ORGANIC CHEMISTRY(EBOOK)-W/WILEYPLUS
ORGANIC CHEMISTRY(EBOOK)-W/WILEYPLUS
4th Edition
ISBN: 9781119830474
Author: Klein
Publisher: WILEY
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Chapter 12, Problem 55ASP
Interpretation Introduction

Interpretation:

The major product that would give the above reduction reaction is to be determined.

Concept introduction:

The reduction reaction is the addition of the hydrogen atom so only the carbonyl group would be converted to alcohol with the reagent NaBH4 . This is because NaBH4 is a mild reducing agent therefore it cannot reduce ester and can only reduce aldehyde and ketone, functional groups.

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When an unknown amine reacts with an unknown acid chloride, an amide with a molecular mass of 163 g/mol (M* = 163 m/z) is formed. In the infrared spectrum, important absorptions appear at 1661, 750 and 690 cm. The 13C NMR and DEPT spectra are provided. Draw the structure of the product as the resonance contributor lacking any formal charges. 13C NMR DEPT 90 200 160 120 80 40 0 200 160 120 80 40 0 DEPT 135 T 200 160 120 80 40 0 Draw the unknown amide. Select Dow Templates More Frage
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