Student Solutions Manual For Masterton/hurley's Chemistry: Principles And Reactions, 8th
8th Edition
ISBN: 9781305095236
Author: Maria Cecilia D. De Mesa, Thomas D. Mcgrath
Publisher: Cengage Learning
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Textbook Question
Chapter 12, Problem 43QAP
Solid ammonium iodide decomposes to ammonia and hydrogen gases at sufficiently high temperatures.
(a) What is the total pressure in the flask at equilibrium?
(b) How much solid NH4I is left after the decomposition?
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10.
Stereochemistry. Assign R/S stereochemistry for the chiral center indicated on the
following compound. In order to recieve full credit, you MUST SHOW YOUR WORK!
H₂N
CI
OH
CI
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11. () Stereochemistry. Draw all possible stereoisomers of the following compound. Assign
R/S configurations for all stereoisomers and indicate the relationship between each as
enantiomer, diastereomer, or meso.
NH2
H
HNH,
-18
b)
8.
Indicate whether the following carbocation rearrangements are likely to occur
Please explain your rational using 10 words or less
not likely to occur
• The double bond is still in the
Same position
+
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to oc
occur
WHY?
-3
H3C
Brave
Chair Conformers. Draw the chair conformer of the following substituted
cyclohexane. Peform a RING FLIP and indicate the most stable
conformation and briefly explain why using 20 words or less.
CI
2
-cobs ??
MUST INDICATE H -2
-2
Br
EQ
Cl
OR
AT
Br
H&
most stable
WHY?
- 4
CH
12
Conformational Analysis. Draw all 6 conformers (one above each letter) of the
compound below looking down the indicated bond. Write the letter of the
conformer with the HIGHEST and LOWEST in energies on the lines provided.
NOTE: Conformer A MUST be the specific conformer of the structure as drawn below
-4 NOT
HOH
OH
3
Conformer A:
Br
OH
A
Samo
Br H
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Br
H
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CH₂
H
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H
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H
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B
C
D
E
F
X
6
Conformer with HIGHEST ENERGY:
13. (1
structure
LOWEST ENERGY:
Nomenclature. a) Give the systematic (IUPAC) name structure. b) Draw the
corresponding to this name. HINT: Do not forget to indicate stereochemistry
when applicable.
a)
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Sub = 2-methylethyl-4 Bromo nonane
b) (3R,4S)-3-chloro-4-ethyl-2,7-dimethyloctane
# -2
-2
Chapter 12 Solutions
Student Solutions Manual For Masterton/hurley's Chemistry: Principles And Reactions, 8th
Ch. 12 - The following data are for the system A(g)2B(g)...Ch. 12 - The following data are for the system A(g)2B(g)...Ch. 12 - Prob. 3QAPCh. 12 - Complete the table below for the reaction...Ch. 12 - Write the equilibrium expressions (K) for the...Ch. 12 - Write the equilibrium expressions (K) for the...Ch. 12 - Write the equilibrium expressions (K) for the...Ch. 12 - Write the equilibrium expressions (K) for the...Ch. 12 - Given the following descriptions of reversible...Ch. 12 - Given the following descriptions of reversible...
Ch. 12 - Write an equation for an equilibrium system that...Ch. 12 - Write a chemical equation for an equilibrium...Ch. 12 - Consider the following reaction at 250C:...Ch. 12 - Consider the following reaction at 1000 C:...Ch. 12 - At 627C, K=0.76 for the reaction...Ch. 12 - At 800C, K=2.2104 for the following reaction...Ch. 12 - Prob. 17QAPCh. 12 - Given the following data at 25C...Ch. 12 - Given the following data at a certain temperature,...Ch. 12 - Consider the following hypothetical reactions and...Ch. 12 - When one mole of carbon disulfide gas reacts with...Ch. 12 - Calculate K for the formation of methyl alcohol at...Ch. 12 - Ammonium carbamate solid (NH4CO2NH2) decomposes at...Ch. 12 - Consider the decomposition at 25C of one mole of...Ch. 12 - Consider the decomposition of ammonium hydrogen...Ch. 12 - A sealed flask has 0.541 atm of SO3 at 1000 K. The...Ch. 12 - A gaseous reaction mixture contains 0.30 atm SO2,...Ch. 12 - For the system PCl5(g)PCl3(g)+Cl2(g)K is 26 at...Ch. 12 - The reversible reaction between hydrogen chloride...Ch. 12 - The reversible reaction between hydrogen chloride...Ch. 12 - A compound, X, decomposes at 131C according to the...Ch. 12 - Consider the following reaction at 75C:...Ch. 12 - Consider the reaction between nitrogen and steam:...Ch. 12 - At 500C, k for the for the formation of ammonia...Ch. 12 - At a certain temperature, K is 4.9 for the...Ch. 12 - At a certain temperature, K=0.29 for the...Ch. 12 - For the reaction N2(g)+2H2O(g)2NO(g)+2H2(g) K is...Ch. 12 - Nitrogen dioxide can decompose to nitrogen oxide...Ch. 12 - Consider the following reaction:...Ch. 12 - Consider the hypothetical reaction at 325C...Ch. 12 - At a certain temperature, the equilibrium constant...Ch. 12 - At 460C, the reaction SO2(g)+NO2(g)NO(g)+SO3(g)...Ch. 12 - Solid ammonium iodide decomposes to ammonia and...Ch. 12 - Consider the following decomposition at 80C....Ch. 12 - Hydrogen cyanide, a highly toxic gas, can...Ch. 12 - At 800 K, hydrogen iodide can decompose into...Ch. 12 - For the following reactions, predict whether the...Ch. 12 - Follow the directions of Question 47 for the...Ch. 12 - Consider the system SO3(g)SO2(g)+12 O2(g)H=98.9kJ...Ch. 12 - Consider the system...Ch. 12 - Predict the direction in which each of the...Ch. 12 - Predict the direction in which each of the...Ch. 12 - At a certain temperature, nitrogen and oxygen...Ch. 12 - Consider the following hypothetical reaction:...Ch. 12 - Iodine chloride decomposes at high temperatures to...Ch. 12 - Sulfur oxychloride, SO2Cl2, decomposes to sulfur...Ch. 12 - For the following reaction C(s)+2H2(g)CH4(g)...Ch. 12 - For the system 2SO3(g)2SO2(g)+O2(g) K=1.32 at 627....Ch. 12 - For a certain reaction, H is +33 kJ. What is the...Ch. 12 - Prob. 60QAPCh. 12 - Hemoglobin (Hb) binds to both oxygen and carbon...Ch. 12 - Mustard gas, used in chemical warfare in World War...Ch. 12 - Prob. 63QAPCh. 12 - For the decomposition of CaCO3 at 900C, K=1.04....Ch. 12 - Isopropyl alcohol is the main ingredient in...Ch. 12 - Consider the equilibrium H2(g)+S(s)H2S(g)When this...Ch. 12 - Prob. 67QAPCh. 12 - The following data apply to the unbalanced...Ch. 12 - Consider the reaction: A(g)+2B(g)+C(s)2D(g)At 25C,...Ch. 12 - For the reaction C(s)+CO2(g)2CO(g) K=168 at 1273...Ch. 12 - Consider the system A(g)+2B(g)+C(g)2D(g)at 25C. At...Ch. 12 - The graph below is similar to that of Figure 12.2....Ch. 12 - Prob. 73QAPCh. 12 - The figures below represent the following reaction...Ch. 12 - Prob. 75QAPCh. 12 - Prob. 76QAPCh. 12 - Consider the following reaction at a certain...Ch. 12 - Prob. 78QAPCh. 12 - Ammonia can decompose into its constituent...Ch. 12 - Hydrogen iodide gas decomposes to hydrogen gas and...Ch. 12 - For the system SO3(g)SO2(g)+12 O2(g)at 1000 K,...Ch. 12 - A student studies the equilibrium I2(g)2I(g)at a...Ch. 12 - At a certain temperature, the reaction...Ch. 12 - Benzaldehyde, a flavoring agent, is obtained by...Ch. 12 - Prob. 85QAPCh. 12 - Prob. 86QAP
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