PHYSICAL CHEMISTRY. VOL.1+2 (LL)(11TH)
11th Edition
ISBN: 9780198826910
Author: ATKINS
Publisher: Oxford University Press
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Question
Chapter 12, Problem 12B.7P
Interpretation Introduction
Interpretation:
The coupling constant expressed by the Karplus equation passes through a minimum when
Concept introduction:
The coupling constant is a way of measuring the interaction between protons. It has the units of frequency. Karplus equation is a relation between the coupling constant and dihedral angle which is the angle between two planes.
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a. The change in the Gibbs energy of a certain constant pressure process is found to fit the expression:
AG-85.1 J mol −1 +36.5 J mol ¹K-1 × T
A. Calculate the value of AS for the process.
B. Next, use the Gibbs-Helmholtz equation:
(a(AG/T))
ΔΗ
-
T2
to calculate the value of AH for the process.
None
Chapter 12 Solutions
PHYSICAL CHEMISTRY. VOL.1+2 (LL)(11TH)
Ch. 12 - Prob. 12B.1STCh. 12 - Prob. 12B.2STCh. 12 - Prob. 12B.3STCh. 12 - Prob. 12D.1STCh. 12 - Prob. 12A.1DQCh. 12 - Prob. 12A.2DQCh. 12 - Prob. 12A.3DQCh. 12 - Prob. 12A.1AECh. 12 - Prob. 12A.1BECh. 12 - Prob. 12A.2AE
Ch. 12 - Prob. 12A.2BECh. 12 - Prob. 12A.3AECh. 12 - Prob. 12A.3BECh. 12 - Prob. 12A.4AECh. 12 - Prob. 12A.4BECh. 12 - Prob. 12A.5AECh. 12 - Prob. 12A.5BECh. 12 - Prob. 12A.6AECh. 12 - Prob. 12A.6BECh. 12 - Prob. 12A.7AECh. 12 - Prob. 12A.7BECh. 12 - Prob. 12A.8AECh. 12 - Prob. 12A.8BECh. 12 - Prob. 12A.9AECh. 12 - Prob. 12A.9BECh. 12 - Prob. 12A.1PCh. 12 - Prob. 12A.3PCh. 12 - Prob. 12B.1DQCh. 12 - Prob. 12B.2DQCh. 12 - Prob. 12B.3DQCh. 12 - Prob. 12B.4DQCh. 12 - Prob. 12B.5DQCh. 12 - Prob. 12B.1AECh. 12 - Prob. 12B.1BECh. 12 - Prob. 12B.2AECh. 12 - Prob. 12B.2BECh. 12 - Prob. 12B.3AECh. 12 - Prob. 12B.3BECh. 12 - Prob. 12B.4AECh. 12 - Prob. 12B.4BECh. 12 - Prob. 12B.5AECh. 12 - Prob. 12B.5BECh. 12 - Prob. 12B.6AECh. 12 - Prob. 12B.6BECh. 12 - Prob. 12B.7AECh. 12 - Prob. 12B.7BECh. 12 - Prob. 12B.8AECh. 12 - Prob. 12B.8BECh. 12 - Prob. 12B.9AECh. 12 - Prob. 12B.9BECh. 12 - Prob. 12B.10AECh. 12 - Prob. 12B.10BECh. 12 - Prob. 12B.11AECh. 12 - Prob. 12B.11BECh. 12 - Prob. 12B.12AECh. 12 - Prob. 12B.12BECh. 12 - Prob. 12B.13AECh. 12 - Prob. 12B.13BECh. 12 - Prob. 12B.14AECh. 12 - Prob. 12B.14BECh. 12 - Prob. 12B.1PCh. 12 - Prob. 12B.2PCh. 12 - Prob. 12B.3PCh. 12 - Prob. 12B.5PCh. 12 - Prob. 12B.6PCh. 12 - Prob. 12B.7PCh. 12 - Prob. 12B.8PCh. 12 - Prob. 12B.9PCh. 12 - Prob. 12C.1DQCh. 12 - Prob. 12C.2DQCh. 12 - Prob. 12C.3DQCh. 12 - Prob. 12C.4DQCh. 12 - Prob. 12C.5DQCh. 12 - Prob. 12C.1AECh. 12 - Prob. 12C.1BECh. 12 - Prob. 12C.2AECh. 12 - Prob. 12C.2BECh. 12 - Prob. 12C.3AECh. 12 - Prob. 12C.3BECh. 12 - Prob. 12C.4AECh. 12 - Prob. 12C.4BECh. 12 - Prob. 12C.5AECh. 12 - Prob. 12C.5BECh. 12 - Prob. 12C.4PCh. 12 - Prob. 12C.5PCh. 12 - Prob. 12C.6PCh. 12 - Prob. 12C.10PCh. 12 - Prob. 12D.1DQCh. 12 - Prob. 12D.2DQCh. 12 - Prob. 12D.1AECh. 12 - Prob. 12D.1BECh. 12 - Prob. 12D.2AECh. 12 - Prob. 12D.2BECh. 12 - Prob. 12D.3AECh. 12 - Prob. 12D.3BECh. 12 - Prob. 12D.4AECh. 12 - Prob. 12D.4BECh. 12 - Prob. 12D.5AECh. 12 - Prob. 12D.5BECh. 12 - Prob. 12D.6AECh. 12 - Prob. 12D.6BECh. 12 - Prob. 12D.1PCh. 12 - Prob. 12D.2PCh. 12 - Prob. 12D.4PCh. 12 - Prob. 12D.5PCh. 12 - Prob. 12D.6PCh. 12 - Prob. 12D.7PCh. 12 - Prob. 12D.8PCh. 12 - Prob. 12.3IACh. 12 - Prob. 12.4IA
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