An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given. Concept Introduction: A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary. IUPAC rules for naming alcohols: Alcohols are named by identifying the parent compound and replacing the –e ending with –ol . Ketones are named by identifying the parent compound and replacing the –e ending with –one as suffix. Lowest possible number should be given for the hydroxyl group present in the parent chain, similarly do for carbonyl group. Name and number all substituent, and put them as prefixes to “ alkanol ” name also give the first preference as per the alphabetical order. If an alcohol contains two hydroxyl groups then name it as diol , an alcohol; contains three hydroxyl groups then name it as triol . Common names for alcohols are derived from alkyl group corresponding to the parent compound.

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 12.4, Problem 12.7Q

(a)

Interpretation Introduction

Interpretation:

An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given.

Concept Introduction:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

IUPAC rules for naming alcohols:

Alcohols are named by identifying the parent compound and replacing the –e ending with –ol.

Ketones are named by identifying the parent compound and replacing the –e ending with –one as suffix.

Lowest possible number should be given for the hydroxyl group present in the parent chain, similarly do for carbonyl group.

Name and number all substituent, and put them as prefixes to “alkanol” name also give the first preference as per the alphabetical order.

If an alcohol contains two hydroxyl groups then name it as diol, an alcohol; contains three hydroxyl groups then name it as triol.

Common names for alcohols are derived from alkyl group corresponding to the parent compound.

(b)

Interpretation Introduction

Interpretation:

An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given.

Concept Introduction:

Refer part (a).

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Experiment: Each team will be provided with 5g of a mixture of acetanilide and salicylic acid. You will divide it into three 1.5 g portions in separate 125 mL Erlenmeyer flasks savıng some for melting point analysis. Dissolve the mixture in each flask in ~60mL of DI water by heating to boiling on a hotplate. Take the flasks off the hotplate once you have a clear solution and let them stand on the bench top for 5 mins and then allow them to cool as described below. Sample A-Let the first sample cool slowly to room temperature by letting it stand on your lab bench, with occasional stirring to promote crystallization. Sample B-Cool the second sample 1n a tap-water bath to 10-15 °C Sample C-Cool the third sample in an ice-bath to 0-2 °C Results: weight after recrystalization and melting point temp. A=0.624g,102-115° B=0.765g, 80-105° C=1.135g, 77-108 What is the percent yield of A,B, and C.

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Answer 2

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Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 12.4, Problem 12.7Q

(a)

Interpretation Introduction

Interpretation:

An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given.

Concept Introduction:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

IUPAC rules for naming alcohols:

Alcohols are named by identifying the parent compound and replacing the –e ending with –ol.

Ketones are named by identifying the parent compound and replacing the –e ending with –one as suffix.

Lowest possible number should be given for the hydroxyl group present in the parent chain, similarly do for carbonyl group.

Name and number all substituent, and put them as prefixes to “alkanol” name also give the first preference as per the alphabetical order.

If an alcohol contains two hydroxyl groups then name it as diol, an alcohol; contains three hydroxyl groups then name it as triol.

Common names for alcohols are derived from alkyl group corresponding to the parent compound.

(b)

Interpretation Introduction

Interpretation:

An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given.

Concept Introduction:

Refer part (a).

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 12.4, Problem 12.7Q

(a)

Interpretation Introduction

Interpretation:

An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given.

Concept Introduction:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

IUPAC rules for naming alcohols:

Alcohols are named by identifying the parent compound and replacing the –e ending with –ol.

Ketones are named by identifying the parent compound and replacing the –e ending with –one as suffix.

Lowest possible number should be given for the hydroxyl group present in the parent chain, similarly do for carbonyl group.

Name and number all substituent, and put them as prefixes to “alkanol” name also give the first preference as per the alphabetical order.

If an alcohol contains two hydroxyl groups then name it as diol, an alcohol; contains three hydroxyl groups then name it as triol.

Common names for alcohols are derived from alkyl group corresponding to the parent compound.

(b)

Interpretation Introduction

Interpretation:

An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given.

Concept Introduction:

Refer part (a).

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 12.4, Problem 12.7Q

(a)

Interpretation Introduction

Interpretation:

An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given.

Concept Introduction:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

IUPAC rules for naming alcohols:

Alcohols are named by identifying the parent compound and replacing the –e ending with –ol.

Ketones are named by identifying the parent compound and replacing the –e ending with –one as suffix.

Lowest possible number should be given for the hydroxyl group present in the parent chain, similarly do for carbonyl group.

Name and number all substituent, and put them as prefixes to “alkanol” name also give the first preference as per the alphabetical order.

If an alcohol contains two hydroxyl groups then name it as diol, an alcohol; contains three hydroxyl groups then name it as triol.

Common names for alcohols are derived from alkyl group corresponding to the parent compound.

(b)

Interpretation Introduction

Interpretation:

An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given.

Concept Introduction:

Refer part (a).

Expert Solution & Answer

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Answer 5

Chapter 12.4, Problem 12.7Q

(a)

Interpretation Introduction

Interpretation:

An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given.

Concept Introduction:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

IUPAC rules for naming alcohols:

Alcohols are named by identifying the parent compound and replacing the –e ending with –ol.

Ketones are named by identifying the parent compound and replacing the –e ending with –one as suffix.

Lowest possible number should be given for the hydroxyl group present in the parent chain, similarly do for carbonyl group.

Name and number all substituent, and put them as prefixes to “alkanol” name also give the first preference as per the alphabetical order.

If an alcohol contains two hydroxyl groups then name it as diol, an alcohol; contains three hydroxyl groups then name it as triol.

Common names for alcohols are derived from alkyl group corresponding to the parent compound.

(b)

Interpretation Introduction

Interpretation:

An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given.

Concept Introduction:

Refer part (a).

Answer 6

Chapter 12.4, Problem 12.7Q

(a)

Interpretation Introduction

Interpretation:

An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given.

Concept Introduction:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

IUPAC rules for naming alcohols:

Alcohols are named by identifying the parent compound and replacing the –e ending with –ol.

Ketones are named by identifying the parent compound and replacing the –e ending with –one as suffix.

Lowest possible number should be given for the hydroxyl group present in the parent chain, similarly do for carbonyl group.

Name and number all substituent, and put them as prefixes to “alkanol” name also give the first preference as per the alphabetical order.

If an alcohol contains two hydroxyl groups then name it as diol, an alcohol; contains three hydroxyl groups then name it as triol.

Common names for alcohols are derived from alkyl group corresponding to the parent compound.

Answer 7

Chapter 12.4, Problem 12.7Q

(a)

Interpretation Introduction

Interpretation:

An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given.

Concept Introduction:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

IUPAC rules for naming alcohols:

Alcohols are named by identifying the parent compound and replacing the –e ending with –ol.

Ketones are named by identifying the parent compound and replacing the –e ending with –one as suffix.

Lowest possible number should be given for the hydroxyl group present in the parent chain, similarly do for carbonyl group.

Name and number all substituent, and put them as prefixes to “alkanol” name also give the first preference as per the alphabetical order.

If an alcohol contains two hydroxyl groups then name it as diol, an alcohol; contains three hydroxyl groups then name it as triol.

Common names for alcohols are derived from alkyl group corresponding to the parent compound.

Answer 8

(b)

Interpretation Introduction

Interpretation:

An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given.

Concept Introduction:

Refer part (a).

Answer 9

(b)

Interpretation Introduction

Interpretation:

An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given.

Concept Introduction:

Refer part (a).

Answer 10

Expert Solution & Answer

Answer 11

Expert Solution & Answer

Answer 12

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Answer 13

Ch. 12.1 - Prob. 12.1PP Ch. 12.2 - Prob. 12.2PP Ch. 12.2 - Prob. 12.3PP Ch. 12.2 - Prob. 12.1Q Ch. 12.2 - Prob. 12.2Q Ch. 12.4 - Write an equation representing the reduction of...Ch. 12.4 - Write an equation representing the reduction of...Ch. 12.4 - Prob. 12.6PP Ch. 12.4 - Prob. 12.7PP Ch. 12.4 - Prob. 12.8PP

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Interpretation:

An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given.

Concept Introduction:

Refer part (a).

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Chapter 12 Solutions

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Interpretation: An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given. Concept Introduction: Refer part (a).

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Chapter 12 Solutions

Interpretation:

An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given.

Concept Introduction:

Refer part (a).