Organic Chemistry; Organic Chemistry Study Guide A Format: Kit/package/shrinkwrap
Organic Chemistry; Organic Chemistry Study Guide A Format: Kit/package/shrinkwrap
8th Edition
ISBN: 9780134581064
Author: Bruice, Paula Yurkanis
Publisher: Prentice Hall
Question
Book Icon
Chapter 12, Problem 39P

(a)

Interpretation Introduction

Interpretation:

The alkyl halide which will be obtained in greater yield from the given reaction has to be given.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Chiral: Four different atoms attached to a carbon atom is called chiral molecule.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called enantiomers

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer

(b)

Interpretation Introduction

Interpretation:

The alkyl halide which will be obtained in greater yield from the given reaction has to be given.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

(c)

Interpretation Introduction

Interpretation:

The alkyl halide which will be obtained in greater yield from the given reaction has to be given.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Chiral: Four different atoms attached to a carbon atom is called chiral molecule.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-super imposable mirror image is called enantiomers.

Diastereomers: A compound which is non-super imposable and non-mirror image is called enantiomers

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer.

Bromination of alkene in presence of peroxide:

Organic Chemistry; Organic Chemistry Study Guide A Format: Kit/package/shrinkwrap, Chapter 12, Problem 39P , additional homework tip  1

Br2 is the brominating agent and it is used as a source of bromine in the radical reaction. It undergoes homolytic cleavage forms bromine radical. In the first step abstraction of proton takes place and forms more stable radical which undergoes halogen abstraction and leads to the formation of brominated product (bromine radical adds to the sp2 carbon which is bonded with most hydrogen atom).

(d)

Interpretation Introduction

Interpretation:

The alkyl halide which will be obtained in greater yield from the given reaction has to be given.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Chiral: Four different atoms attached to a carbon atom is called chiral molecule.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-super imposable mirror image is called enantiomers.

Diastereomers: A compound which is non-super imposable and non-mirror image is called enantiomers

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer.

Bromination of alkene in presence of peroxide:

Organic Chemistry; Organic Chemistry Study Guide A Format: Kit/package/shrinkwrap, Chapter 12, Problem 39P , additional homework tip  2

Br2 is the brominating agent and it is used as a source of bromine in the radical reaction. It undergoes homolytic cleavage forms bromine radical. In the first step abstraction of proton takes place and forms more stable radical which undergoes halogen abstraction and leads to the formation of brominated product (bromine radical adds to the sp2 carbon which is bonded with most hydrogen atom)

(e)

Interpretation Introduction

Interpretation:

The alkyl halide which will be obtained in greater yield from the given reaction has to be given.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Chiral: Four different atoms attached to a carbon atom is called chiral molecule.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-super imposable mirror image is called enantiomers.

Diastereomers: A compound which is non-super imposable and non-mirror image is called enantiomers

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer.

Bromination of alkene in presence of peroxide:

Organic Chemistry; Organic Chemistry Study Guide A Format: Kit/package/shrinkwrap, Chapter 12, Problem 39P , additional homework tip  3

Br2 is the brominating agent and it is used as a source of bromine in the radical reaction. It undergoes homolytic cleavage forms bromine radical. In the first step abstraction of proton takes place and forms more stable radical which undergoes halogen abstraction and leads to the formation of brominated product (bromine radical adds to the sp2 carbon which is bonded with most hydrogen atom).

(f)

Interpretation Introduction

Interpretation:

The alkyl halide which will be obtained in greater yield from the given reaction has to be given.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Chiral: Four different atoms attached to a carbon atom is called chiral molecule.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-super imposable mirror image is called enantiomers.

Diastereomers: A compound which is non-super imposable and non-mirror image is called enantiomers

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer.

Bromination of alkene in presence of peroxide:

Organic Chemistry; Organic Chemistry Study Guide A Format: Kit/package/shrinkwrap, Chapter 12, Problem 39P , additional homework tip  4

Br2 is the brominating agent and it is used as a source of bromine in the radical reaction. It undergoes hemolytic cleavage forms bromine radical. In the first step abstraction of proton takes place and forms more stable radical which undergoes halogen abstraction and leads to the formation of brominated product (bromine radical adds to the sp2  carbon which is bonded with most hydrogen atom).

Blurred answer
Students have asked these similar questions
All of the following are allowed energy levels except _. a) 3f b) 1s c) 3d d) 5p e) 6s
A student wants to make the following product in good yield from a single transformation step, starting from benzene. Add any organic reagents the student is missing on the left-hand side of the arrow, and any addition reagents that are necessary above or below the arrow. If this product can't be made in good yield with a single transformation step, check the box below the drawing area. Note for advanced students: you may assume that an excess of benzene is used as part of the reaction conditions. : ☐ + I X This product can't be made in a single transformation step.
Predict the major products of this organic reaction:

Chapter 12 Solutions

Organic Chemistry; Organic Chemistry Study Guide A Format: Kit/package/shrinkwrap

Knowledge Booster
Background pattern image
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
  • Text book image
    Organic Chemistry: A Guided Inquiry
    Chemistry
    ISBN:9780618974122
    Author:Andrei Straumanis
    Publisher:Cengage Learning
    Text book image
    Organic Chemistry
    Chemistry
    ISBN:9781305580350
    Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
    Publisher:Cengage Learning
    Text book image
    Organic Chemistry
    Chemistry
    ISBN:9781305080485
    Author:John E. McMurry
    Publisher:Cengage Learning
Text book image
Organic Chemistry: A Guided Inquiry
Chemistry
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9781305080485
Author:John E. McMurry
Publisher:Cengage Learning