Chemistry: A Molecular Approach & Student Solutions Manual for Chemistry: A Molecular Approach, Books a la Carte Edition Package
1st Edition
ISBN: 9780321955517
Author: Nivaldo J. Tro
Publisher: PEARSON
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Question
Chapter 12, Problem 7SAQ
Interpretation Introduction
To determine: Vapor pressure of aqueous ethylene glycol.
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Consider the reaction of a propanoate ester with hydroxide ion shown below. A
series of four alcohol leaving groups were tested to determine which would be the
best leaving group.
Based on the pKa values of the alcohols, predict which alcohol would produce the
fastest hydrolysis reaction.
HO
FOR
A
Alcohol I, pKa =16.0
B
Alcohol II, pKa =10.0
C
Alcohol III, pKa = 7.2
+ ROH
D
Alcohol IV, pKa = 6.6
Curved arrows are used to illustrate the flow of electrons. Using
the provided starting and product structures, draw the curved
electron-pushing arrows for the following reaction or
mechanistic step(s).
Be sure to account for all bond-breaking and bond-making
steps.
:0:
NaOH, H₂O
00:4
Na O
heat
NaO
Select to Add Arrows
Select to Add Arrows
:0:
Na
a
NaOH, H2O
:0:
NaOH,
H2O
heat
heat
Na
ONH
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Curved arrows are used to illustrate the flow of electrons. Using
the provided starting and product structures, draw the curved
electron-pushing arrows for the following reaction or
mechanistic step(s).
Be sure to account for all bond-breaking and bond-making
steps.
H
CH3NH3+
:0:
:0:
HO
CH3NH2
HH
iSelect to Add Arrows i
Select to Add Arrows i
HH
CH3NH3+
CH3NH2
Select to Add Arrows i
CH3NH3
CH3NH2
ايكدا
HH
Select to Add Arrows
Chapter 12 Solutions
Chemistry: A Molecular Approach & Student Solutions Manual for Chemistry: A Molecular Approach, Books a la Carte Edition Package
Ch. 12 - Prob. 1SAQCh. 12 - Prob. 2SAQCh. 12 - Q3. A 500.0-mL sample of pure water is allowed to...Ch. 12 - Q4. A potassium bromide solution is 7.55 %...Ch. 12 - Prob. 5SAQCh. 12 - Prob. 6SAQCh. 12 - Prob. 7SAQCh. 12 - Prob. 8SAQCh. 12 - Prob. 9SAQCh. 12 - Prob. 10SAQ
Ch. 12 - Prob. 11SAQCh. 12 - Q12. The enthalpy of solution for NaOH is –44.46...Ch. 12 - Q13. A 2.4 m aqueous solution of an ionic compound...Ch. 12 - Q14. A solution is an equimolar mixture of two...Ch. 12 - Prob. 15SAQCh. 12 - Prob. 1ECh. 12 - Prob. 2ECh. 12 - Prob. 3ECh. 12 - Prob. 4ECh. 12 - Prob. 5ECh. 12 - Prob. 6ECh. 12 - Prob. 7ECh. 12 - Prob. 8ECh. 12 - Prob. 9ECh. 12 - 10. What is the heat of hydration (ΔHhydration)?...Ch. 12 - Prob. 11ECh. 12 - Prob. 12ECh. 12 - Prob. 13ECh. 12 - Prob. 14ECh. 12 - Prob. 15ECh. 12 - Prob. 16ECh. 12 - Prob. 17ECh. 12 - Prob. 18ECh. 12 - Prob. 19ECh. 12 - Prob. 20ECh. 12 - Prob. 21ECh. 12 - 22. Explain why the lower vapor pressure for a...Ch. 12 - Prob. 23ECh. 12 - Prob. 24ECh. 12 - Prob. 25ECh. 12 - Prob. 26ECh. 12 - Prob. 27ECh. 12 - Prob. 28ECh. 12 - Prob. 29ECh. 12 - 30. Pick an appropriate solvent from Table 13.3 to...Ch. 12 - 31. Which molecule would you expect to be more...Ch. 12 - 32. Which molecule would you expect to be more...Ch. 12 - Prob. 33ECh. 12 - Prob. 34ECh. 12 - 35. When ammonium chloride (NH4Cl) is dissolved in...Ch. 12 - 36. When lithium iodide (LiI) is dissolved in...Ch. 12 - Silver nitrate has a lattice energy of 820 kJ/mol...Ch. 12 - Prob. 38ECh. 12 - Prob. 39ECh. 12 - Prob. 40ECh. 12 - Prob. 41ECh. 12 - 42. A solution contains 32 g of KNO3 per 100.0 g...Ch. 12 - Prob. 43ECh. 12 - Prob. 44ECh. 12 - Prob. 45ECh. 12 - Prob. 46ECh. 12 - Prob. 47ECh. 12 - Prob. 48ECh. 12 - Prob. 49ECh. 12 - Prob. 50ECh. 12 - Prob. 51ECh. 12 - Prob. 52ECh. 12 - Prob. 53ECh. 12 - Prob. 54ECh. 12 - 55. Silver nitrate solutions are often used to...Ch. 12 - Prob. 56ECh. 12 - Prob. 57ECh. 12 - Prob. 58ECh. 12 - Prob. 59ECh. 12 - Prob. 60ECh. 12 - Prob. 61ECh. 12 - Prob. 62ECh. 12 - Prob. 63ECh. 12 - Prob. 64ECh. 12 - Prob. 65ECh. 12 - Prob. 66ECh. 12 - Prob. 67ECh. 12 - Prob. 68ECh. 12 - Prob. 69ECh. 12 - Prob. 70ECh. 12 - 71. Calculate the vapor pressure of a solution...Ch. 12 - Prob. 72ECh. 12 - 73. A solution contains 50.0 g of heptane (C7H16)...Ch. 12 - Prob. 74ECh. 12 - 75. A solution contains 4.08 g of chloroform...Ch. 12 - Prob. 76ECh. 12 - Prob. 77ECh. 12 - Prob. 78ECh. 12 - 79. Calculate the freezing point and boiling point...Ch. 12 - 80. Calculate the freezing point and boiling...Ch. 12 - 81. An aqueous solution containing 17.5 g of an...Ch. 12 - Prob. 82ECh. 12 - 83. Calculate the osmotic pressure of a solution...Ch. 12 - Prob. 84ECh. 12 - 85. A solution containing 27.55 mg of an unknown...Ch. 12 - Prob. 86ECh. 12 - 87. Calculate the freezing point and boiling point...Ch. 12 - Prob. 88ECh. 12 - Prob. 89ECh. 12 - Prob. 90ECh. 12 - Prob. 91ECh. 12 - Prob. 92ECh. 12 - Prob. 93ECh. 12 - Prob. 94ECh. 12 - 95. A 0.100 M ionic solution has an osmotic...Ch. 12 - Prob. 96ECh. 12 - 97. Calculate the vapor pressure at 25 °C of an...Ch. 12 - Prob. 98ECh. 12 - Prob. 99ECh. 12 - 100. The solubility of phenol in water at 25 °C is...Ch. 12 - Prob. 101ECh. 12 - Prob. 102ECh. 12 - Prob. 103ECh. 12 - Prob. 104ECh. 12 - Prob. 105ECh. 12 - Prob. 106ECh. 12 - Prob. 107ECh. 12 - 108. The vapor above an aqueous solution contains...Ch. 12 - Prob. 109ECh. 12 - Prob. 110ECh. 12 - Prob. 111ECh. 12 - Prob. 112ECh. 12 - Prob. 113ECh. 12 - Prob. 114ECh. 12 - Prob. 115ECh. 12 - Prob. 116ECh. 12 - Prob. 117ECh. 12 - Prob. 118ECh. 12 - Prob. 119ECh. 12 - Prob. 120ECh. 12 - Prob. 121ECh. 12 - Prob. 122ECh. 12 - 123. A 100.0-mL aqueous sodium chloride solution...Ch. 12 - Prob. 124ECh. 12 - Prob. 125ECh. 12 - Prob. 126ECh. 12 - 127. A 1.10-g sample contains only glucose...Ch. 12 - 128. A solution is prepared by mixing 631 mL of...Ch. 12 - 129. Two alcohols, isopropyl alcohol and propyl...Ch. 12 - Prob. 130ECh. 12 - Prob. 131ECh. 12 - 132. A solution of 75.0 g of benzene (C6H6) and...Ch. 12 - Prob. 133ECh. 12 - Prob. 134ECh. 12 - Prob. 135ECh. 12 - Prob. 136ECh. 12 - 137. If each substance listed here costs the same...Ch. 12 - Prob. 138E
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