Chemistry: The Central Science (13th Edition)
13th Edition
ISBN: 9780321910417
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus
Publisher: PEARSON
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Textbook Question
Chapter 12.7, Problem 12.3.1PE
The following diagram represents a high-temperature reaction between CH4 and H20. Based
on this reaction, find how many moles of each product can be obtained starting with 4.0 mol CH4
[Section 3.6]
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. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
2°C. +2°C. < cleavage
Bond A
• CH3 + 26. t cleavage
2°C• +3°C•
Bond C
Cleavage
CH3 ZC
'2°C. 26.
E
Strongest
3°C. 2C.
Gund
Largest
BDE
weakest bond
In that molecule
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
Weakest
C bond
Produces
A
Weakest
Bond
Most
Strongest
Bond
Stable radical
Strongest Gund
produces least stable
radicals
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
人
8°C. formed in
bound C
cleavage
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
methyl radical
•CH3
formed in
bund A Cleavage
Which carbocation is more stable?
Are the products of the given reaction correct? Why or why not?
Chapter 12 Solutions
Chemistry: The Central Science (13th Edition)
Ch. 12.3 - The following diagram shows the combination...Ch. 12.3 -
3.3 The following diagram represents the...Ch. 12.5 -
3.4 The following diagram represents the...Ch. 12.5 - Glycine, an amino acid used by organisms to make...Ch. 12.7 - The following diagram represents a...Ch. 12.7 -
3.7 Nitrogen (N2) and hydrogen (H2) react to form...Ch. 12.7 -
3.8 Nitrogen monoxide and oxygen react to form...Ch. 12.7 - Write "true" or "false" for each statement. a. We...Ch. 12 - Determine the empirical and molecular formulas of...Ch. 12 - a. Combustion analysis of toluene, a common...
Ch. 12 -
3.67 Automotive air bags infilate when sodium...Ch. 12 - Prob. 3ECh. 12 - Prob. 4ECh. 12 -
12.5 Which of these molecular fragments would...Ch. 12 - Prob. 6ECh. 12 - Prob. 7ECh. 12 - Prob. 8ECh. 12 - Prob. 9ECh. 12 - Prob. 10ECh. 12 - Prob. 11ECh. 12 - Prob. 12ECh. 12 - 12.13 Indicate the type of solid (molecular,...Ch. 12 - Prob. 14ECh. 12 -
12.15 A white substance melts with some...Ch. 12 -
12.16 You are given a white substance that...Ch. 12 - Prob. 17ECh. 12 - Prob. 18ECh. 12 - Prob. 19ECh. 12 - Prob. 20ECh. 12 - Prob. 21ECh. 12 - Prob. 22ECh. 12 - Prob. 23ECh. 12 - Prob. 24ECh. 12 - Prob. 25ECh. 12 - Prob. 26ECh. 12 - Prob. 27ECh. 12 - Prob. 28ECh. 12 - Prob. 29ECh. 12 - Prob. 30ECh. 12 - Prob. 31ECh. 12 - Prob. 32ECh. 12 - Prob. 33ECh. 12 - Prob. 34ECh. 12 - Prob. 35ECh. 12 - Prob. 36ECh. 12 - Prob. 37ECh. 12 - Prob. 38ECh. 12 - Prob. 39ECh. 12 - Prob. 40ECh. 12 - Prob. 41ECh. 12 - Prob. 42ECh. 12 - Prob. 43ECh. 12 - Prob. 44ECh. 12 - Prob. 45ECh. 12 - Prob. 46ECh. 12 - Prob. 47ECh. 12 - Prob. 48ECh. 12 -
12.49 Which would you expect to be the more...Ch. 12 - Prob. 50ECh. 12 - Prob. 51ECh. 12 - Prob. 52ECh. 12 - Prob. 53ECh. 12 - Prob. 54ECh. 12 - Prob. 55ECh. 12 - Clausthalite is a mineral composed of lead...Ch. 12 - Prob. 57ECh. 12 - Prob. 58ECh. 12 - Prob. 59ECh. 12 - Prob. 60ECh. 12 - Prob. 61ECh. 12 - Prob. 62ECh. 12 - Prob. 63ECh. 12 - Prob. 64ECh. 12 - Prob. 65ECh. 12 - Prob. 66ECh. 12 - Prob. 67ECh. 12 - Prob. 68ECh. 12 - Prob. 69ECh. 12 - Prob. 70ECh. 12 - Prob. 71ECh. 12 - Prob. 72ECh. 12 - Prob. 73ECh. 12 - Prob. 74ECh. 12 - Prob. 75ECh. 12 - Prob. 76ECh. 12 - Prob. 77ECh. 12 - Prob. 78ECh. 12 - Prob. 79ECh. 12 - Prob. 80ECh. 12 - Prob. 81ECh. 12 - Prob. 82ECh. 12 - Prob. 83ECh. 12 - Prob. 84ECh. 12 - Prob. 85ECh. 12 - Prob. 86ECh. 12 - Prob. 87ECh. 12 - Prob. 88ECh. 12 - Prob. 89ECh. 12 - Prob. 90ECh. 12 - Prob. 91ECh. 12 - Prob. 92ECh. 12 - Prob. 93ECh. 12 - Prob. 94ECh. 12 - Prob. 95ECh. 12 - Prob. 96ECh. 12 - Prob. 97ECh. 12 - Prob. 98ECh. 12 - Prob. 99AECh. 12 - Prob. 100AECh. 12 - Prob. 101AECh. 12 - Prob. 102AECh. 12 - Prob. 103AECh. 12 - What type of lattice—primitive cubic body-centered...Ch. 12 - Prob. 105AECh. 12 - Prob. 106AECh. 12 - Prob. 107AECh. 12 - Prob. 108AECh. 12 - Prob. 109AECh. 12 - Prob. 110AECh. 12 - Prob. 111AECh. 12 - Prob. 112AECh. 12 - Prob. 113AECh. 12 - 12.114 Germanium has the same structure as...Ch. 12 - Prob. 115AECh. 12 - Prob. 116AECh. 12 - The karat scale used to describe gold alloys is...Ch. 12 - Prob. 118IECh. 12 - Prob. 119IECh. 12 - Prob. 120IECh. 12 - Prob. 121IECh. 12 - Prob. 122IECh. 12 - Prob. 123IECh. 12 - Prob. 124IECh. 12 - Prob. 125IE
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