The reagents that will aid in the transformation of the following compound is to be determined. Concept introduction : The final product contains two more carbon atoms than the starting material. This can be achieved by using a Grignard reagent to add the ethyl fragment. The compound will then be oxidized using a suitable oxidizing reagent to yield the desired product.

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 12.13, Problem 26CC

(a)

Interpretation Introduction

Interpretation: The reagents that will aid in the transformation of the following compound is to be determined.

Concept introduction: The final product contains two more carbon atoms than the starting material. This can be achieved by using a Grignard reagent to add the ethyl fragment. The compound will then be oxidized using a suitable oxidizing reagent to yield the desired product.

(b)

Interpretation Introduction

Interpretation: The reagents required for the transformation of the following compound are to be determined.

Concept introduction: The final product has one more carbon atom than the starting material. By using a suitable Grignard reagent, a substituted alcohol is formed. This alcohol can be oxidized using a suitable oxidizing agent to yield the desired ketone product.

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2. Name the following hydrocarbons. (9 marks) a) HHHHHHHH H-C-C- H-O-S b) HCEC-CH3 H H H H H d) c) H C=C- H H H e) CH3 CH3 CH2CH=CH-CH=CHCH3 HHHH H-C-C-C-C-H H HH H f) large CH2CH3 pola H3C section lovels tower, able ocart firs g) Tower H3C-CH2 then in H3C-CH-CH-CH3 enblbano bne noitsidab Copyright © 2008. Durham Continuing Education CH3

Name the molecules & Identify any chiral center CH3CH2CH2CHCH₂CH₂CH₂CH₂ OH CH₂CHCH2CH3 Br CH3 CH3CHCH2CHCH2CH3 CH3

Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electrons-pushing arrows for the following reaction or mechanistic step(s).

Answer 2

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 12.13, Problem 26CC

(a)

Interpretation Introduction

Interpretation: The reagents that will aid in the transformation of the following compound is to be determined.

Concept introduction: The final product contains two more carbon atoms than the starting material. This can be achieved by using a Grignard reagent to add the ethyl fragment. The compound will then be oxidized using a suitable oxidizing reagent to yield the desired product.

(b)

Interpretation Introduction

Interpretation: The reagents required for the transformation of the following compound are to be determined.

Concept introduction: The final product has one more carbon atom than the starting material. By using a suitable Grignard reagent, a substituted alcohol is formed. This alcohol can be oxidized using a suitable oxidizing agent to yield the desired ketone product.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 12.13, Problem 26CC

(a)

Interpretation Introduction

Interpretation: The reagents that will aid in the transformation of the following compound is to be determined.

Concept introduction: The final product contains two more carbon atoms than the starting material. This can be achieved by using a Grignard reagent to add the ethyl fragment. The compound will then be oxidized using a suitable oxidizing reagent to yield the desired product.

(b)

Interpretation Introduction

Interpretation: The reagents required for the transformation of the following compound are to be determined.

Concept introduction: The final product has one more carbon atom than the starting material. By using a suitable Grignard reagent, a substituted alcohol is formed. This alcohol can be oxidized using a suitable oxidizing agent to yield the desired ketone product.

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 12.13, Problem 26CC

(a)

Interpretation Introduction

Interpretation: The reagents that will aid in the transformation of the following compound is to be determined.

Concept introduction: The final product contains two more carbon atoms than the starting material. This can be achieved by using a Grignard reagent to add the ethyl fragment. The compound will then be oxidized using a suitable oxidizing reagent to yield the desired product.

(b)

Interpretation Introduction

Interpretation: The reagents required for the transformation of the following compound are to be determined.

Concept introduction: The final product has one more carbon atom than the starting material. By using a suitable Grignard reagent, a substituted alcohol is formed. This alcohol can be oxidized using a suitable oxidizing agent to yield the desired ketone product.

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Answer 5

Chapter 12.13, Problem 26CC

(a)

Interpretation Introduction

Interpretation: The reagents that will aid in the transformation of the following compound is to be determined.

Concept introduction: The final product contains two more carbon atoms than the starting material. This can be achieved by using a Grignard reagent to add the ethyl fragment. The compound will then be oxidized using a suitable oxidizing reagent to yield the desired product.

(b)

Interpretation Introduction

Interpretation: The reagents required for the transformation of the following compound are to be determined.

Concept introduction: The final product has one more carbon atom than the starting material. By using a suitable Grignard reagent, a substituted alcohol is formed. This alcohol can be oxidized using a suitable oxidizing agent to yield the desired ketone product.

Answer 6

Chapter 12.13, Problem 26CC

(a)

Interpretation Introduction

Interpretation: The reagents that will aid in the transformation of the following compound is to be determined.

Concept introduction: The final product contains two more carbon atoms than the starting material. This can be achieved by using a Grignard reagent to add the ethyl fragment. The compound will then be oxidized using a suitable oxidizing reagent to yield the desired product.

Answer 7

Chapter 12.13, Problem 26CC

(a)

Interpretation Introduction

Interpretation: The reagents that will aid in the transformation of the following compound is to be determined.

Concept introduction: The final product contains two more carbon atoms than the starting material. This can be achieved by using a Grignard reagent to add the ethyl fragment. The compound will then be oxidized using a suitable oxidizing reagent to yield the desired product.

Answer 8

(b)

Interpretation Introduction

Interpretation: The reagents required for the transformation of the following compound are to be determined.

Concept introduction: The final product has one more carbon atom than the starting material. By using a suitable Grignard reagent, a substituted alcohol is formed. This alcohol can be oxidized using a suitable oxidizing agent to yield the desired ketone product.

Answer 9

(b)

Interpretation Introduction

Interpretation: The reagents required for the transformation of the following compound are to be determined.

Concept introduction: The final product has one more carbon atom than the starting material. By using a suitable Grignard reagent, a substituted alcohol is formed. This alcohol can be oxidized using a suitable oxidizing agent to yield the desired ketone product.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 12.1 - Prob. 1LTS Ch. 12.1 - Prob. 1PTS Ch. 12.1 - Prob. 2ATS Ch. 12.1 - Prob. 3CC Ch. 12.2 - Prob. 4CC Ch. 12.3 - Prob. 8CC Ch. 12.3 - Prob. 9CC Ch. 12.4 - Prob. 3LTS Ch. 12.4 - Prob. 10PTS Ch. 12.4 - Prob. 11ATS

Solution Summary: The author explains the reagents required for the transformation of the following compound.

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