
General, Organic, and Biological Chemistry - 4th edition
4th Edition
ISBN: 9781259883989
Author: by Janice Smith
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 1.2, Problem 1.2P
Characterize each process as a physical change or a chemical change: (a) making ice cubes; (b) burning natural gas; (c) silver jewelry tarnishing; (d) a pile of snow melting; (e) fermenting grapes to produce wine.
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For Raman spectroscopy/imaging, which statement is not true regarding its disadvantages?
a) Limited spatial resolution.
b) Short integration time.
c) A one-dimensional technique.
d) Weak signal, only 1 in 108 incident photons is Raman scattered.
e) Fluorescence interference.
Using a cell of known pathlength b = 1.25115 x 10-3 cm, a water absorption spectrum was measured. The band at 1645 cm-1, assigned to the O-H bending, showed an absorbance, A, of 1.40.
a) Assuming that water density is 1.00 g/mL, calculate the water molar concentration c (hint: M= mole/L)
b) Calculate the molar absorptivity, a, of the 1645 cm-1 band
c) The transmitted light, I, can be written as I= Ioexp(-xb), where x is the absorption coefficient (sometimes designated as alpha), Io is the input light, and b is the cell pathlength. Prove that x= (ln10)*x*c. (Please provide a full derivation of the equation for x from the equation for I).
d) Calculate x for the 1645 cm-1 band
I need help with the follloaing
Chapter 1 Solutions
General, Organic, and Biological Chemistry - 4th edition
Ch. 1.1 - Prob. 1.1PCh. 1.2 - Characterize each process as a physical change or...Ch. 1.2 - Does the molecular art represent a chemical change...Ch. 1.3 - Classify each example of molecular art as a pure...Ch. 1.3 - (a) Which representation(s) of molecular art...Ch. 1.3 - Classify each item as a pure substance or a...Ch. 1.3 - Classify each item as an element or a compound:...Ch. 1.4 - What term is used for each of the following units:...Ch. 1.4 - If a nanometer is one-billionth of a meter...Ch. 1.4 - Prob. 1.8P
Ch. 1.4 - Using the prefixes in Table 1.2, determine which...Ch. 1.5 - How many significant figures does each number...Ch. 1.5 - Indicate whether each zero in the following...Ch. 1.5 - Round off each number in Sample Problem 1.4 to two...Ch. 1.5 - Carry out each caluction and give the answer using...Ch. 1.5 - Carry out each calculation and give the answer...Ch. 1.6 - Write each number in scientific notation. 93,200...Ch. 1.6 - Lab results for a routine check-up showed an...Ch. 1.6 - Convert each number to its standard form. 6.5103...Ch. 1.7 - Write two conversion factors for each pair of...Ch. 1.7 - Carry out each of the following conversions. 25 L...Ch. 1.7 - On a flight from Bangkok, Thailand, to Taipei,...Ch. 1.7 - What is the volume of liquid contained in the...Ch. 1.7 - Carry out each of the following conversions. 6,250...Ch. 1.8 - A patient is prescribed 0.100 mg of a drug that is...Ch. 1.8 - Prob. 1.13PPCh. 1.8 - Prob. 1.14PCh. 1.9 - Prob. 1.14PPCh. 1.9 - Prob. 1.15PCh. 1.10 - How does the mass of liquid A in cylinder [1]...Ch. 1.10 - Calculate the mass in grams of 10.0 mL of diethyl...Ch. 1.10 - If a 120-lb woman uses five 2.0lb lead weights in...Ch. 1.10 - If a household recycles 10.5 kg of plastic bottles...Ch. 1.10 - If the density of a liquid is 0.80 g/mL, what is...Ch. 1 - Classify each example of molecular art as a pure...Ch. 1 - (a) Which representation(s) in Problem 1.19...Ch. 1 - Label each component in the molecular art as an...Ch. 1 - Label each component in the molecular art as an...Ch. 1 - (a) Which representation(s) illustrate a mixture...Ch. 1 - Label each of the following conversions as a...Ch. 1 - Classify each process as a chemical or physical...Ch. 1 - Classify each process as a chemical or physical...Ch. 1 - When a chunk of dry ice (solid carbon dioxide) is...Ch. 1 - The inexpensive preparation of nitrogen-containing...Ch. 1 - What is the temperature on the given Fahrenheit...Ch. 1 - a. What is the length of the given crayon in...Ch. 1 - Label each quantity as an exact or inexact number....Ch. 1 - Label each quantity as an exact or inexact number....Ch. 1 - Which quantity in each pair is larger? 5 mL or 5...Ch. 1 - Which quantity in each pair is larger? 10 km or 10...Ch. 1 - How many significant figures does each number...Ch. 1 - Prob. 36PCh. 1 - Prob. 37PCh. 1 - Prob. 38PCh. 1 - Prob. 39PCh. 1 - Prob. 40PCh. 1 - Prob. 41PCh. 1 - Prob. 42PCh. 1 - Prob. 43PCh. 1 - Prob. 44PCh. 1 - Prob. 45PCh. 1 - Rank the numbers in each group from smallest to...Ch. 1 - Prob. 47PCh. 1 - Prob. 48PCh. 1 - Prob. 49PCh. 1 - What is the volume of liquid contained in the...Ch. 1 - Prob. 51PCh. 1 - (a) If there are 15 mL in one tablespoon, how many...Ch. 1 - The concentration of mercury, a toxi pollutant, in...Ch. 1 - Prob. 54PCh. 1 - Prob. 55PCh. 1 - Prob. 56PCh. 1 - Prob. 57PCh. 1 - Prob. 58PCh. 1 - Prob. 59PCh. 1 - Prob. 60PCh. 1 - Which temperature in each pair is higher? a....Ch. 1 - Prob. 62PCh. 1 - Prob. 63PCh. 1 - Draw a graduated cylinder similar to Problem 1.63...Ch. 1 - The given beaker contains 100 mL of water. Draw an...Ch. 1 - Prob. 66PCh. 1 - Prob. 67PCh. 1 - Prob. 68PCh. 1 - If milk has a density of 1.03 g/mL, what is the...Ch. 1 - Prob. 70PCh. 1 - Prob. 71PCh. 1 - Prob. 72PCh. 1 - A lab test showed an individual’s chloesterol leve...Ch. 1 - Hemoglobin is a protein that transports oxygen...Ch. 1 - Prob. 75PCh. 1 - A soccer weighed 70.7 kg before a match, drank 1.8...Ch. 1 - Liposuction is a cosmetic procedure used to remove...Ch. 1 - A single 1-oz serving of tortilla chips contains...Ch. 1 - Prob. 79PCh. 1 - Prob. 80PCh. 1 - Prob. 81PCh. 1 - Prob. 82PCh. 1 - Prob. 83PCh. 1 - Prob. 84PCh. 1 - Often the specific amount of a drug to be...Ch. 1 - Prob. 86CPCh. 1 - Prob. 87CPCh. 1 - Prob. 88CPCh. 1 - Prob. 89CPCh. 1 - Prob. 90CPCh. 1 - Prob. 91CPCh. 1 - If the proper dosage of a medication is 10g/kg of...
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- For a CARS experiment on a Raman band 918 cm-1, if omega1= 1280 nm, calculate the omega2 in wavelength (nm) and the CARS output in wavelength (nm).arrow_forwardI need help with the following questionarrow_forwardFor CARS, which statement is not true regarding its advantages? a) Contrast signal based on vibrational characteristics, no need for fluorescent tagging. b) Stronger signals than spontaneous Raman. c) Suffers from fluorescence interference, because CARS signal is at high frequency. d) Faster, more efficient imaging for real-time analysis. e) Higher resolution than spontaneous Raman microscopy.arrow_forward
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