Chemistry (7th Edition)
Chemistry (7th Edition)
7th Edition
ISBN: 9780321943170
Author: John E. McMurry, Robert C. Fay, Jill Kirsten Robinson
Publisher: PEARSON
Question
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Chapter 13, Problem 13.29P

(a)

Interpretation Introduction

To write:

the balanced reaction

b)

Interpretation Introduction

To propose:

a reaction mechanism

Explanaiton:

Proposed Mechanism

1st Step: Determine equilibrium ratios
Rate Law from the slow step

Rate=k2[NO3][NO]

Rate law form the fast step

rateforward=k1[NO][O2]ratereverse=k1[NO3]

In equilibrium, we know that
rateforward=ratereverse

Then
rate=k1[NO3]=k1[NO][O2]

2nd step: Get this based on the slow step reactants, that is NO3

[NO3]=k1k1[NO][O2]

3rd Step: substitute in rate law
Rate=k2[NO3][NO][NO3]=k1k 1[NO][O2]Rate=k2k1k 1[NO][O2][NO]

Assume all constant as “K”
Rate=K[NO]2[O2]

(c)

To propose:

expression for k.

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Chapter 13 Solutions

Chemistry (7th Edition)

Ch. 13 - Prob. 13.11PCh. 13 - Prob. 13.12ACh. 13 - Prob. 13.13PCh. 13 - Prob. 13.14ACh. 13 - Prob. 13.15PCh. 13 - Prob. 13.16ACh. 13 - Prob. 13.17PCh. 13 - Prob. 13.18ACh. 13 - Prob. 13.19PCh. 13 - Prob. 13.20ACh. 13 - Prob. 13.21PCh. 13 - Apply 13.22 The rate of the reaction...Ch. 13 - Prob. 13.23PCh. 13 - Prob. 13.24ACh. 13 - Prob. 13.25PCh. 13 - Prob. 13.26ACh. 13 - Prob. 13.27PCh. 13 - Prob. 13.28ACh. 13 - Prob. 13.29PCh. 13 - Prob. 13.30ACh. 13 - Prob. 13.31PCh. 13 - Prob. 13.32ACh. 13 - Prob. 13.33PCh. 13 - Prob. 13.34PCh. 13 - Prob. 13.35PCh. 13 - Prob. 13.36PCh. 13 - Prob. 13.37PCh. 13 - Prob. 13.38PCh. 13 - Prob. 13.39CPCh. 13 - Prob. 13.40CPCh. 13 - Prob. 13.41CPCh. 13 - Prob. 13.42CPCh. 13 - Prob. 13.43CPCh. 13 - Prob. 13.44CPCh. 13 - Prob. 13.45CPCh. 13 - Prob. 13.46CPCh. 13 - Prob. 13.47CPCh. 13 - Prob. 13.48CPCh. 13 - Prob. 13.49CPCh. 13 - Use the data in Table 13.1 to calculate the...Ch. 13 - 13.50 Use the data in Table 13.1 to calculate the...Ch. 13 - Prob. 13.52SPCh. 13 - Prob. 13.53SPCh. 13 - From the plot of concentrationtime data in Figure...Ch. 13 - Prob. 13.55SPCh. 13 - Prob. 13.56SPCh. 13 - Prob. 13.57SPCh. 13 - Prob. 13.58SPCh. 13 - Prob. 13.59SPCh. 13 - Prob. 13.60SPCh. 13 - Prob. 13.61SPCh. 13 - Prob. 13.62SPCh. 13 - Prob. 13.63SPCh. 13 - Prob. 13.64SPCh. 13 - Prob. 13.65SPCh. 13 - Prob. 13.66SPCh. 13 - Prob. 13.67SPCh. 13 - Prob. 13.68SPCh. 13 - Prob. 13.69SPCh. 13 - Prob. 13.70SPCh. 13 - Prob. 13.71SPCh. 13 - Prob. 13.72SPCh. 13 - Prob. 13.73SPCh. 13 - Prob. 13.74SPCh. 13 - Prob. 13.75SPCh. 13 - Prob. 13.76SPCh. 13 - Prob. 13.77SPCh. 13 - Prob. 13.78SPCh. 13 - Prob. 13.79SPCh. 13 - Prob. 13.80SPCh. 13 - Prob. 13.81SPCh. 13 - Prob. 13.82SPCh. 13 - Prob. 13.83SPCh. 13 - Prob. 13.84SPCh. 13 - Prob. 13.85SPCh. 13 - Prob. 13.86SPCh. 13 - Prob. 13.87SPCh. 13 - Prob. 13.88SPCh. 13 - Prob. 13.89SPCh. 13 - Prob. 13.90SPCh. 13 - Prob. 13.91SPCh. 13 - Prob. 13.92SPCh. 13 - Prob. 13.93SPCh. 13 - Prob. 13.94SPCh. 13 - Prob. 13.95SPCh. 13 - Prob. 13.96SPCh. 13 - Prob. 13.97SPCh. 13 - Prob. 13.98SPCh. 13 - Prob. 13.99SPCh. 13 - Prob. 13.100SPCh. 13 - Prob. 13.101SPCh. 13 - Prob. 13.102SPCh. 13 - Prob. 13.103SPCh. 13 - Prob. 13.104SPCh. 13 - Prob. 13.105SPCh. 13 - Prob. 13.106SPCh. 13 - Prob. 13.107SPCh. 13 - Prob. 13.108SPCh. 13 - Prob. 13.109SPCh. 13 - Prob. 13.110SPCh. 13 - Prob. 13.111SPCh. 13 - Prob. 13.112SPCh. 13 - Prob. 13.113SPCh. 13 - Prob. 13.114SPCh. 13 - Prob. 13.115CPCh. 13 - Prob. 13.116CPCh. 13 - Prob. 13.117CPCh. 13 - Prob. 13.118CPCh. 13 - Prob. 13.119CPCh. 13 - Prob. 13.120CPCh. 13 - Prob. 13.121CPCh. 13 - Prob. 13.122CPCh. 13 - Prob. 13.123CPCh. 13 - Prob. 13.124CPCh. 13 - Prob. 13.125CPCh. 13 - Prob. 13.126CPCh. 13 - Prob. 13.127CPCh. 13 - Prob. 13.128CPCh. 13 - Prob. 13.129CPCh. 13 - Prob. 13.130CPCh. 13 - Prob. 13.131CPCh. 13 - Prob. 13.132CPCh. 13 - Prob. 13.133CPCh. 13 - Prob. 13.134CPCh. 13 - Prob. 13.135CPCh. 13 - Prob. 13.136CPCh. 13 - Prob. 13.137CPCh. 13 - Prob. 13.138CPCh. 13 - Prob. 13.139CPCh. 13 - Prob. 13.140CPCh. 13 - Prob. 13.141CPCh. 13 - Prob. 13.142CPCh. 13 - Prob. 13.143CPCh. 13 - Prob. 13.144MPCh. 13 - Prob. 13.145MPCh. 13 - Prob. 13.146MPCh. 13 - Prob. 13.147MPCh. 13 - Prob. 13.148MPCh. 13 - Prob. 13.149MPCh. 13 - Prob. 13.150MP
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