Atkins' Physical chemistry
11th Edition
ISBN: 9780198814740
Author: ATKINS, P. W. (peter William), 1940- (author.)
Publisher: Oxford University Press,
expand_more
expand_more
format_list_bulleted
Question
Chapter 12, Problem 12D.5P
Interpretation Introduction
Interpretation:
The spin density of anthracene radical anion at
Concept introduction:
EPR stands for electronic paramagnetic resonance. It is used to study species that contain unpaired electrons. EPR can be used to study both solids and liquids. However, the study of the gas phase samples is difficult due to the free rotation of the molecules. The
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Add conditions above and below the arrow that turn the reactant below into the product below in a single transformation.
+ More...
If you need to write reagents above and below the arrow that have complex hydrocarbon groups in them, there is a set of standard abbreviations you can use.
More...
T
H,N
NC
Dat
Indicate the order of basicity of primary, secondary and tertiary amines.
>
Classify each of the following molecules as aromatic, antiaromatic, or nonaromatic.
Cl
Z-
N
O aromatic
O antiaromatic
O nonaromatic
O aromatic
O antiaromatic
O nonaromatic
O aromatic
○ antiaromatic
nonaromatic
Chapter 12 Solutions
Atkins' Physical chemistry
Ch. 12 - Prob. 12B.1STCh. 12 - Prob. 12B.2STCh. 12 - Prob. 12B.3STCh. 12 - Prob. 12D.1STCh. 12 - Prob. 12A.1DQCh. 12 - Prob. 12A.2DQCh. 12 - Prob. 12A.3DQCh. 12 - Prob. 12A.1AECh. 12 - Prob. 12A.1BECh. 12 - Prob. 12A.2AE
Ch. 12 - Prob. 12A.2BECh. 12 - Prob. 12A.3AECh. 12 - Prob. 12A.3BECh. 12 - Prob. 12A.4AECh. 12 - Prob. 12A.4BECh. 12 - Prob. 12A.5AECh. 12 - Prob. 12A.5BECh. 12 - Prob. 12A.6AECh. 12 - Prob. 12A.6BECh. 12 - Prob. 12A.7AECh. 12 - Prob. 12A.7BECh. 12 - Prob. 12A.8AECh. 12 - Prob. 12A.8BECh. 12 - Prob. 12A.9AECh. 12 - Prob. 12A.9BECh. 12 - Prob. 12A.1PCh. 12 - Prob. 12A.3PCh. 12 - Prob. 12B.1DQCh. 12 - Prob. 12B.2DQCh. 12 - Prob. 12B.3DQCh. 12 - Prob. 12B.4DQCh. 12 - Prob. 12B.5DQCh. 12 - Prob. 12B.1AECh. 12 - Prob. 12B.1BECh. 12 - Prob. 12B.2AECh. 12 - Prob. 12B.2BECh. 12 - Prob. 12B.3AECh. 12 - Prob. 12B.3BECh. 12 - Prob. 12B.4AECh. 12 - Prob. 12B.4BECh. 12 - Prob. 12B.5AECh. 12 - Prob. 12B.5BECh. 12 - Prob. 12B.6AECh. 12 - Prob. 12B.6BECh. 12 - Prob. 12B.7AECh. 12 - Prob. 12B.7BECh. 12 - Prob. 12B.8AECh. 12 - Prob. 12B.8BECh. 12 - Prob. 12B.9AECh. 12 - Prob. 12B.9BECh. 12 - Prob. 12B.10AECh. 12 - Prob. 12B.10BECh. 12 - Prob. 12B.11AECh. 12 - Prob. 12B.11BECh. 12 - Prob. 12B.12AECh. 12 - Prob. 12B.12BECh. 12 - Prob. 12B.13AECh. 12 - Prob. 12B.13BECh. 12 - Prob. 12B.14AECh. 12 - Prob. 12B.14BECh. 12 - Prob. 12B.1PCh. 12 - Prob. 12B.2PCh. 12 - Prob. 12B.3PCh. 12 - Prob. 12B.5PCh. 12 - Prob. 12B.6PCh. 12 - Prob. 12B.7PCh. 12 - Prob. 12B.8PCh. 12 - Prob. 12B.9PCh. 12 - Prob. 12C.1DQCh. 12 - Prob. 12C.2DQCh. 12 - Prob. 12C.3DQCh. 12 - Prob. 12C.4DQCh. 12 - Prob. 12C.5DQCh. 12 - Prob. 12C.1AECh. 12 - Prob. 12C.1BECh. 12 - Prob. 12C.2AECh. 12 - Prob. 12C.2BECh. 12 - Prob. 12C.3AECh. 12 - Prob. 12C.3BECh. 12 - Prob. 12C.4AECh. 12 - Prob. 12C.4BECh. 12 - Prob. 12C.5AECh. 12 - Prob. 12C.5BECh. 12 - Prob. 12C.4PCh. 12 - Prob. 12C.5PCh. 12 - Prob. 12C.6PCh. 12 - Prob. 12C.10PCh. 12 - Prob. 12D.1DQCh. 12 - Prob. 12D.2DQCh. 12 - Prob. 12D.1AECh. 12 - Prob. 12D.1BECh. 12 - Prob. 12D.2AECh. 12 - Prob. 12D.2BECh. 12 - Prob. 12D.3AECh. 12 - Prob. 12D.3BECh. 12 - Prob. 12D.4AECh. 12 - Prob. 12D.4BECh. 12 - Prob. 12D.5AECh. 12 - Prob. 12D.5BECh. 12 - Prob. 12D.6AECh. 12 - Prob. 12D.6BECh. 12 - Prob. 12D.1PCh. 12 - Prob. 12D.2PCh. 12 - Prob. 12D.4PCh. 12 - Prob. 12D.5PCh. 12 - Prob. 12D.6PCh. 12 - Prob. 12D.7PCh. 12 - Prob. 12D.8PCh. 12 - Prob. 12.3IACh. 12 - Prob. 12.4IA
Knowledge Booster
Similar questions
- Please help me answer this question. I don't understand how or even if this can happen in a single transformation. Please provide a detailed explanation and a drawing showing how it can happen in a single transformation. Add the necessary reagents and reaction conditions above and below the arrow in this organic reaction. If the products can't be made from the reactant with a single transformation, check the box under the drawing area instead.arrow_forward2) Draw the correct chemical structure (using line-angle drawings / "line structures") from their given IUPAC name: a. (E)-1-chloro-3,4,5-trimethylhex-2-ene b. (Z)-4,5,7-trimethyloct-4-en-2-ol C. (2E,6Z)-4-methylocta-2,6-dienearrow_forwardපිපිම Draw curved arrows to represent the flow of electrons in the reaction on the left Label the reactants on the left as either "Acid" or "Base" (iii) Decide which direction the equilibrium arrows will point in each reaction, based on the given pk, values (a) + H-O H 3-H + (c) H" H + H****H 000 44-00 NH₂ (e) i Дон OH Ө NHarrow_forward
- 3) Label the configuration in each of the following alkenes as E, Z, or N/A (for non-stereogenic centers). 00 E 000 N/A E Br N/A N/A (g) E N/A OH E (b) Oz N/A Br (d) 00 E Z N/A E (f) Oz N/A E (h) Z N/Aarrow_forward6) Fill in the missing Acid, pKa value, or conjugate base in the table below: Acid HCI Approximate pK, -7 Conjugate Base H-C: Hydronium (H₂O') -1.75 H-O-H Carboxylic Acids (RCOOH) Ammonium (NH4) 9.24 Water (H₂O) H-O-H Alcohols (ROH) RO-H Alkynes R--H Amines 25 25 38 HOarrow_forward5) Rank the following sets of compounds in order of decreasing acidity (most acidic to least acidic), and choose the justification(s) for each ranking. (a) OH V SH я вон CH most acidic (lowst pKa) least acidic (highest pKa) Effect(s) Effect(s) Effect(s) inductive effect O inductive effect O inductive effect electronegativity electronegativity O electronegativity resonance polarizability resonance polarizability O resonance O polarizability hybridization Ohybridization O hybridization оarrow_forward
- How negatively charged organic bases are formed.arrow_forwardNonearrow_forward1) For the following molecules: (i) Label the indicated alkenes as either cis (Z), trans (E), or N/A (for non-stereogenic centers) by bubbling in the appropriate label on the molecule. (ii) Complete the IUPAC name located below the structure (HINT: Put the letter of the configuration in parentheses at the beginning of the name!) E z N/A ()-3,4,6-trimethylhept-2-ene E Oz O N/A ()-3-ethyl-1-fluoro-4-methylhex-3-ene E -+- N/A Me )-2,3-dimethylpent-2-ene (d) (b) E O N/A Br ()-5-bromo-1-chloro-3-ethyloct-4-ene ОЕ Z N/A Et (___)-3-ethyl-4-methylhex-3-ene E (f) Oz N/A z N/A HO (4.7)-4-(2-hydroxyethyl)-7-methylnona-4,7-dien-2-onearrow_forward
- O 9:21AM Tue Mar 4 ## 64% Problem 51 of 15 Submit Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s). Be sure to account for all bond-breaking and bond-making steps. H :0: CI. AI :CI: :CI: Cl AI Select to Add Arrows Select to Add Arrows O: Cl :CI: :0: H CI: CI CO Select to Add Arrows Select to Add Arrows :O: CI :0: Cl. 10: AIarrow_forward(i) Draw in the missing lone pair(s) of electrons of the reactants on the left (ii) Draw (curved) arrows to show the flow of electrons in the acid/base reaction on the left (iii) Draw the products of the acid/base on the right (iv) Select the correct label for each product as either "conjugate acid" or "conjugate base" (a) JOH OH NH₂ acid base (b) De "H conjugate acid conjugate acid conjugate base conjugate base acid base conjugate acid conjugate base conjugate acid conjugate base acid basearrow_forwardCould someone answer this NMR and explain please Comment on the general features of the 1H-NMR spectrum of isoamyl ester provided below.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
ChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill Education
Principles of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill Education
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY