Chapter 12.10, Problem 20PTS

(a)

Interpretation Introduction

Interpretation:

The product for the given set of reactions should be identified.

Concept introduction:

Oxidation Reaction: It involves loss of electrons, addition of oxygen atoms or removal of hydrogen atoms. The oxidation of alcohol are achieved by using reagents like $\text{PCC}$$\left(\text{Pyridinium chloro chromate}\right)$, ${\text{Na}}_{\text{2}}{\text{Cr}}_{\text{2}}{\text{O}}_{\text{7}}$, ${\text{CrO}}_{\text{3}}$ etc.

(b)

Interpretation Introduction

Interpretation:

The product for the given set of reactions should be identified.

Concept introduction:

Oxidation Reaction: It involves loss of electrons, addition of oxygen atoms or removal of hydrogen atoms. The oxidation of alcohol are achieved by using reagents like $\text{PCC}$$\left(\text{Pyridinium chloro chromate}\right)$, ${\text{Na}}_{\text{2}}{\text{Cr}}_{\text{2}}{\text{O}}_{\text{7}}$, ${\text{CrO}}_{\text{3}}$ etc.

(c)

Interpretation Introduction

Interpretation:

The product for the given set of reactions should be identified.

Concept introduction:

Oxidation Reaction: It involves loss of electrons, addition of oxygen atoms or removal of hydrogen atoms. The oxidation of alcohol are achieved by using reagents like $\text{PCC}$$\left(\text{Pyridinium chloro chromate}\right)$, ${\text{Na}}_{\text{2}}{\text{Cr}}_{\text{2}}{\text{O}}_{\text{7}}$, ${\text{CrO}}_{\text{3}}$ etc.

(d)

Interpretation Introduction

Interpretation:

The product for the given set of reactions should be identified.

Concept introduction:

Swern oxidation:

Primary and secondary alcohols undergoes oxidation reaction using dimethyl sulfoxide, oxalyl chloride and triethyl amine which provides aldehyde and ketones.

(e)

Interpretation Introduction

Interpretation:

The product for the given set of reactions should be identified.

Concept introduction:

Oxidation Reaction: It involves loss of electrons, addition of oxygen atoms or removal of hydrogen atoms. The oxidation of alcohol are achieved by using reagents like $\text{PCC}$$\left(\text{Pyridinium chloro chromate}\right)$, ${\text{Na}}_{\text{2}}{\text{Cr}}_{\text{2}}{\text{O}}_{\text{7}}$, ${\text{CrO}}_{\text{3}}$ etc.

(f)

Interpretation Introduction

Interpretation:

The product for the given set of reactions should be identified.

Concept introduction:

Oxidation Reaction: The Dess-Martin Periodinane (DMP), a hyper valent iodine compound, offers selective and very mild oxidation of alcohols to aldehydes.