A gaseous material XY( g ) dissociates to some extent to produce X( g ) and Y( g ): XY ( g ) ⇌ X ( g ) + Y ( g ) A 2.00-g sample of XY (molar mass = 165 g/mol) is placed in a container with a movable piston at 25°C. The pressure is held constant at 0.967 atm. As XY begins to dissociate, the piston moves until 35.0 mole percent of the original XY has dissociated and then remains at a constant position. Assuming ideal behavior, calculate the density of the gas in the container after the piston has stopped moving, and determine the value of K for this reaction of 25°C.
A gaseous material XY( g ) dissociates to some extent to produce X( g ) and Y( g ): XY ( g ) ⇌ X ( g ) + Y ( g ) A 2.00-g sample of XY (molar mass = 165 g/mol) is placed in a container with a movable piston at 25°C. The pressure is held constant at 0.967 atm. As XY begins to dissociate, the piston moves until 35.0 mole percent of the original XY has dissociated and then remains at a constant position. Assuming ideal behavior, calculate the density of the gas in the container after the piston has stopped moving, and determine the value of K for this reaction of 25°C.
Solution Summary: The author explains how the equilibrium constant K describes the ratio of the reactant to the product on equilibrium conditions in terms of molar concentration.
A gaseous material XY(g) dissociates to some extent to produce X(g) and Y(g):
XY
(
g
)
⇌
X
(
g
)
+
Y
(
g
)
A 2.00-g sample of XY (molar mass = 165 g/mol) is placed in a container with a movable piston at 25°C. The pressure is held constant at 0.967 atm. As XY begins to dissociate, the piston moves until 35.0 mole percent of the original XY has dissociated and then remains at a constant position. Assuming ideal behavior, calculate the density of the gas in the container after the piston has stopped moving, and determine the value of K for this reaction of 25°C.
Draw e arrows between the following resonance structures:
a)
b)
: 0:
:0:
c) :0:
N
t
: 0:
بار
N
Draw the major substitution products you would expect for the reaction shown below. If substitution would not occur at a significant
rate under these conditions, check the box underneath the drawing area instead.
Be sure you use wedge and dash bonds where necessary, for example to distinguish between major products.
Note for advanced students: you can assume that the reaction mixture is heated mildly, somewhat above room temperature, but
strong heat or reflux is not used.
Cl
Substitution will not occur at a significant rate.
Explanation
Check
:☐
O-CH
+
Х
Click and drag to start
drawing a structure.
Draw the major substitution products you would expect for the reaction shown below. If substitution would not occur at a significant
rate under these conditions, check the box underneath the drawing area instead.
Be sure you use wedge and dash bonds where necessary, for example to distinguish between major products.
Note for advanced students: you can assume that the reaction mixture is heated mildly, somewhat above room temperature, but
strong heat or reflux is not used.
Cl
C
O Substitution will not occur at a significant rate.
Explanation
Check
+
O-CH3
Х
Click and drag to start
drawing a structure.
Chapter 13 Solutions
Lab Manual for Zumdahl/Zumdahl/DeCoste¿s Chemistry, 10th Edition
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