ORGANIC CHEMISTRY (LL)-W/WILEYPLUS
ORGANIC CHEMISTRY (LL)-W/WILEYPLUS
4th Edition
ISBN: 9781119659556
Author: Klein
Publisher: WILEY
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Chapter 12, Problem 43PP
Interpretation Introduction

Interpretation:

The starting material is a compound with three carbon atoms, and the desired product contains six carbon atoms. Reagents for the given conversion are to be determined.

Concept Introduction:

One of the ways this reaction can be achieved is by carbon-carbon coupling with the appropriate Grignard reagent. Organometallic reagents like Grignard Reagents are most used for carbon-carbon coupling reactions. This reaction can occur in presence of dry ether or acetone and Grignard reagent. In this case, Propyl Magnesium Bromide with 2-propanol can be used to obtain our product.

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3. Name this ether correctly. H₁C H3C CH3 CH3 4. Show the best way to make the ether in #3 by a Williamson Ether Synthesis. Start from an alcohol or phenol. 5. Draw the structure of an example of a sulfide.
1. Which one(s) of these can be oxidized with CrO3 ? (could be more than one) a) triphenylmethanol b) 2-pentanol c) Ethyl alcohol d) CH3 2. Write in all the product(s) of this reaction. Label them as "major" or "minor". 2-methyl-2-hexanol H2SO4, heat
3) Determine if the pairs are constitutional isomers, enantiomers, diastereomers, or mesocompounds. (4 points)
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