General, Organic, & Biological Chemistry
3rd Edition
ISBN: 9780073511245
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 1.2, Problem 1.3P
Does the molecular art represent a chemical change or a physical change? Explain your choice.
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10.
Stereochemistry. Assign R/S stereochemistry for the chiral center indicated on the
following compound. In order to recieve full credit, you MUST SHOW YOUR WORK!
H₂N
CI
OH
CI
カー
11. () Stereochemistry. Draw all possible stereoisomers of the following compound. Assign
R/S configurations for all stereoisomers and indicate the relationship between each as
enantiomer, diastereomer, or meso.
NH2
H
HNH,
-18
b)
8.
Indicate whether the following carbocation rearrangements are likely to occur
Please explain your rational using 10 words or less
not likely to occur
• The double bond is still in the
Same position
+
Likely
to oc
occur
WHY?
-3
H3C
Brave
Chair Conformers. Draw the chair conformer of the following substituted
cyclohexane. Peform a RING FLIP and indicate the most stable
conformation and briefly explain why using 20 words or less.
CI
2
-cobs ??
MUST INDICATE H -2
-2
Br
EQ
Cl
OR
AT
Br
H&
most stable
WHY?
- 4
CH
12
Conformational Analysis. Draw all 6 conformers (one above each letter) of the
compound below looking down the indicated bond. Write the letter of the
conformer with the HIGHEST and LOWEST in energies on the lines provided.
NOTE: Conformer A MUST be the specific conformer of the structure as drawn below
-4 NOT
HOH
OH
3
Conformer A:
Br
OH
A
Samo
Br H
04
Br
H
H3
CH₂
H
anti
stagere
Br CH
clipsed
H
Brott
H
IV
H
MISSING 2
-2
B
C
D
E
F
X
6
Conformer with HIGHEST ENERGY:
13. (1
structure
LOWEST ENERGY:
Nomenclature. a) Give the systematic (IUPAC) name structure. b) Draw the
corresponding to this name. HINT: Do not forget to indicate stereochemistry
when applicable.
a)
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Parent name (noname)
4 Bromo
Sub = 2-methylethyl-4 Bromo nonane
b) (3R,4S)-3-chloro-4-ethyl-2,7-dimethyloctane
# -2
-2
Chapter 1 Solutions
General, Organic, & Biological Chemistry
Ch. 1.1 - Prob. 1.1PCh. 1.2 - Characterize each process as a physical change or...Ch. 1.2 - Does the molecular art represent a chemical change...Ch. 1.3 - Classify each example of molecular art as a pure...Ch. 1.3 - Classify each item as a pure substance or a...Ch. 1.3 - Classify each item as an element or a compound:...Ch. 1.4 - What term is used for each of the following units:...Ch. 1.4 - If a nanometer is one-billionth of a meter...Ch. 1.4 - Prob. 1.9PCh. 1.4 - Using the prefixes in Table 1.2, determine which...
Ch. 1.5 - How many significant figures does each number...Ch. 1.5 - Indicate whether each zero in the following...Ch. 1.5 - Prob. 1.13PCh. 1.5 - Carry out each caluction and give the answer using...Ch. 1.5 - Carry out each calculation and give the answer...Ch. 1.6 - Lab results for a routine check-up showed an...Ch. 1.6 - Write each number in scientific notation. 93,200...Ch. 1.6 - Convert each number to its standard form. 6.5103...Ch. 1.7 - Write two conversion factors for each pair of...Ch. 1.7 - Prob. 1.20PCh. 1.7 - Carry out each of the following conversions. 25 L...Ch. 1.7 - What is the volume of liquid contained in the...Ch. 1.7 - Carry out each of the following conversions. 6,250...Ch. 1.8 - Prob. 1.24PCh. 1.8 - A patient is prescribed 0.100 mg of a drug that is...Ch. 1.8 - Prob. 1.26PCh. 1.9 - Prob. 1.27PCh. 1.9 - Prob. 1.28PCh. 1.10 - How does the mass of liquid A in cylinder [1]...Ch. 1.10 - Calculate the mass in grams of 10.0 mL of diethyl...Ch. 1.10 - If a 120-lb woman uses five 2.0lb lead weights in...Ch. 1.10 - If the density of a liquid is 0.80 g/mL, what is...Ch. 1 - Classify each example of molecular art as a pure...Ch. 1 - (a) Which representation(s) in Problem 1.19...Ch. 1 - Label each component in the molecular art as an...Ch. 1 - Label each component in the molecular art as an...Ch. 1 - Prob. 1.37PCh. 1 - Prob. 1.38PCh. 1 - Prob. 1.39PCh. 1 - Classify each process as a chemical or physical...Ch. 1 - Prob. 1.41PCh. 1 - Prob. 1.42PCh. 1 - What is the temperature on the given Fahrenheit...Ch. 1 - a. What is the length of the given crayon in...Ch. 1 - What is the difference between an exact number and...Ch. 1 - Label each quantity as an exact or inexact number....Ch. 1 - Which quantity in each pair is larger? 5 mL or 5...Ch. 1 - Which quantity in each pair is larger? 10 km or 10...Ch. 1 - How many significant figures does each number...Ch. 1 - Prob. 1.50PCh. 1 - Prob. 1.51PCh. 1 - Round each number ¡n Problem 1.51 to four...Ch. 1 - Prob. 1.53PCh. 1 - Prob. 1.54PCh. 1 - Prob. 1.55PCh. 1 - Prob. 1.56PCh. 1 - Prob. 1.57PCh. 1 - Prob. 1.58PCh. 1 - Prob. 1.59PCh. 1 - Rank the numbers in each group from smallest to...Ch. 1 - Prob. 1.61PCh. 1 - Prob. 1.62PCh. 1 - Prob. 1.63PCh. 1 - What is the volume of liquid contained in the...Ch. 1 - Prob. 1.65PCh. 1 - (a) If there are 15 mL in one tablespoon, how many...Ch. 1 - Prob. 1.67PCh. 1 - Prob. 1.68PCh. 1 - Carry out each of the following conversions.
a....Ch. 1 - Carry out each of the following conversions.
a....Ch. 1 - Prob. 1.71PCh. 1 - Prob. 1.72PCh. 1 - Prob. 1.73PCh. 1 - Prob. 1.74PCh. 1 - Which temperature in each pair is higher? a....Ch. 1 - Prob. 1.76PCh. 1 - Prob. 1.77PCh. 1 - Prob. 1.78PCh. 1 - Prob. 1.79PCh. 1 - Prob. 1.80PCh. 1 - Prob. 1.81PCh. 1 - If gasoline has a density of 0.66 g/mL, what is...Ch. 1 - Which is the upper layer when each of the...Ch. 1 - Prob. 1.84PCh. 1 - A lab test showed an individual’s chloesterol leve...Ch. 1 - Hemoglobin is a protein that transports oxygen...Ch. 1 - Prob. 1.87PCh. 1 - A soccer weighed 70.7 kg before a match, drank 1.8...Ch. 1 - Liposuction is a cosmetic procedure used to remove...Ch. 1 - A single 1-oz serving of tortilla chips contains...Ch. 1 - Prob. 1.91PCh. 1 - Prob. 1.92PCh. 1 - Prob. 1.93PCh. 1 - Prob. 1.94PCh. 1 - Prob. 1.95PCh. 1 - Prob. 1.96PCh. 1 - Often the specific amount of a drug to be...Ch. 1 - Prob. 1.98CPCh. 1 - Prob. 1.99CPCh. 1 - Prob. 1.100CPCh. 1 - Prob. 1.101CPCh. 1 - Prob. 1.102CPCh. 1 - Prob. 1.103CPCh. 1 - If the proper dosage of a medication is 10g/kg of...
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