It is to be determined among aprotic solvents DMSO and DMF, which is best suitable for S N 2 reaction, based on their toxicity. Concept introduction: Polar aprotic solvents do not stabilize nucleophiles as much as polar protic solvents do’ thus polar aprotic solvents tend to favor S N 2 reactions. As a safety precaution, it is better to use less toxic solvents for the reactions.

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Answer 1

Question

Chapter 13, Problem 13.24P

Interpretation Introduction

Interpretation:

It is to be determined among aprotic solvents DMSO and DMF, which is best suitable for SN2 reaction, based on their toxicity.

Concept introduction:

Polar aprotic solvents do not stabilize nucleophiles as much as polar protic solvents do’ thus polar aprotic solvents tend to favor SN2 reactions. As a safety precaution, it is better to use less toxic solvents for the reactions.

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First image: I have to explain why the molecule C is never formed in those conditions. Second image: I have to propose a synthesis for the lactone A

First image: I have to explain why the molecule C is never formed in these conditions Second image: I have to propose a synthesis for the lactone A

Answer 2

Question

Chapter 13, Problem 13.24P

Interpretation Introduction

Interpretation:

It is to be determined among aprotic solvents DMSO and DMF, which is best suitable for SN2 reaction, based on their toxicity.

Concept introduction:

Polar aprotic solvents do not stabilize nucleophiles as much as polar protic solvents do’ thus polar aprotic solvents tend to favor SN2 reactions. As a safety precaution, it is better to use less toxic solvents for the reactions.

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Answer 3

Question

Chapter 13, Problem 13.24P

Interpretation Introduction

Interpretation:

It is to be determined among aprotic solvents DMSO and DMF, which is best suitable for SN2 reaction, based on their toxicity.

Concept introduction:

Polar aprotic solvents do not stabilize nucleophiles as much as polar protic solvents do’ thus polar aprotic solvents tend to favor SN2 reactions. As a safety precaution, it is better to use less toxic solvents for the reactions.

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Answer 4

Question

Chapter 13, Problem 13.24P

Interpretation Introduction

Interpretation:

It is to be determined among aprotic solvents DMSO and DMF, which is best suitable for SN2 reaction, based on their toxicity.

Concept introduction:

Polar aprotic solvents do not stabilize nucleophiles as much as polar protic solvents do’ thus polar aprotic solvents tend to favor SN2 reactions. As a safety precaution, it is better to use less toxic solvents for the reactions.

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Answer 5

Chapter 13, Problem 13.24P

Interpretation Introduction

Interpretation:

It is to be determined among aprotic solvents DMSO and DMF, which is best suitable for SN2 reaction, based on their toxicity.

Concept introduction:

Polar aprotic solvents do not stabilize nucleophiles as much as polar protic solvents do’ thus polar aprotic solvents tend to favor SN2 reactions. As a safety precaution, it is better to use less toxic solvents for the reactions.

Answer 6

Chapter 13, Problem 13.24P

Interpretation Introduction

Interpretation:

It is to be determined among aprotic solvents DMSO and DMF, which is best suitable for SN2 reaction, based on their toxicity.

Concept introduction:

Polar aprotic solvents do not stabilize nucleophiles as much as polar protic solvents do’ thus polar aprotic solvents tend to favor SN2 reactions. As a safety precaution, it is better to use less toxic solvents for the reactions.

Answer 7

Chapter 13, Problem 13.24P

Interpretation Introduction

Interpretation:

It is to be determined among aprotic solvents DMSO and DMF, which is best suitable for SN2 reaction, based on their toxicity.

Concept introduction:

Polar aprotic solvents do not stabilize nucleophiles as much as polar protic solvents do’ thus polar aprotic solvents tend to favor SN2 reactions. As a safety precaution, it is better to use less toxic solvents for the reactions.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 13 - Prob. 13.1P Ch. 13 - Prob. 13.2P Ch. 13 - Prob. 13.3P Ch. 13 - Prob. 13.4P Ch. 13 - Prob. 13.5P Ch. 13 - Prob. 13.6P Ch. 13 - Prob. 13.7P Ch. 13 - Prob. 13.8P Ch. 13 - Prob. 13.9P Ch. 13 - Prob. 13.10P

Solution Summary: The author explains that aprotic solvents DMSO and DMF are more suitable for S_

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Chapter 13 Solutions