Basic Chemistry (5th Edition)
Basic Chemistry (5th Edition)
5th Edition
ISBN: 9780134138046
Author: Karen C. Timberlake
Publisher: PEARSON
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Chapter 12.3, Problem 12.17QAP
Interpretation Introduction

Interpretation:

To determine whether each o the following solutions will be saturated or unsaturated at 20oC.. by using the following table.

  Solubility (g/100 g H2O)
Solutions 200C 500C
KCl 34 43
NaNO3 88 110
C12H22O11(sugar) 204 260

a. Adding 25g of KCl to 100 g of H2O.

b. Adding 11 g of NaNO3 to 25 g of H2O.

c. Adding 400g of sugar to 125 g of H2O.

Concept introduction:

Solubility: It is defined as the amount of a given substance that can be dissolved in the certain amount of solvent.

Depending upon the solubility and nature of solutions they can be divided into two types.

A saturated solution contains the maximum quantity of a solute that dissolves at that temperature.

An unsaturated solution contain less than the maximum amount of solute that can dissolves at a particular temperature.

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2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled** Peak Chemical Shift (d) 5.7 1 Multiplicity multiplate .......... 5.04 double of doublet 2 4.98 double of doublet 3 4.05 doublet of quartet 4 5 LO 3.80 quartet 1.3 doublet 6 Peak Chemical Shift (d) Multiplicity
Interpreting NMR spectra is a skill that often requires some amount of practice, which, in turn, necessitates access to a collection of NMR spectra. Beyond Labz Organic Synthesis and Organic Qualitative Analysis have spectral libraries containing over 700 1H NMR spectra. In this assignment, you will take advantage of this by first predicting the NMR spectra for two closely related compounds and then checking your predictions by looking up the actual spectra in the spectra library. After completing this assignment, you may wish to select other compounds for additional practice. 1. Write the IUPAC names for the following two structures: Question 2 Question 3 2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled**
11:14 ... worksheets.beyondlabz.com 3. To check your predictions, click this link for Interpreting NMR Spectra 1. You will see a list of all the - compounds in the spectra library in alphabetical order by IUPAC name. Hovering over a name in the list will show the structure on the chalkboard. The four buttons on the top of the Spectra tab in the tray are used to select the different spectroscopic techniques for the selected compound. Make sure the NMR button has been selected. 4. Scroll through the list of names to find the names for the two compounds you have been given and click on the name to display the NMR spectrum for each. In the NMR tables below, list the chemical shift, the splitting, and the number of hydrogens associated with each peak for each compound. Compare your answers to your predictions. **Not all slots must be filled** Peak Chemical Shift (d) Multiplicity 1 2 3 4 5

Chapter 12 Solutions

Basic Chemistry (5th Edition)

Ch. 12.2 - Prob. 12.11QAPCh. 12.2 - Prob. 12.12QAPCh. 12.2 - Prob. 12.13QAPCh. 12.2 - Prob. 12.14QAPCh. 12.3 - Prob. 12.15QAPCh. 12.3 - State whether each of the following refers to a...Ch. 12.3 - Prob. 12.17QAPCh. 12.3 - Use the following table for problems 9.23 to 9.26:...Ch. 12.3 - Use the following table for problems 9.23 to 9.26:...Ch. 12.3 - Use the following table for problems 9.23 to 9.26:...Ch. 12.3 - Explain the following observations: More sugar...Ch. 12.3 - Explain the following observations: An open can of...Ch. 12.3 - Prob. 12.23QAPCh. 12.3 - Prob. 12.24QAPCh. 12.3 - Determine whether a solid forms when solutions...Ch. 12.3 - Prob. 12.26QAPCh. 12.4 - Prob. 12.27QAPCh. 12.4 - Prob. 12.28QAPCh. 12.4 - Calculate the mass percent (m/m) for the solute in...Ch. 12.4 - Calculate the mass percent (m/m) for the solute in...Ch. 12.4 - Calculate the mass/volume percent (m/v) for the...Ch. 12.4 - Calculate the mass/volume percent (m/v) for the...Ch. 12.4 - Prob. 12.33QAPCh. 12.4 - Calculate the grams or milliliters of solute...Ch. 12.4 - A mouthwash contains 22.5% (v/v) alcohol. If the...Ch. 12.4 - A bottle of champagne is 11% (v/v) alcohol. If...Ch. 12.4 - Prob. 12.37QAPCh. 12.4 - Prob. 12.38QAPCh. 12.4 - Prob. 12.39QAPCh. 12.4 - Prob. 12.40QAPCh. 12.4 - Prob. 12.41QAPCh. 12.4 - Prob. 12.42QAPCh. 12.4 - Prob. 12.43QAPCh. 12.4 - Prob. 12.44QAPCh. 12.4 - Prob. 12.45QAPCh. 12.4 - Prob. 12.46QAPCh. 12.4 - Prob. 12.47QAPCh. 12.4 - Prob. 12.48QAPCh. 12.4 - Prob. 12.49QAPCh. 12.4 - Prob. 12.50QAPCh. 12.5 - To make tomato soup, you add one can of water to...Ch. 12.5 - Prob. 12.52QAPCh. 12.5 - Prob. 12.53QAPCh. 12.5 - Prob. 12.54QAPCh. 12.5 - Prob. 12.55QAPCh. 12.5 - Prob. 12.56QAPCh. 12.5 - Prob. 12.57QAPCh. 12.5 - Prob. 12.58QAPCh. 12.5 - Prob. 12.59QAPCh. 12.5 - Prob. 12.60QAPCh. 12.6 - Prob. 12.61QAPCh. 12.6 - Prob. 12.62QAPCh. 12.6 - Prob. 12.63QAPCh. 12.6 - Prob. 12.64QAPCh. 12.6 - Prob. 12.65QAPCh. 12.6 - Prob. 12.66QAPCh. 12.7 - Prob. 12.67QAPCh. 12.7 - Prob. 12.68QAPCh. 12.7 - In each pair, identify the solution that will have...Ch. 12.7 - Prob. 12.70QAPCh. 12.7 - Prob. 12.71QAPCh. 12.7 - Prob. 12.72QAPCh. 12.7 - Prob. 12.73QAPCh. 12.7 - Prob. 12.74QAPCh. 12.8 - A 10% (m/v)starch solution is separated from a 1%...Ch. 12.8 - Prob. 12.76QAPCh. 12.8 - Prob. 12.77QAPCh. 12.8 - Prob. 12.78QAPCh. 12.8 - Prob. 12.79QAPCh. 12.8 - Prob. 12.80QAPCh. 12.8 - Each of the following mixtures is placed in a...Ch. 12.8 - Prob. 12.82QAPCh. 12 - Prob. 12.83FUCh. 12 - Prob. 12.84FUCh. 12 - Prob. 12.85FUCh. 12 - Prob. 12.86FUCh. 12 - Prob. 12.87UTCCh. 12 - Prob. 12.88UTCCh. 12 - Prob. 12.89UTCCh. 12 - Prob. 12.90UTCCh. 12 - Prob. 12.91UTCCh. 12 - Prob. 12.92UTCCh. 12 - Prob. 12.93UTCCh. 12 - Prob. 12.94UTCCh. 12 - Prob. 12.95UTCCh. 12 - Prob. 12.96UTCCh. 12 - Prob. 12.97AQAPCh. 12 - Prob. 12.98AQAPCh. 12 - Prob. 12.99AQAPCh. 12 - Prob. 12.100AQAPCh. 12 - Prob. 12.101AQAPCh. 12 - Prob. 12.102AQAPCh. 12 - Prob. 12.103AQAPCh. 12 - Prob. 12.104AQAPCh. 12 - If NaCl has a solubility of 36.0 g in 100. g of...Ch. 12 - Prob. 12.106AQAPCh. 12 - Prob. 12.107AQAPCh. 12 - Prob. 12.108AQAPCh. 12 - Prob. 12.109AQAPCh. 12 - Prob. 12.110AQAPCh. 12 - Prob. 12.111AQAPCh. 12 - Prob. 12.112AQAPCh. 12 - Prob. 12.113AQAPCh. 12 - What is the molarity of a solution containing 15.6...Ch. 12 - Prob. 12.115AQAPCh. 12 - Prob. 12.116AQAPCh. 12 - Prob. 12.117AQAPCh. 12 - Prob. 12.118AQAPCh. 12 - Prob. 12.119AQAPCh. 12 - Prob. 12.120AQAPCh. 12 - Prob. 12.121AQAPCh. 12 - Prob. 12.122AQAPCh. 12 - Prob. 12.123AQAPCh. 12 - Prob. 12.124AQAPCh. 12 - Prob. 12.125AQAPCh. 12 - Prob. 12.126AQAPCh. 12 - Prob. 12.127AQAPCh. 12 - Cadmium reacts with HCl to produce hydrogen gas...Ch. 12 - Prob. 12.129AQAPCh. 12 - Calculate the boiling point of each of the...Ch. 12 - Prob. 12.131AQAPCh. 12 - Prob. 12.132AQAPCh. 12 - Prob. 12.133CQCh. 12 - Write the net ionic equation to show the formation...Ch. 12 - Prob. 12.135CQCh. 12 - Prob. 12.136CQCh. 12 - Prob. 12.137CQCh. 12 - Prob. 12.138CQCh. 12 - Prob. 12.139CQCh. 12 - 9.134 A solution is prepared by dissolving 22.0 g...Ch. 12 - Prob. 12.141CQCh. 12 - Prob. 12.142CQCh. 12 - Prob. 12.143CQCh. 12 - Prob. 12.144CQCh. 12 - Prob. 12.145CQCh. 12 - Prob. 12.146CQ
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY