GENERAL CHEMISTRY-MOD.MASTERINGCHEM.
11th Edition
ISBN: 9780134193601
Author: Petrucci
Publisher: PEARSON
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Textbook Question
Chapter 12, Problem 130SAE
Explain the important distinctions between each pair of terms: (a) adhesive and cohesive forces; (b) vaporization and condensation; (c) triple point and critical point; (d) face-centered and body-centered cubic unit cell; (e) tetrahedral and octahedral hole.
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Students have asked these similar questions
Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an
organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the
compound. Find the structure. Show complete solutions.
Predicted 1H NMR Spectrum
4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1
f1 (ppm)
Predicted 13C NMR Spectrum
100
f1 (ppm)
30
220 210 200 190 180
170
160 150 140 130 120
110
90
80
70
-26
60
50
40
46
30
20
115
10
1.0 0.9 0.8
0
-10
Q: Arrange BCC and Fec
metals, in sequence from the
Fable (Dr. R's slides) and
Calculate Volume and Density.
Aa
BCC
V
52 5
SFCC
None
Chapter 12 Solutions
GENERAL CHEMISTRY-MOD.MASTERINGCHEM.
Ch. 12 - For each of the following substances describe the...Ch. 12 - When another atom or group of atoms is substituted...Ch. 12 - Prob. 3ECh. 12 - Arrange the liquids represented by the following...Ch. 12 - One of the following substances is a liquid at...Ch. 12 - In which of the following compound might...Ch. 12 - Prob. 7ECh. 12 - Prob. 8ECh. 12 - Prob. 9ECh. 12 - Prob. 10E
Ch. 12 - Silicone oils, such as H3C[SiO(CH2)2],Si(CH3) ,...Ch. 12 - Surface tension, viscosity, and vapor pressure are...Ch. 12 - Is there any scientific basis for the colloquial...Ch. 12 - A television commercial claims that a product...Ch. 12 - Prob. 15ECh. 12 - Prob. 16ECh. 12 - Prob. 17ECh. 12 - Carbon tetrachloride (CCl4) and mercury have...Ch. 12 - As a liquid evaporated from an open container, its...Ch. 12 - Prob. 20ECh. 12 - The enthalpy of vaporization of benzene, C6H6(l)...Ch. 12 - A vapor volume of 1.17 L forms when a sample of...Ch. 12 - Use data from the Integrative Example (page 566)...Ch. 12 - How much heat is required to raise the temperature...Ch. 12 - How many liters of CH4(g) , measured at 23.4 °C...Ch. 12 - A 50.0 g piece of iron at 152°C is dropped into...Ch. 12 - From Figure 12-18, estimate (a) the vapor pressure...Ch. 12 - Prob. 28ECh. 12 - Equilibrium is established between Br2(l) and...Ch. 12 - Prob. 30ECh. 12 - A double boiler is used when a careful control of...Ch. 12 - One popular demonstration in chemistry labs is...Ch. 12 - Pressure cookers achieve a high cooking...Ch. 12 - Prob. 34ECh. 12 - A 25.0 L volume of He(g) at 30.0°C is passed...Ch. 12 - A 7.53 L sample of N2 (g) at 742 mmHg and 45.0 °C...Ch. 12 - Prob. 37ECh. 12 - A 10.0 g sample of liquid water is sealed in a...Ch. 12 - Cyclohexanol has a vapor pressure of 10.0 mmHg at...Ch. 12 - Prob. 40ECh. 12 - Prob. 41ECh. 12 - Prob. 42ECh. 12 - Benzaldehyde, C2H2CHO , has a normal boiling point...Ch. 12 - With reference to Figure 12-20, which is the more...Ch. 12 - Which substances listed in Table 12.6 can exist as...Ch. 12 - Prob. 46ECh. 12 - The normal melting point of copper is 1357 K, and...Ch. 12 - An ice calorimeter measures quantities of heat by...Ch. 12 - An 80.0 g piece of dry ice, CO2 (s), is placed in...Ch. 12 - Sketch a plausible phase diagram for hydrazine...Ch. 12 - Shown here is a portion of the phase diagram for...Ch. 12 - Prob. 52ECh. 12 - Prob. 53ECh. 12 - Prob. 54ECh. 12 - Use appropriate phase diagrams data from Table...Ch. 12 - Prob. 56ECh. 12 - To an insulated container with 100.0 g H2O(l) at...Ch. 12 - A 54 cm2 ice cube at 25.0 °C is added to a...Ch. 12 - Prob. 59ECh. 12 - Prob. 60ECh. 12 - Prob. 61ECh. 12 - Prob. 62ECh. 12 - Silicon carbide, SiC, crystallizes in a form...Ch. 12 - Prob. 64ECh. 12 - Prob. 65ECh. 12 - Use Coulomb's law (see Appendix B) to verify the...Ch. 12 - The hardness of crystals is rated based on Mohs...Ch. 12 - Will the mineral villaumite (NaF) or periclase...Ch. 12 - Prob. 69ECh. 12 - Prob. 70ECh. 12 - Consider the two-dimensional lattice shown here....Ch. 12 - As we saw in Section 12-6, stacking spheres always...Ch. 12 - Tungsten has a body-centered cubic crystal...Ch. 12 - Magnesium crystallizes in the hcp arrangement...Ch. 12 - Polonium (Po) is the only element known to take on...Ch. 12 - Prob. 76ECh. 12 - Silicon tetrafluoride molecules are arranged in a...Ch. 12 - Two views, a top and side view, for the unit cell...Ch. 12 - Show that the unit cells for CaF2 and TiO2 in...Ch. 12 - Prob. 80ECh. 12 - The crystal structure of magnesium oxide, MgO, is...Ch. 12 - Potassium chloride has the same crystal structure...Ch. 12 - Prob. 83ECh. 12 - Use data from Figure 9-9 to predict the type of...Ch. 12 - Without doing calculations, indicate how you would...Ch. 12 - Determine the lattice energy of KF(s) from the...Ch. 12 - Refer to Example 12-12. Together with data given...Ch. 12 - Prob. 88ECh. 12 - Prob. 89IAECh. 12 - Prob. 90IAECh. 12 - Prob. 91IAECh. 12 - Use the following data and data from Appendix D to...Ch. 12 - Prob. 93IAECh. 12 - Prob. 94IAECh. 12 - Because solid p-dichlorobenzene, C6H4CI2 ,...Ch. 12 - A 1.05 mol sample of H2O(g) is compressed into a...Ch. 12 - Prob. 97IAECh. 12 - By the method used to graph Figure 12-20, plot In...Ch. 12 - Prob. 99IAECh. 12 - Prob. 100IAECh. 12 - Prob. 101IAECh. 12 - Prob. 102IAECh. 12 - In acetic acid vapor, some molecules exist as...Ch. 12 - Prob. 104IAECh. 12 - Sketched here are two hypothetical phase diagrams...Ch. 12 - Prob. 106IAECh. 12 - The triple point temperature of bismuth is 544.5 K...Ch. 12 - The crystal structure of lithium sulfide ( Li2S ),...Ch. 12 - Refer to Figure 12-44 and Figure 12-48. Suppose...Ch. 12 - Prob. 110IAECh. 12 - One way to describe ionic crystal structures is in...Ch. 12 - Prob. 112IAECh. 12 - The enthalpy of formation of Nal(s) is 288 kJ...Ch. 12 - Prob. 114IAECh. 12 - A crystalline solid contains three types of ions,...Ch. 12 - A certain mineral has a cubic unit cell with...Ch. 12 - Prob. 117IAECh. 12 - In some barbecue grills the electric lighter...Ch. 12 - Prob. 119IAECh. 12 - Prob. 120IAECh. 12 - Intermolecular forces play vital and varied roles...Ch. 12 - Prob. 122FPCh. 12 - Prob. 123FPCh. 12 - All solids contain defects or imperfections of...Ch. 12 - In an ionic crystal lattice each cation will be...Ch. 12 - Prob. 126FPCh. 12 - Prob. 127FPCh. 12 - Prob. 128SAECh. 12 - Briefly describe each of the following phenomena...Ch. 12 - Explain the important distinctions between each...Ch. 12 - Prob. 131SAECh. 12 - Prob. 132SAECh. 12 - Prob. 133SAECh. 12 - Prob. 134SAECh. 12 - Prob. 135SAECh. 12 - Prob. 136SAECh. 12 - Prob. 137SAECh. 12 - Prob. 138SAECh. 12 - Prob. 139SAECh. 12 - Prob. 140SAECh. 12 - Prob. 141SAECh. 12 - Prob. 142SAECh. 12 - Prob. 143SAECh. 12 - Prob. 144SAECh. 12 - The following data are given for CCl4 . Normal...Ch. 12 - The fcc unit cell is a cube with atoms at each of...Ch. 12 - Prob. 147SAECh. 12 - Prob. 148SAECh. 12 - Prob. 149SAECh. 12 - Prob. 150SAECh. 12 - In the lithium iodide crystal, the Li—l distance...Ch. 12 - Prob. 152SAECh. 12 - Prob. 153SAECh. 12 - Prob. 154SAECh. 12 - Construct a concept map showing the ideas...
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