(a) Interpretation: The species that is larger between the given pair is to be predicted and an explanation for the correct choice is to be stated. Concept Introduction: Compounds formed from ions are known as ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion. Cations are always smaller than the atoms from which they are formed because they have lesser number of electrons than the parent atom due to which the force of attraction between protons and electrons increases size decreases. Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electrons increases, the force of attraction between protons and electrons, decreases, and the size increases.

Question

Consider the following nucleophilic substitution reaction. The compound listed above the arrow is the solvent for the reaction. If nothing is listed over the arrow, then the nucleophile is also the solvent for the reaction. Part 1 of 2 Br CH,CN + I¯ What is the correct mechanism for the reaction? Select the single best answer. @SN2 ○ SN 1 Part: 1/2 Part 2 of 2 Draw the products for the reaction. Include both the major organic product and the inorganic product. If more than one stereoisomer is possible, draw only one stereoisomer. Include stereochemistry where relevant. Click and drag to start drawing a structure. X હૈ

Answer 1

Question

Chapter 12, Problem 46QAP

Interpretation Introduction

(a)

Interpretation:

The species that is larger between the given pair is to be predicted and an explanation for the correct choice is to be stated.

Concept Introduction:

Compounds formed from ions are known as ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have lesser number of electrons than the parent atom due to which the force of attraction between protons and electrons increases size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electrons increases, the force of attraction between protons and electrons, decreases, and the size increases.

Interpretation Introduction

(b)

Interpretation:

The species that is larger between the given pair is to be predicted and explanation for the correct choice is to be stated.

Concept Introduction:

Compounds formed from ions are known as ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have lesser number of electrons than the parent atom due to which the force of attraction between protons and electrons increases size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electrons increases, the force of attraction between protons and electrons, decreases, and the size increases.

Interpretation Introduction

(c)

Interpretation:

The species that is larger between the given pair is to be predicted and explanation for the correct choice is to be stated.

Concept Introduction:

Compounds formed from ions are known as ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have lesser number of electrons than the parent atom due to which the force of attraction between protons and electrons increases size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electrons increases, the force of attraction between protons and electrons, decreases, and the size increases.

Interpretation Introduction

(d)

Interpretation:

The species that is larger between the given pair is to be predicted and explanation for the correct choice is to be stated.

Concept Introduction:

Compounds formed from ions are known as ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have lesser number of electrons than the parent atom due to which the force of attraction between protons and electrons increases size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electrons increases, the force of attraction between protons and electrons, decreases, and the size increases.

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Consider the following nucleophilic substitution reaction. The compound listed above the arrow is the solvent for the reaction. If nothing is listed over the arrow, then the nucleophile is also the solvent for the reaction. Part 1 of 2 Br CH,CN + I¯ What is the correct mechanism for the reaction? Select the single best answer. @SN2 ○ SN 1 Part: 1/2 Part 2 of 2 Draw the products for the reaction. Include both the major organic product and the inorganic product. If more than one stereoisomer is possible, draw only one stereoisomer. Include stereochemistry where relevant. Click and drag to start drawing a structure. X હૈ

20.33 Think-Pair-Share (a) Rank the following dienes and dienophiles in order of increasing reactivity in the Diels-Alder reaction. (i) CO₂Et (ii) COEt || CO₂Et MeO MeO (b) Draw the product that results from the most reactive diene and most reactive dienophile shown in part (a). (c) Draw a depiction of the orbital overlap involved in the pericyclic reaction that oc- curs between the diene and dienophile in part (b). (d) Is the major product formed in part (b) the endo or exo configuration? Explain your reasoning.

20.40 The following compound undergoes an intramolecular Diels-Alder reaction to give a tricyclic product. Propose a structural formula for the product. CN heat An intramolecular Diels-Alder adduct

Answer 2

Question

Chapter 12, Problem 46QAP

Interpretation Introduction

(a)

Interpretation:

The species that is larger between the given pair is to be predicted and an explanation for the correct choice is to be stated.

Concept Introduction:

Compounds formed from ions are known as ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have lesser number of electrons than the parent atom due to which the force of attraction between protons and electrons increases size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electrons increases, the force of attraction between protons and electrons, decreases, and the size increases.

Interpretation Introduction

(b)

Interpretation:

The species that is larger between the given pair is to be predicted and explanation for the correct choice is to be stated.

Concept Introduction:

Compounds formed from ions are known as ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have lesser number of electrons than the parent atom due to which the force of attraction between protons and electrons increases size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electrons increases, the force of attraction between protons and electrons, decreases, and the size increases.

Interpretation Introduction

(c)

Interpretation:

The species that is larger between the given pair is to be predicted and explanation for the correct choice is to be stated.

Concept Introduction:

Compounds formed from ions are known as ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have lesser number of electrons than the parent atom due to which the force of attraction between protons and electrons increases size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electrons increases, the force of attraction between protons and electrons, decreases, and the size increases.

Interpretation Introduction

(d)

Interpretation:

The species that is larger between the given pair is to be predicted and explanation for the correct choice is to be stated.

Concept Introduction:

Compounds formed from ions are known as ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have lesser number of electrons than the parent atom due to which the force of attraction between protons and electrons increases size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electrons increases, the force of attraction between protons and electrons, decreases, and the size increases.

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Answer 3

Question

Chapter 12, Problem 46QAP

Interpretation Introduction

(a)

Interpretation:

The species that is larger between the given pair is to be predicted and an explanation for the correct choice is to be stated.

Concept Introduction:

Compounds formed from ions are known as ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have lesser number of electrons than the parent atom due to which the force of attraction between protons and electrons increases size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electrons increases, the force of attraction between protons and electrons, decreases, and the size increases.

Interpretation Introduction

(b)

Interpretation:

The species that is larger between the given pair is to be predicted and explanation for the correct choice is to be stated.

Concept Introduction:

Compounds formed from ions are known as ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have lesser number of electrons than the parent atom due to which the force of attraction between protons and electrons increases size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electrons increases, the force of attraction between protons and electrons, decreases, and the size increases.

Interpretation Introduction

(c)

Interpretation:

The species that is larger between the given pair is to be predicted and explanation for the correct choice is to be stated.

Concept Introduction:

Compounds formed from ions are known as ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have lesser number of electrons than the parent atom due to which the force of attraction between protons and electrons increases size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electrons increases, the force of attraction between protons and electrons, decreases, and the size increases.

Interpretation Introduction

(d)

Interpretation:

The species that is larger between the given pair is to be predicted and explanation for the correct choice is to be stated.

Concept Introduction:

Compounds formed from ions are known as ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have lesser number of electrons than the parent atom due to which the force of attraction between protons and electrons increases size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electrons increases, the force of attraction between protons and electrons, decreases, and the size increases.

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Answer 4

Question

Chapter 12, Problem 46QAP

Interpretation Introduction

(a)

Interpretation:

The species that is larger between the given pair is to be predicted and an explanation for the correct choice is to be stated.

Concept Introduction:

Compounds formed from ions are known as ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have lesser number of electrons than the parent atom due to which the force of attraction between protons and electrons increases size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electrons increases, the force of attraction between protons and electrons, decreases, and the size increases.

Interpretation Introduction

(b)

Interpretation:

The species that is larger between the given pair is to be predicted and explanation for the correct choice is to be stated.

Concept Introduction:

Compounds formed from ions are known as ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have lesser number of electrons than the parent atom due to which the force of attraction between protons and electrons increases size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electrons increases, the force of attraction between protons and electrons, decreases, and the size increases.

Interpretation Introduction

(c)

Interpretation:

The species that is larger between the given pair is to be predicted and explanation for the correct choice is to be stated.

Concept Introduction:

Compounds formed from ions are known as ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have lesser number of electrons than the parent atom due to which the force of attraction between protons and electrons increases size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electrons increases, the force of attraction between protons and electrons, decreases, and the size increases.

Interpretation Introduction

(d)

Interpretation:

The species that is larger between the given pair is to be predicted and explanation for the correct choice is to be stated.

Concept Introduction:

Compounds formed from ions are known as ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have lesser number of electrons than the parent atom due to which the force of attraction between protons and electrons increases size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electrons increases, the force of attraction between protons and electrons, decreases, and the size increases.

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Answer 5

Chapter 12, Problem 46QAP

Interpretation Introduction

(a)

Interpretation:

The species that is larger between the given pair is to be predicted and an explanation for the correct choice is to be stated.

Concept Introduction:

Compounds formed from ions are known as ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have lesser number of electrons than the parent atom due to which the force of attraction between protons and electrons increases size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electrons increases, the force of attraction between protons and electrons, decreases, and the size increases.

Interpretation Introduction

(b)

Interpretation:

The species that is larger between the given pair is to be predicted and explanation for the correct choice is to be stated.

Concept Introduction:

Compounds formed from ions are known as ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have lesser number of electrons than the parent atom due to which the force of attraction between protons and electrons increases size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electrons increases, the force of attraction between protons and electrons, decreases, and the size increases.

Interpretation Introduction

(c)

Interpretation:

The species that is larger between the given pair is to be predicted and explanation for the correct choice is to be stated.

Concept Introduction:

Compounds formed from ions are known as ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have lesser number of electrons than the parent atom due to which the force of attraction between protons and electrons increases size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electrons increases, the force of attraction between protons and electrons, decreases, and the size increases.

Interpretation Introduction

(d)

Interpretation:

The species that is larger between the given pair is to be predicted and explanation for the correct choice is to be stated.

Concept Introduction:

Compounds formed from ions are known as ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have lesser number of electrons than the parent atom due to which the force of attraction between protons and electrons increases size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electrons increases, the force of attraction between protons and electrons, decreases, and the size increases.

Answer 6

Chapter 12, Problem 46QAP

Interpretation Introduction

(a)

Interpretation:

The species that is larger between the given pair is to be predicted and an explanation for the correct choice is to be stated.

Concept Introduction:

Compounds formed from ions are known as ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have lesser number of electrons than the parent atom due to which the force of attraction between protons and electrons increases size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electrons increases, the force of attraction between protons and electrons, decreases, and the size increases.

Answer 7

Chapter 12, Problem 46QAP

Interpretation Introduction

(a)

Interpretation:

The species that is larger between the given pair is to be predicted and an explanation for the correct choice is to be stated.

Concept Introduction:

Compounds formed from ions are known as ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have lesser number of electrons than the parent atom due to which the force of attraction between protons and electrons increases size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electrons increases, the force of attraction between protons and electrons, decreases, and the size increases.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The species that is larger between the given pair is to be predicted and explanation for the correct choice is to be stated.

Concept Introduction:

Compounds formed from ions are known as ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have lesser number of electrons than the parent atom due to which the force of attraction between protons and electrons increases size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electrons increases, the force of attraction between protons and electrons, decreases, and the size increases.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The species that is larger between the given pair is to be predicted and explanation for the correct choice is to be stated.

Concept Introduction:

Compounds formed from ions are known as ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have lesser number of electrons than the parent atom due to which the force of attraction between protons and electrons increases size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electrons increases, the force of attraction between protons and electrons, decreases, and the size increases.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The species that is larger between the given pair is to be predicted and explanation for the correct choice is to be stated.

Concept Introduction:

Compounds formed from ions are known as ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have lesser number of electrons than the parent atom due to which the force of attraction between protons and electrons increases size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electrons increases, the force of attraction between protons and electrons, decreases, and the size increases.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The species that is larger between the given pair is to be predicted and explanation for the correct choice is to be stated.

Concept Introduction:

Compounds formed from ions are known as ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have lesser number of electrons than the parent atom due to which the force of attraction between protons and electrons increases size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electrons increases, the force of attraction between protons and electrons, decreases, and the size increases.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The species that is larger between the given pair is to be predicted and explanation for the correct choice is to be stated.

Concept Introduction:

Compounds formed from ions are known as ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have lesser number of electrons than the parent atom due to which the force of attraction between protons and electrons increases size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electrons increases, the force of attraction between protons and electrons, decreases, and the size increases.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The species that is larger between the given pair is to be predicted and explanation for the correct choice is to be stated.

Concept Introduction:

Compounds formed from ions are known as ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have lesser number of electrons than the parent atom due to which the force of attraction between protons and electrons increases size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electrons increases, the force of attraction between protons and electrons, decreases, and the size increases.

Answer 14

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Answer 25

Ch. 12.2 - use differences in electronegativity to account...Ch. 12.2 - trong>Exercise 12.1 For each of the following...Ch. 12.5 - ns have different radii than their parent atoms....Ch. 12.6 - trong>Exercise 12.2 Write the Lewis structure for...Ch. 12.7 - trong>Exercise 12.3 Ozone is a very important...Ch. 12.7 - trong>Exercise 12.4 Write the Lewis structures...Ch. 12.9 - u have seen that molecules with four electron...Ch. 12.9 - Prob. 12.5SC Ch. 12 - sing only the periodic table, predict the most...Ch. 12 - rite the proper charges so that an alkali metal, a...

Solution Summary: The author explains that ionic compounds consist of cation and anion. Cations are positively charged and are formed when an atom loses electrons to get stable.

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Chapter 12 Solutions