Exploring Chemical Analysis
Exploring Chemical Analysis
5th Edition
ISBN: 9781429275033
Author: Daniel C. Harris
Publisher: Macmillan Higher Education
Question
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Chapter 13, Problem 13.18P

(a)

Interpretation Introduction

Interpretation:

Chemical reaction that has β4 as its equilibrium constant has to be determined.

Concept Introduction:

Equilibrium constants required for formation of complexes is known as formation constants. These can be stepwise or overall formation constants. Stepwise formation constants are represented by Ki whereas overall or cumulative formation constants are denoted by βi. Here, i indicates number of steps involved in any particular chemical reaction.

(b)

Interpretation Introduction

Interpretation:

Chemical reaction that has K4 as its stepwise formation constant has to be determined. Also, numerical value of K4 has to be determined.

Concept Introduction:

Equilibrium constants required for formation of complexes is known as formation constants. These can be stepwise or overall formation constants. Stepwise formation constants are represented by Ki whereas overall or cumulative formation constants are denoted by βi. Here, i indicates number of steps involved in any particular chemical reaction.

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Done 11:14 ⚫ worksheets.beyondlabz.com 5 (a). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 6 5 (b). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 7 6. Are there any differences between the spectra you obtained in Beyond Labz and the predicted spectra? If so, what were the differences? <
2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled** Peak Chemical Shift (d) 5.7 1 Multiplicity multiplate .......... 5.04 double of doublet 2 4.98 double of doublet 3 4.05 doublet of quartet 4 5 LO 3.80 quartet 1.3 doublet 6 Peak Chemical Shift (d) Multiplicity
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