ORGANIC CHEMISTRY
ORGANIC CHEMISTRY
9th Edition
ISBN: 9780134645704
Author: WADE AND SIMEK
Publisher: PEARSON
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Chapter 12.5, Problem 12.2P

Which of the bonds shown in red are expected to have IR-active stretching frequencies?

  1. (a) H—C≡C—H
  2. (b) H—C≡C—H
  3. (c) H—C≡C—CH3
  4. (d) H3C—C≡C—CH3
  5. (e) H3C—C≡C—CH3
  6. (f) H3C—CH3

Chapter 12.5, Problem 12.2P, Which of the bonds shown in red are expected to have IR-active stretching frequencies? (a) HCCH (b) , example  1

Chapter 12.5, Problem 12.2P, Which of the bonds shown in red are expected to have IR-active stretching frequencies? (a) HCCH (b) , example  2

Chapter 12.5, Problem 12.2P, Which of the bonds shown in red are expected to have IR-active stretching frequencies? (a) HCCH (b) , example  3

Chapter 12.5, Problem 12.2P, Which of the bonds shown in red are expected to have IR-active stretching frequencies? (a) HCCH (b) , example  4

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Q1: Draw the most stable and the least stable Newman projections about the C2-C3 bond for each of the following isomers (A-C). Are the barriers to rotation identical for enantiomers A and B? How about the diastereomers (A versus C or B versus C)? enantiomers H Br H Br (S) CH3 H3C (S) (R) CH3 H3C H Br A Br H C H Br H3C (R) B (R)CH3 H Br H Br H3C (R) (S) CH3 Br H D identical
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