(a)
Interpretation:
The reagent for the given transformation should be identified.
Concept introduction:
9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of
The role of dilute sulfuric acid is used for the hydration of alkene in
The oxymercuration reaction is an electrophilic addition reaction, an alkene undergoes oxymercuration and forms neutral alcohol.
Anti-Markovnikov’s rule: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the less substitution position of carbon-carbon double bond which provides
Markovnikov addition: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.
(b)
Interpretation:
The reagent for the given transformation should be identified.
Concept introduction:
9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols.
The role of dilute sulfuric acid is used for the hydration of alkene in organic synthesis.
The oxymercuration reaction is an electrophilic addition reaction, an alkene undergoes oxymercuration and forms neutral alcohol.
Anti-Markovnikov’s rule: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.
Markovnikov addition: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.
(c)
Interpretation:
The reagent for the given transformation should be identified.
Concept introduction:
9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols.
The role of dilute sulfuric acid is used for the hydration of alkene in organic synthesis.
The oxymercuration reaction is an electrophilic addition reaction, an alkene undergoes oxymercuration and forms neutral alcohol.
Anti-Markovnikov’s rule: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.
Markovnikov addition: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.
Want to see the full answer?
Check out a sample textbook solution
Chapter 12 Solutions
Organic Chemistry, Third Edition Binder Ready Version
- Please complete the reactions, thank youarrow_forwardConsider the synthesis. What is compound Y? Please explain what is happening in this question. Provide a detailed explanation and a drawing to show how the compound Y creates the product. The correct answer is D.arrow_forwardWhat would be the major product of the following reaction? Please include a detailed explanation of what is happening in this question. Include steps and a drawing to show this reaction proceeds and how the final product is formed. The correct answer is B. I put answer D and I don't really understand what is going on in the question.arrow_forward
- What is the product of the following reaction? Please explain what is happening in this question. Provide a detailed explanation and a drawing showing how the reagent is reacting with the catalysts to product the correct product. The correct answer is B.arrow_forwardWhat is the missing intermediate 1 and the final product 2. Please include a detailed explanation explaining the steps of malonic ester synthesis. Please include drawings of the intermediate and how it occurs and how the final product is former.arrow_forwardWhat would be the reagents and conditions above and below the arrow that will complete the proposed acetoacetic ester synthesis? If it cannot be done efficiently, then I will choose that answer. There could be 2 or 4 reagents involved. Please provide a detailed explanation and drawings showing how it would proceed with the correct reagents.arrow_forward
- For benzene, the ∆H° of vaporization is 30.72 kJ/mol and the ∆S° of vaporization is 86.97 J/mol･K. At 1.00 atm and 228.0 K, what is the ∆G° of vaporization for benzene, in kJ/mol?arrow_forwardThe reaction Q(g) + R(g) → Z(l) is shown to be exothermic. Which of the following is true concerning the reaction. it is spontaneous only at High T, it is spontaneous at low T it is nonspontaneous at all T it is spontanrous at all T. it is non spontaneous only at low T.arrow_forwardThe reaction Q(g) + R(g) → Z(l) is shown to be exothermic. Which of the following is true concerning the reactionarrow_forward
- Which of the following has the largest standard molar entropy, S° (298.15 K) He H2 NaCl KBr Hgarrow_forwardWhich of the following is true for a particular reaction if ∆G° is -40.0 kJ/mol at 290 K and –20.0 kJ/mol at 390 K?arrow_forwardWhat is the major product of the following reaction? O O OH OH 1. BH 2. H₂O₂, NaOH OH OHarrow_forward
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
ChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill Education
Principles of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill Education
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY