer 7

Chapter 13, Problem 13.5YT

Interpretation Introduction

(a)

Interpretation:

To design a synthesis successfully, you must become very familiar with a variety of reactions. Therefore, take the time now to assess how familiar you are with the reactions we have learned so far, which appear in the reaction tables at the ends of Chapters 9–12. Go through the tables first to see if you can determine the typical reagents and reaction conditions for each reaction by examining just the reactants and products.

Concept introduction:

The reaction conditions are written after the reagent for each numbered step. The reaction conditions are typically separated from the reactant or reagent by either a comma or a slash.

Answer 8

Interpretation Introduction

(b)

Interpretation:

To design a synthesis successfully, you must become very familiar with a variety of reactions. Therefore, take the time now to assess how familiar you are with the reactions we have learned so far, which appear in the reaction tables at the ends of Chapters 9–12. Go through the reaction tables again to see if you can determine the reactants for each reaction by examining just the products and the typical reagents and reaction conditions.

Concept introduction:

The reaction conditions are written after the reagent for each numbered step. The reaction conditions are typically separated from the reactant or reagent by either a comma or a slash.

Answer 9

Interpretation Introduction

(b)

Interpretation:

To design a synthesis successfully, you must become very familiar with a variety of reactions. Therefore, take the time now to assess how familiar you are with the reactions we have learned so far, which appear in the reaction tables at the ends of Chapters 9–12. Go through the reaction tables again to see if you can determine the reactants for each reaction by examining just the products and the typical reagents and reaction conditions.

Concept introduction:

The reaction conditions are written after the reagent for each numbered step. The reaction conditions are typically separated from the reactant or reagent by either a comma or a slash.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 13 - Prob. 13.1P Ch. 13 - Prob. 13.2P Ch. 13 - Prob. 13.3P Ch. 13 - Prob. 13.4P Ch. 13 - Prob. 13.5P Ch. 13 - Prob. 13.6P Ch. 13 - Prob. 13.7P Ch. 13 - Prob. 13.8P Ch. 13 - Prob. 13.9P Ch. 13 - Prob. 13.10P

Solution Summary: The author explains how to determine the typical reagents and reaction conditions for each reaction by examining just the reactants and products.

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Chapter 13 Solutions