IUPAC nomenclature for the given compound has to be given. Concept Introduction: A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary. IUPAC rules for naming alcohols: Alcohols are named by identifying the parent compound and replacing the –e ending with –ol . Lowest possible number should be given for the hydroxyl group present in the parent chain. Name and number all substituent, and put them as prefixes to “ alkanol ” name also give the first preference as per the alphabetical order. If an alcohol contains two hydroxyl groups then name it as diol , an alcohol; contains three hydroxyl groups then name it as triol . Common names for alcohols are derived from alkyl group corresponding to the parent compound.

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Answer 1

Question

Chapter 12.2, Problem 12.2PP

(a)

Interpretation Introduction

Interpretation:

IUPAC nomenclature for the given compound has to be given.

Concept Introduction:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

IUPAC rules for naming alcohols:

Alcohols are named by identifying the parent compound and replacing the –e ending with –ol.

Lowest possible number should be given for the hydroxyl group present in the parent chain.

Name and number all substituent, and put them as prefixes to “alkanol” name also give the first preference as per the alphabetical order.

If an alcohol contains two hydroxyl groups then name it as diol, an alcohol; contains three hydroxyl groups then name it as triol.

Common names for alcohols are derived from alkyl group corresponding to the parent compound.

(b)

Interpretation Introduction

Interpretation:

IUPAC nomenclature for the given compound has to be given.

Concept Introduction:

Refer part (a).

(c)

Interpretation Introduction

Interpretation:

IUPAC nomenclature for the given compound glycerol has to be given.

Concept Introduction:

Refer part (a).

(d)

Interpretation Introduction

Interpretation:

IUPAC nomenclature for the given compound has to be given.

Concept Introduction:

Refer part (a).

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1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)

19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+

Li+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiCl

Answer 2

Question

Chapter 12.2, Problem 12.2PP

(a)

Interpretation Introduction

Interpretation:

IUPAC nomenclature for the given compound has to be given.

Concept Introduction:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

IUPAC rules for naming alcohols:

Alcohols are named by identifying the parent compound and replacing the –e ending with –ol.

Lowest possible number should be given for the hydroxyl group present in the parent chain.

Name and number all substituent, and put them as prefixes to “alkanol” name also give the first preference as per the alphabetical order.

If an alcohol contains two hydroxyl groups then name it as diol, an alcohol; contains three hydroxyl groups then name it as triol.

Common names for alcohols are derived from alkyl group corresponding to the parent compound.

(b)

Interpretation Introduction

Interpretation:

IUPAC nomenclature for the given compound has to be given.

Concept Introduction:

Refer part (a).

(c)

Interpretation Introduction

Interpretation:

IUPAC nomenclature for the given compound glycerol has to be given.

Concept Introduction:

Refer part (a).

(d)

Interpretation Introduction

Interpretation:

IUPAC nomenclature for the given compound has to be given.

Concept Introduction:

Refer part (a).

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Answer 3

Question

Chapter 12.2, Problem 12.2PP

(a)

Interpretation Introduction

Interpretation:

IUPAC nomenclature for the given compound has to be given.

Concept Introduction:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

IUPAC rules for naming alcohols:

Alcohols are named by identifying the parent compound and replacing the –e ending with –ol.

Lowest possible number should be given for the hydroxyl group present in the parent chain.

Name and number all substituent, and put them as prefixes to “alkanol” name also give the first preference as per the alphabetical order.

If an alcohol contains two hydroxyl groups then name it as diol, an alcohol; contains three hydroxyl groups then name it as triol.

Common names for alcohols are derived from alkyl group corresponding to the parent compound.

(b)

Interpretation Introduction

Interpretation:

IUPAC nomenclature for the given compound has to be given.

Concept Introduction:

Refer part (a).

(c)

Interpretation Introduction

Interpretation:

IUPAC nomenclature for the given compound glycerol has to be given.

Concept Introduction:

Refer part (a).

(d)

Interpretation Introduction

Interpretation:

IUPAC nomenclature for the given compound has to be given.

Concept Introduction:

Refer part (a).

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Answer 4

Question

Chapter 12.2, Problem 12.2PP

(a)

Interpretation Introduction

Interpretation:

IUPAC nomenclature for the given compound has to be given.

Concept Introduction:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

IUPAC rules for naming alcohols:

Alcohols are named by identifying the parent compound and replacing the –e ending with –ol.

Lowest possible number should be given for the hydroxyl group present in the parent chain.

Name and number all substituent, and put them as prefixes to “alkanol” name also give the first preference as per the alphabetical order.

If an alcohol contains two hydroxyl groups then name it as diol, an alcohol; contains three hydroxyl groups then name it as triol.

Common names for alcohols are derived from alkyl group corresponding to the parent compound.

(b)

Interpretation Introduction

Interpretation:

IUPAC nomenclature for the given compound has to be given.

Concept Introduction:

Refer part (a).

(c)

Interpretation Introduction

Interpretation:

IUPAC nomenclature for the given compound glycerol has to be given.

Concept Introduction:

Refer part (a).

(d)

Interpretation Introduction

Interpretation:

IUPAC nomenclature for the given compound has to be given.

Concept Introduction:

Refer part (a).

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Answer 5

Chapter 12.2, Problem 12.2PP

(a)

Interpretation Introduction

Interpretation:

IUPAC nomenclature for the given compound has to be given.

Concept Introduction:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

IUPAC rules for naming alcohols:

Alcohols are named by identifying the parent compound and replacing the –e ending with –ol.

Lowest possible number should be given for the hydroxyl group present in the parent chain.

Name and number all substituent, and put them as prefixes to “alkanol” name also give the first preference as per the alphabetical order.

If an alcohol contains two hydroxyl groups then name it as diol, an alcohol; contains three hydroxyl groups then name it as triol.

Common names for alcohols are derived from alkyl group corresponding to the parent compound.

(b)

Interpretation Introduction

Interpretation:

IUPAC nomenclature for the given compound has to be given.

Concept Introduction:

Refer part (a).

(c)

Interpretation Introduction

Interpretation:

IUPAC nomenclature for the given compound glycerol has to be given.

Concept Introduction:

Refer part (a).

(d)

Interpretation Introduction

Interpretation:

IUPAC nomenclature for the given compound has to be given.

Concept Introduction:

Refer part (a).

Answer 6

Chapter 12.2, Problem 12.2PP

(a)

Interpretation Introduction

Interpretation:

IUPAC nomenclature for the given compound has to be given.

Concept Introduction:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

IUPAC rules for naming alcohols:

Alcohols are named by identifying the parent compound and replacing the –e ending with –ol.

Lowest possible number should be given for the hydroxyl group present in the parent chain.

Name and number all substituent, and put them as prefixes to “alkanol” name also give the first preference as per the alphabetical order.

If an alcohol contains two hydroxyl groups then name it as diol, an alcohol; contains three hydroxyl groups then name it as triol.

Common names for alcohols are derived from alkyl group corresponding to the parent compound.

Answer 7

Chapter 12.2, Problem 12.2PP

(a)

Interpretation Introduction

Interpretation:

IUPAC nomenclature for the given compound has to be given.

Concept Introduction:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

IUPAC rules for naming alcohols:

Alcohols are named by identifying the parent compound and replacing the –e ending with –ol.

Lowest possible number should be given for the hydroxyl group present in the parent chain.

Name and number all substituent, and put them as prefixes to “alkanol” name also give the first preference as per the alphabetical order.

If an alcohol contains two hydroxyl groups then name it as diol, an alcohol; contains three hydroxyl groups then name it as triol.

Common names for alcohols are derived from alkyl group corresponding to the parent compound.

Answer 8

(b)

Interpretation Introduction

Interpretation:

IUPAC nomenclature for the given compound has to be given.

Concept Introduction:

Refer part (a).

Answer 9

(b)

Interpretation Introduction

Interpretation:

IUPAC nomenclature for the given compound has to be given.

Concept Introduction:

Refer part (a).

Answer 10

(c)

Interpretation Introduction

Interpretation:

IUPAC nomenclature for the given compound glycerol has to be given.

Concept Introduction:

Refer part (a).

Answer 11

(c)

Interpretation Introduction

Interpretation:

IUPAC nomenclature for the given compound glycerol has to be given.

Concept Introduction:

Refer part (a).

Answer 12

(d)

Interpretation Introduction

Interpretation:

IUPAC nomenclature for the given compound has to be given.

Concept Introduction:

Refer part (a).

Answer 13

(d)

Interpretation Introduction

Interpretation:

IUPAC nomenclature for the given compound has to be given.

Concept Introduction:

Refer part (a).

Answer 14

Expert Solution & Answer

Answer 15

Expert Solution & Answer

Answer 16

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Answer 17

Ch. 12.1 - Prob. 12.1PP Ch. 12.2 - Prob. 12.2PP Ch. 12.2 - Prob. 12.3PP Ch. 12.2 - Prob. 12.1Q Ch. 12.2 - Prob. 12.2Q Ch. 12.4 - Write an equation representing the reduction of...Ch. 12.4 - Write an equation representing the reduction of...Ch. 12.4 - Prob. 12.6PP Ch. 12.4 - Prob. 12.7PP Ch. 12.4 - Prob. 12.8PP

Concept explainers

Interpretation:

IUPAC nomenclature for the given compound has to be given.

Concept Introduction:

Refer part (a).

Interpretation:

IUPAC nomenclature for the given compound glycerol has to be given.

Concept Introduction:

Refer part (a).

Interpretation:

IUPAC nomenclature for the given compound has to be given.

Concept Introduction:

Refer part (a).

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Chapter 12 Solutions

Concept explainers

Interpretation: IUPAC nomenclature for the given compound has to be given. Concept Introduction: Refer part (a).

Interpretation: IUPAC nomenclature for the given compound glycerol has to be given. Concept Introduction: Refer part (a).

Interpretation: IUPAC nomenclature for the given compound has to be given. Concept Introduction: Refer part (a).

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Chapter 12 Solutions

Interpretation:

IUPAC nomenclature for the given compound has to be given.

Concept Introduction:

Refer part (a).

Interpretation:

IUPAC nomenclature for the given compound glycerol has to be given.

Concept Introduction:

Refer part (a).

Interpretation:

IUPAC nomenclature for the given compound has to be given.

Concept Introduction:

Refer part (a).