General Chemistry
7th Edition
ISBN: 9780073402758
Author: Chang, Raymond/ Goldsby
Publisher: McGraw-Hill College
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Chapter 13, Problem 13.4QP
Interpretation Introduction
Interpretation:
The endothermic and exothermic solution processes should be differentiated by providing molecular interpretation.
Concept introduction
Solvation detailed that interaction between solvent and ion or molecules present in the solution. In some cases the interaction between ion or molecule and solvent would be strong and nature of this interaction predominant many properties such as solubility, reactivity and colour, etc.
The solvation process is endothermic when more energy is released than the energy used to making or breaking the bond between solvent and solute.
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Solution
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Use retrosynthetic analysis to suggest two paths to synthesize 2-methyl-3-hexanol using the Grignard reaction. (Click and drag
the appropriate image to the correct position in the reactions.)
Route 1
Aldehyde 1
or
+98
Aldehyde 2
Route 2
Q6
+100
Solved in 1 attempt
Q7
+95
Solved in 2 attempts
Q8
+98
Unlimited attempts
possible
+
+
Grignard 1
OH
H3O+
Grignard 2
Answer Bank
Q9
+90
MgBr
Unlimited attempts
possible
CH3CH2CH2MgBr
Q10
Unlimited attempts
Q11
?
?
+100
in 1 attempt
2-methyl-3-hexanol
CH3CH2MgBr
H
H
о
H
Attempt 3
2) (4 pt) After the reaction was completed, the student collected the following data. Crude
product data is the data collected after the reaction is finished, but before the product
is purified. "Pure" product data is the data collected after attempted purification using
recrystallization.
Student B's data:
Crude product data
"Pure"
product data
after
recrystallization
Crude mass: 0.93 g grey solid
Crude mp: 96-106 °C
Crude % yield:
Pure mass: 0.39 g white solid
Pure mp: 111-113 °C
Pure % yield:
a) Calculate the crude and pure percent yields for the student's reaction.
b) Summarize what is indicated by the crude and pure melting points.
Don't used hand raiting
Chapter 13 Solutions
General Chemistry
Ch. 13.2 - Prob. 1PECh. 13.2 - Prob. 1RCCh. 13.3 - Prob. 1PECh. 13.3 - Prob. 2PECh. 13.3 - Prob. 3PECh. 13.3 - Prob. 1RCCh. 13.4 - Prob. 1RCCh. 13.5 - Prob. 1PECh. 13.5 - Prob. 1RCCh. 13.6 - Prob. 1PE
Ch. 13.6 - Prob. 2PECh. 13.6 - Prob. 2RCCh. 13.6 - Prob. 3PECh. 13.6 - Prob. 4PECh. 13.6 - Prob. 3RCCh. 13.6 - Prob. 5PECh. 13.6 - Prob. 4RCCh. 13 - Prob. 13.1QPCh. 13 - Prob. 13.2QPCh. 13 - Prob. 13.3QPCh. 13 - 13.4 As you know, some solution processes are...Ch. 13 - Prob. 13.5QPCh. 13 - Prob. 13.6QPCh. 13 - Prob. 13.7QPCh. 13 - Prob. 13.8QPCh. 13 - 13.9 Arrange these compounds in order of...Ch. 13 - Prob. 13.10QPCh. 13 - Prob. 13.11QPCh. 13 - Prob. 13.12QPCh. 13 - Prob. 13.13QPCh. 13 - 13.14 Calculate the amount of water (in grams)...Ch. 13 - Prob. 13.15QPCh. 13 - Prob. 13.16QPCh. 13 - Prob. 13.17QPCh. 13 - 12.20 For dilute aqueous solutions in which the...Ch. 13 - Prob. 13.19QPCh. 13 - 13.20 The concentrated sulfuric acid we use in the...Ch. 13 - 13.21 Calculate the molarity and the molality of...Ch. 13 - 13.22 The density of an aqueous solution...Ch. 13 - Prob. 13.23QPCh. 13 - Prob. 13.25QPCh. 13 - 13.26 The solubility of KNO3 is 155 g per 100 g of...Ch. 13 - Prob. 13.27QPCh. 13 - Prob. 13.28QPCh. 13 - Prob. 13.29QPCh. 13 - Prob. 13.30QPCh. 13 - Prob. 13.31QPCh. 13 - 13.32 A man bought a goldfish in a pet shop. Upon...Ch. 13 - Prob. 13.33QPCh. 13 - 13.34 A miner working 260 m below sea level opened...Ch. 13 - Prob. 13.35QPCh. 13 - 13.36 The solubility of N2 in blood at 37°C and at...Ch. 13 - Prob. 13.37QPCh. 13 - Prob. 13.38QPCh. 13 - Prob. 13.39QPCh. 13 - 13.40 How is the lowering in vapor pressure...Ch. 13 - Prob. 13.41QPCh. 13 - Prob. 13.42QPCh. 13 - Prob. 13.43QPCh. 13 - Prob. 13.44QPCh. 13 - Prob. 13.45QPCh. 13 - Prob. 13.46QPCh. 13 - Prob. 13.47QPCh. 13 - 13.48 How many grams of sucrose (C12H22O11) must...Ch. 13 - Prob. 13.49QPCh. 13 - 13.50 The vapor pressures of ethanol (C2H5OH) and...Ch. 13 - Prob. 13.51QPCh. 13 - Prob. 13.52QPCh. 13 - 13.53 What are the boiling point and freezing...Ch. 13 - 13.54 An aqueous solution contains the amino acid...Ch. 13 - 13.55 Pheromones are compounds secreted by the...Ch. 13 - 12.58 The elemental analysis of an organic solid...Ch. 13 - Prob. 13.57QPCh. 13 - 13.58 A solution is prepared by condensing 4.00 L...Ch. 13 - Prob. 13.59QPCh. 13 - 13.60 A solution of 2.50 g of a compound of...Ch. 13 - Prob. 13.61QPCh. 13 - 13.62 A solution containing 0.8330 g of a protein...Ch. 13 - Prob. 13.63QPCh. 13 - 13.64 A solution of 6.85 g of a carbohydrate in...Ch. 13 - 13.65 Define ion pairs. What effect does ion-pair...Ch. 13 - Prob. 13.66QPCh. 13 - Prob. 13.67QPCh. 13 - Prob. 13.68QPCh. 13 - Prob. 13.69QPCh. 13 - Prob. 13.70QPCh. 13 - Prob. 13.71QPCh. 13 - 13.72 At 25°C the vapor pressure of pure water is...Ch. 13 - 13.73 Both NaCl and CaCl2 are used to melt ice on...Ch. 13 - Prob. 13.74QPCh. 13 - Prob. 13.75QPCh. 13 - Prob. 13.76QPCh. 13 - Prob. 13.77QPCh. 13 - Prob. 13.78QPCh. 13 - Prob. 13.79QPCh. 13 - Prob. 13.80QPCh. 13 - Prob. 13.81QPCh. 13 - Prob. 13.82QPCh. 13 - Prob. 13.83QPCh. 13 - Prob. 13.84QPCh. 13 - Prob. 13.85QPCh. 13 - Prob. 13.86QPCh. 13 - Prob. 13.87QPCh. 13 - Prob. 13.88QPCh. 13 - Prob. 13.89QPCh. 13 - Prob. 13.90QPCh. 13 - 13.91 Hydrogen peroxide with a concentration of...Ch. 13 - 13.92 Before a carbonated beverage bottle is...Ch. 13 - Prob. 13.93QPCh. 13 - 13.94 Explain each of these statements: (a) The...Ch. 13 - Prob. 13.95QPCh. 13 - Prob. 13.96QPCh. 13 - Prob. 13.97QPCh. 13 - Prob. 13.98QPCh. 13 - Prob. 13.99QPCh. 13 - Prob. 13.100QPCh. 13 - Prob. 13.101QPCh. 13 - Prob. 13.102QPCh. 13 - Prob. 13.103QPCh. 13 - Prob. 13.104QPCh. 13 - Prob. 13.105SPCh. 13 - Prob. 13.106SPCh. 13 - Prob. 13.107SPCh. 13 - Prob. 13.108SPCh. 13 - Prob. 13.109SPCh. 13 - Prob. 13.110SPCh. 13 - 13.111 A student carried out the following...Ch. 13 - Prob. 13.112SPCh. 13 - Prob. 13.113SPCh. 13 - Prob. 13.114SP
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY