EP CHEMISTRY:CENTRAL..-MOD.MASTERING
14th Edition
ISBN: 9780136781509
Author: Brown
Publisher: PEARSON CO
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Chapter 12, Problem 95E
Explain why “bands” may not be the most accurate description of bonding in a solid when the solid has nanoscale dimensions.
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(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to
glucose, C6H12O6, and fructose C6H12O6, in acidic solution:
C12H22O11 + H2O → C6H12O6 + C6H12O6
[sucrose]/mol dm³
t/min
0
0.316
14
0.300
39
0.274
60
0.256
80
0.238
110
0.211
(i) Graphically prove the order of the reaction and determine the rate constant of the
reaction.
(ii) Determine the half-life, t½ for the hydrolysis of sucrose.
(III) adsorbent
(b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous
solution was examined. The adsorption was modelled using a modified Langmuir
isotherm, yielding the following values of Kat pH = 6.5:
(ii)
T/K
10-10 K
280
2.505
295
1.819
310
1.364
325
1.050
Determine the enthalpy of adsorption, AadsHⓇ.
If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above
conditions, determine Aads Gº.
with full details solution please
Chapter 12 Solutions
EP CHEMISTRY:CENTRAL..-MOD.MASTERING
Ch. 12.3 - Consider the two-dimensional square lattice of...Ch. 12.3 - Prob. 12.1.2PECh. 12.5 - Given the ionic radii and molar masses of Sc3+...Ch. 12.5 - Prob. 12.2.2PECh. 12.7 - Prob. 12.3.1PECh. 12.7 - Prob. 12.3.2PECh. 12.7 - Prob. 12.4.1PECh. 12.7 - Prob. 12.4.2PECh. 12 - Prob. 1DECh. 12 - Prob. 1E
Ch. 12 - Prob. 2ECh. 12 - Prob. 3ECh. 12 - Prob. 4ECh. 12 - Prob. 5ECh. 12 - Prob. 6ECh. 12 - Prob. 7ECh. 12 - Prob. 8ECh. 12 - Prob. 9ECh. 12 - Prob. 10ECh. 12 - 12.11 Covalent bonding occurs in both molecular...Ch. 12 - Prob. 12ECh. 12 - 12.13 What kinds of attractive forces exist...Ch. 12 - Prob. 14ECh. 12 - Prob. 15ECh. 12 - Prob. 16ECh. 12 - Prob. 17ECh. 12 - Prob. 18ECh. 12 - Prob. 19ECh. 12 - Amorphous silica, SiO2, has a density of about...Ch. 12 - Two patterns of packing for two different circles...Ch. 12 - Prob. 22ECh. 12 - Prob. 23ECh. 12 - Prob. 24ECh. 12 - Which of the three-dimensional primitive lattices...Ch. 12 - Prob. 26ECh. 12 - 12.27 What is the minimum number of atoms that...Ch. 12 - 12.28 What is the minimum number of atoms that...Ch. 12 - Prob. 29ECh. 12 - Prob. 30ECh. 12 - Prob. 31ECh. 12 - Prob. 32ECh. 12 - Prob. 33ECh. 12 - Prob. 34ECh. 12 - Prob. 35ECh. 12 - Prob. 36ECh. 12 - Prob. 37ECh. 12 - Prob. 38ECh. 12 - Prob. 39ECh. 12 - Prob. 40ECh. 12 - Prob. 41ECh. 12 - Prob. 42ECh. 12 - Prob. 43ECh. 12 - Prob. 44ECh. 12 - Prob. 45ECh. 12 - Prob. 46ECh. 12 - Prob. 47ECh. 12 - Prob. 48ECh. 12 - Prob. 49ECh. 12 - Prob. 50ECh. 12 - Prob. 51ECh. 12 - Prob. 52ECh. 12 - 12.53 Which would you expect to be the more...Ch. 12 - 12.54 Which of the following statements does not...Ch. 12 - Prob. 55ECh. 12 - Prob. 56ECh. 12 - Prob. 57ECh. 12 - Prob. 58ECh. 12 - Prob. 59ECh. 12 - Prob. 60ECh. 12 - 12.61 A particular form of cinnabar (HgS) adopts...Ch. 12 - At room temperature and pressure RbI crystallizes...Ch. 12 - Prob. 63ECh. 12 - Prob. 64ECh. 12 - The coordination number for Mg2+ ion is usually...Ch. 12 - Prob. 66ECh. 12 - Prob. 67ECh. 12 - Prob. 68ECh. 12 - Prob. 69ECh. 12 - Prob. 70ECh. 12 - Prob. 71ECh. 12 - Prob. 72ECh. 12 - Prob. 73ECh. 12 - Prob. 74ECh. 12 - Prob. 75ECh. 12 - Prob. 76ECh. 12 - Prob. 77ECh. 12 - Prob. 78ECh. 12 - Prob. 79ECh. 12 - Prob. 80ECh. 12 - Prob. 81ECh. 12 - Prob. 82ECh. 12 - Prob. 83ECh. 12 - Prob. 84ECh. 12 - Prob. 85ECh. 12 - 12.86 Write a balanced chemical equation for the...Ch. 12 - Prob. 87ECh. 12 - Prob. 88ECh. 12 - Prob. 89ECh. 12 - Prob. 90ECh. 12 - Prob. 91ECh. 12 - Prob. 92ECh. 12 - Prob. 93ECh. 12 - Prob. 94ECh. 12 - Explain why “bands” may not be the most accurate...Ch. 12 - Prob. 96ECh. 12 - Prob. 97ECh. 12 - Prob. 98ECh. 12 - Prob. 99ECh. 12 - An ideal quantum dot for use in TVs does not...Ch. 12 - Prob. 101ECh. 12 - Prob. 102ECh. 12 - Prob. 103AECh. 12 - Prob. 104AECh. 12 - Prob. 105AECh. 12 - Pure iron crystallizes in a body-centered cubic...Ch. 12 - Prob. 107AECh. 12 - Prob. 108AECh. 12 - Prob. 109AECh. 12 - What type of latticeprimitive cubic, body-centered...Ch. 12 - Prob. 111AECh. 12 - Prob. 112AECh. 12 - Prob. 113AECh. 12 - Energy bands are considered continuous due to the...Ch. 12 - Prob. 115AECh. 12 - Prob. 116AECh. 12 - Prob. 117AECh. 12 - Prob. 118AECh. 12 - Prob. 119AECh. 12 - Prob. 120AECh. 12 - Prob. 121AECh. 12 - Prob. 122AECh. 12 - Prob. 123AECh. 12 - The karat scale used to describe gold alloys is...Ch. 12 - 12.125 Spinel is a mineral that contains 37.9% AI,...Ch. 12 - Prob. 126IECh. 12 - Prob. 127IECh. 12 - Prob. 128IECh. 12 - Prob. 129IECh. 12 - Silicon has the diamond structure with a unit cell...Ch. 12 - Prob. 131IECh. 12 - Prob. 132IE
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