ORGANIC CHEMISTRY (LL) W/ACCESS
ORGANIC CHEMISTRY (LL) W/ACCESS
4th Edition
ISBN: 9781119856122
Author: Klein
Publisher: WILEY
Question
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Chapter 12, Problem 46PP

(a)

Interpretation Introduction

Interpretation: The reagent used in the given reaction is to be identified.

Concept introduction: Sodium dichromate (Na2Cr2O7) is used to oxidize secondary alcohols to ketones. It is a very strong oxidant.

(b)

Interpretation Introduction

Interpretation: The reagent used in the given reaction is to be identified.

Concept introduction: PCC oxidizes 1° alcohols into aldehydes and secondary alcohols into ketones. PCC does not convert aldehydes into carboxylic acids, in contrast to chromic acid.

(c)

Interpretation Introduction

Interpretation: The reagent used in the given reaction is to be identified.

Concept introduction: PCC oxidizes 1° alcohols into aldehydes and secondary alcohols into ketones. PCC does not convert aldehydes into carboxylic acids, in contrast to chromic acid.

(d)

Interpretation Introduction

Interpretation: The reagent used in the given reaction is to be identified.

Concept introduction: Sodium dichromate (Na2Cr2O7) is a chromic acid reagent, used to oxidize secondary alcohols to ketones. It is a very strong oxidant.

(e)

Interpretation Introduction

Interpretation: The reagent used in the given reaction is to be identified.

Concept introduction: With the aid of reagents like sodium borohydride or lithium aluminum hydride, aldehydes and ketones can undergo a reduction process to produce either primary alcohol or secondary alcohol.

(f)

Interpretation Introduction

Interpretation: The reagent used in the given reaction is to be identified.

Concept introduction:

With the aid of reagents like sodium borohydride or lithium aluminum hydride, aldehydes and ketones can undergo a reduction process to produce either primary alcohol or secondary alcohol.

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