Chemistry the Central Science 13th Edition Custom for Lamar University
13th Edition
ISBN: 9781269962667
Author: Theodore L. Brown, H. Eugene LeMay Jr., Bruce E. Bursten, Batherine J. Murphy, Patrick M. Woodward, Matthew W. Stoltzfus
Publisher: Pearson Learning Center
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Textbook Question
Chapter 12, Problem 56E
Clausthalite is a mineral composed of lead selenide (PbSe). The mineral adopts the rock salt structure. The density of PbSe at 25°C is
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19.78 Write the products of the following sequences of reactions. Refer to your reaction road-
maps to see how the combined reactions allow you to "navigate" between the different
functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18
roadmaps along with your new Chapter 19 roadmap for these.
(a)
1. BHS
2. H₂O₂
3. H₂CrO4
4. SOCI₂
(b)
1. Cl₂/hv
2. KOLBU
3. H₂O, catalytic H₂SO4
4. H₂CrO4
Reaction
Roadmap
An alkene 5. EtOH
6.0.5 Equiv. NaOEt/EtOH
7. Mild H₂O
An alkane
1.0
2. (CH3)₂S
3. H₂CrO
(d)
(c)
4. Excess EtOH, catalytic H₂SO
OH
4. Mild H₂O*
5.0.5 Equiv. NaOEt/EtOH
An alkene 6. Mild H₂O*
A carboxylic
acid
7. Mild H₂O*
1. SOC₁₂
2. EtOH
3.0.5 Equiv. NaOEt/E:OH
5.1.0 Equiv. NaOEt
6.
NH₂
(e)
1. 0.5 Equiv. NaOEt/EtOH
2. Mild H₂O*
Br
(f)
i
H
An aldehyde
1. Catalytic NaOE/EtOH
2. H₂O*, heat
3. (CH,CH₂)₂Culi
4. Mild H₂O*
5.1.0 Equiv. LDA
Br
An ester
4. NaOH, H₂O
5. Mild H₂O*
6. Heat
7.
MgBr
8. Mild H₂O*
7. Mild H₂O+
Li+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water?
Group of answer choices
LiBr
LiI
LiF
LiCl
Q4: Write organic product(s) of the following reactions and show the curved-arrow mechanism
of the reactions.
Br
MeOH
OSO2CH3
MeOH
Chapter 12 Solutions
Chemistry the Central Science 13th Edition Custom for Lamar University
Ch. 12.3 - The following diagram shows the combination...Ch. 12.3 -
3.3 The following diagram represents the...Ch. 12.5 -
3.4 The following diagram represents the...Ch. 12.5 - Glycine, an amino acid used by organisms to make...Ch. 12.7 - The following diagram represents a...Ch. 12.7 -
3.7 Nitrogen (N2) and hydrogen (H2) react to form...Ch. 12.7 -
3.8 Nitrogen monoxide and oxygen react to form...Ch. 12.7 - Write "true" or "false" for each statement. a. We...Ch. 12 - Determine the empirical and molecular formulas of...Ch. 12 - a. Combustion analysis of toluene, a common...
Ch. 12 -
3.67 Automotive air bags infilate when sodium...Ch. 12 - Prob. 3ECh. 12 - Prob. 4ECh. 12 -
12.5 Which of these molecular fragments would...Ch. 12 - Prob. 6ECh. 12 - Prob. 7ECh. 12 - Prob. 8ECh. 12 - Prob. 9ECh. 12 - Prob. 10ECh. 12 - Prob. 11ECh. 12 - Prob. 12ECh. 12 - 12.13 Indicate the type of solid (molecular,...Ch. 12 - Prob. 14ECh. 12 -
12.15 A white substance melts with some...Ch. 12 -
12.16 You are given a white substance that...Ch. 12 - Prob. 17ECh. 12 - Prob. 18ECh. 12 - Prob. 19ECh. 12 - Prob. 20ECh. 12 - Prob. 21ECh. 12 - Prob. 22ECh. 12 - Prob. 23ECh. 12 - Prob. 24ECh. 12 - Prob. 25ECh. 12 - Prob. 26ECh. 12 - Prob. 27ECh. 12 - Prob. 28ECh. 12 - Prob. 29ECh. 12 - Prob. 30ECh. 12 - Prob. 31ECh. 12 - Prob. 32ECh. 12 - Prob. 33ECh. 12 - Prob. 34ECh. 12 - Prob. 35ECh. 12 - Prob. 36ECh. 12 - Prob. 37ECh. 12 - Prob. 38ECh. 12 - Prob. 39ECh. 12 - Prob. 40ECh. 12 - Prob. 41ECh. 12 - Prob. 42ECh. 12 - Prob. 43ECh. 12 - Prob. 44ECh. 12 - Prob. 45ECh. 12 - Prob. 46ECh. 12 - Prob. 47ECh. 12 - Prob. 48ECh. 12 -
12.49 Which would you expect to be the more...Ch. 12 - Prob. 50ECh. 12 - Prob. 51ECh. 12 - Prob. 52ECh. 12 - Prob. 53ECh. 12 - Prob. 54ECh. 12 - Prob. 55ECh. 12 - Clausthalite is a mineral composed of lead...Ch. 12 - Prob. 57ECh. 12 - Prob. 58ECh. 12 - Prob. 59ECh. 12 - Prob. 60ECh. 12 - Prob. 61ECh. 12 - Prob. 62ECh. 12 - Prob. 63ECh. 12 - Prob. 64ECh. 12 - Prob. 65ECh. 12 - Prob. 66ECh. 12 - Prob. 67ECh. 12 - Prob. 68ECh. 12 - Prob. 69ECh. 12 - Prob. 70ECh. 12 - Prob. 71ECh. 12 - Prob. 72ECh. 12 - Prob. 73ECh. 12 - Prob. 74ECh. 12 - Prob. 75ECh. 12 - Prob. 76ECh. 12 - Prob. 77ECh. 12 - Prob. 78ECh. 12 - Prob. 79ECh. 12 - Prob. 80ECh. 12 - Prob. 81ECh. 12 - Prob. 82ECh. 12 - Prob. 83ECh. 12 - Prob. 84ECh. 12 - Prob. 85ECh. 12 - Prob. 86ECh. 12 - Prob. 87ECh. 12 - Prob. 88ECh. 12 - Prob. 89ECh. 12 - Prob. 90ECh. 12 - Prob. 91ECh. 12 - Prob. 92ECh. 12 - Prob. 93ECh. 12 - Prob. 94ECh. 12 - Prob. 95ECh. 12 - Prob. 96ECh. 12 - Prob. 97ECh. 12 - Prob. 98ECh. 12 - Prob. 99AECh. 12 - Prob. 100AECh. 12 - Prob. 101AECh. 12 - Prob. 102AECh. 12 - Prob. 103AECh. 12 - What type of lattice—primitive cubic body-centered...Ch. 12 - Prob. 105AECh. 12 - Prob. 106AECh. 12 - Prob. 107AECh. 12 - Prob. 108AECh. 12 - Prob. 109AECh. 12 - Prob. 110AECh. 12 - Prob. 111AECh. 12 - Prob. 112AECh. 12 - Prob. 113AECh. 12 - 12.114 Germanium has the same structure as...Ch. 12 - Prob. 115AECh. 12 - Prob. 116AECh. 12 - The karat scale used to describe gold alloys is...Ch. 12 - Prob. 118IECh. 12 - Prob. 119IECh. 12 - Prob. 120IECh. 12 - Prob. 121IECh. 12 - Prob. 122IECh. 12 - Prob. 123IECh. 12 - Prob. 124IECh. 12 - Prob. 125IE
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