Chemistry - Modified MasteringChemistry
7th Edition
ISBN: 9780133892321
Author: McMurry
Publisher: PEARSON
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Chapter 12, Problem 12.82SP
Interpretation Introduction
Interpretation:
With the help of the solubility graph in figure, determine which member of each of the given pairs has the higher molar solubility at the given temperature.
Concept Introduction:
Molar solubility refers to the total number of moles of a substance that can be dissolved per litre of solution before the solution becomes saturated. The calculation of molar solubility is based on a substance's solubility product constant and stoichiometry. The unit used to denote molar solubility is mol/L, which is also written as M.
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AG/F-2° V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
-0.93
+0.38
-0.50
-0.51 -0.06
H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3
Acidic solution
Basic solution
-0.28
-0.50
3--1.12
-1.57
-2.05 -0.89
PO HPO H₂PO₂ →P → PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5
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P
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-0.5
-1.0-
-1.5-
-2.0
H.PO,
-2.3+
-3 -2
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b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
H,PO
4
S
Oxidation stale, N
Chapter 12 Solutions
Chemistry - Modified MasteringChemistry
Ch. 12 - Prob. 12.1PCh. 12 - Prob. 12.2ACh. 12 - Prob. 12.3PCh. 12 - Prob. 12.4ACh. 12 - PRACTICE 12.5 A 50.0 mL sample of drinking water...Ch. 12 - APPLY 12.6 The legal limit for human exposure to...Ch. 12 - PRACTICE 12.7 What mass in grams of a 0.500 m...Ch. 12 - APPLY 12.8 What is the molality of a solution...Ch. 12 - PRACTICE 12.9 The density at 20°C of a 0.500 M...Ch. 12 - APPLY 12.10 The density at 20°C of a 0.258 m...
Ch. 12 - Prob. 12.11PCh. 12 - APPLY 12.12 Use the Henry’s law constant you...Ch. 12 - PRACTICE 12.13 What is the vapor pressure in mm Hg...Ch. 12 - APPLY 12.14 A solution made by dissolving 8.110 g...Ch. 12 - Prob. 12.15PCh. 12 - Conceptual APPLY 12.16 The following diagram shows...Ch. 12 - PRACTICE 12.17 What is the vapor pressure of the...Ch. 12 - Conceptual APPLY 12.18 The following diagram shows...Ch. 12 - Prob. 12.19PCh. 12 - APPLY 12.20 The following phase diagram shows a...Ch. 12 - Prob. 12.21PCh. 12 - APPLY 12.22 Cells in the human eye have an osmotic...Ch. 12 - PRACTICE 12.23 A solution prepared by dissolving...Ch. 12 - Prob. 12.24ACh. 12 - PROBLEM 12.25 What is the difference between a...Ch. 12 - PROBLEM 12.26 Urea has a high solubility in blood...Ch. 12 - Prob. 12.27PCh. 12 - Prob. 12.28PCh. 12 - Many people take vitamin supplements to promote...Ch. 12 - Prob. 12.30CPCh. 12 - Prob. 12.31CPCh. 12 - Prob. 12.32CPCh. 12 - Prob. 12.33CPCh. 12 - Prob. 12.34CPCh. 12 - Prob. 12.35CPCh. 12 - Prob. 12.36CPCh. 12 - Prob. 12.37CPCh. 12 - Prob. 12.38CPCh. 12 - Prob. 12.39CPCh. 12 - Prob. 12.40SPCh. 12 - 12.41 Why do ionic substances with higher lattice...Ch. 12 - Prob. 12.42SPCh. 12 - Prob. 12.43SPCh. 12 - Classify the strongest type of intermolecular...Ch. 12 - Classify the strongest type of intermolecular...Ch. 12 - Prob. 12.46SPCh. 12 - Prob. 12.47SPCh. 12 - Prob. 12.48SPCh. 12 - Prob. 12.49SPCh. 12 - Prob. 12.50SPCh. 12 - Prob. 12.51SPCh. 12 - Prob. 12.52SPCh. 12 - Prob. 12.53SPCh. 12 - Prob. 12.54SPCh. 12 - Pentyl alcohol (Problem 12.54) is miscible with...Ch. 12 - Prob. 12.56SPCh. 12 - 12.57 The dissolution of NH4ClO4(s) in water is...Ch. 12 - Prob. 12.58SPCh. 12 - Prob. 12.59SPCh. 12 - Prob. 12.60SPCh. 12 - Prob. 12.61SPCh. 12 - Prob. 12.62SPCh. 12 - Prob. 12.63SPCh. 12 - Prob. 12.64SPCh. 12 - Prob. 12.65SPCh. 12 - Prob. 12.66SPCh. 12 - Prob. 12.67SPCh. 12 - Prob. 12.68SPCh. 12 - Prob. 12.69SPCh. 12 - Prob. 12.70SPCh. 12 - Prob. 12.71SPCh. 12 - Prob. 12.72SPCh. 12 - Prob. 12.73SPCh. 12 - Prob. 12.74SPCh. 12 - Prob. 12.75SPCh. 12 - Ethylene glycol, C2H6O2, is the principal...Ch. 12 - Ethylene glycol, C2H6O2, is a colorless liquid...Ch. 12 - Prob. 12.78SPCh. 12 - Prob. 12.79SPCh. 12 - Prob. 12.80SPCh. 12 - Prob. 12.81SPCh. 12 - Prob. 12.82SPCh. 12 - Prob. 12.83SPCh. 12 - Prob. 12.84SPCh. 12 - Hydrogen sulfide, H2S, is a toxic gas responsible...Ch. 12 - Prob. 12.86SPCh. 12 - Prob. 12.87SPCh. 12 - Prob. 12.88SPCh. 12 - Prob. 12.89SPCh. 12 - Prob. 12.90SPCh. 12 - Prob. 12.91SPCh. 12 - Prob. 12.92SPCh. 12 - Prob. 12.93SPCh. 12 - Prob. 12.94SPCh. 12 - Prob. 12.95SPCh. 12 - Prob. 12.96SPCh. 12 - Prob. 12.97SPCh. 12 - Prob. 12.98SPCh. 12 - Prob. 12.99SPCh. 12 - Prob. 12.100SPCh. 12 - Prob. 12.101SPCh. 12 - Prob. 12.102SPCh. 12 - Prob. 12.103SPCh. 12 - Prob. 12.104SPCh. 12 - Prob. 12.105SPCh. 12 - Prob. 12.106SPCh. 12 - Prob. 12.107SPCh. 12 - Prob. 12.108SPCh. 12 - Prob. 12.109SPCh. 12 - Prob. 12.110SPCh. 12 - Prob. 12.111SPCh. 12 - Prob. 12.112SPCh. 12 - Prob. 12.113SPCh. 12 - Prob. 12.114SPCh. 12 - Prob. 12.115SPCh. 12 - Prob. 12.116SPCh. 12 - Prob. 12.117SPCh. 12 - Prob. 12.118SPCh. 12 - Prob. 12.119SPCh. 12 - Prob. 12.120SPCh. 12 - Prob. 12.121SPCh. 12 - Prob. 12.122SPCh. 12 - Prob. 12.123SPCh. 12 - Prob. 12.124SPCh. 12 - Prob. 12.125SPCh. 12 - Prob. 12.126SPCh. 12 - Prob. 12.127SPCh. 12 - Prob. 12.128SPCh. 12 - Prob. 12.129SPCh. 12 - Prob. 12.130CPCh. 12 - Prob. 12.131CPCh. 12 - Prob. 12.132CPCh. 12 - Prob. 12.133CPCh. 12 - Prob. 12.134CPCh. 12 - Prob. 12.135CPCh. 12 - Prob. 12.136CPCh. 12 - Prob. 12.137CPCh. 12 - Prob. 12.138CPCh. 12 - There’s actually much more in seawater than just...Ch. 12 - Prob. 12.140CPCh. 12 - Prob. 12.141CPCh. 12 - Prob. 12.142CPCh. 12 - Prob. 12.143CPCh. 12 - Prob. 12.144CPCh. 12 - What is the value of the van’t Hoff factor for KCI...Ch. 12 - Prob. 12.146CPCh. 12 - Prob. 12.147CPCh. 12 - Prob. 12.148CPCh. 12 - Prob. 12.149CPCh. 12 - Prob. 12.150CPCh. 12 - Prob. 12.151CPCh. 12 - An aqueous solution of a certain organic compound...Ch. 12 - Prob. 12.153CPCh. 12 - Prob. 12.154CPCh. 12 - Prob. 12.155CPCh. 12 - Prob. 12.156CPCh. 12 - Prob. 12.157CPCh. 12 - Prob. 12.158CPCh. 12 - Prob. 12.159CPCh. 12 - Prob. 12.160MPCh. 12 - Prob. 12.161MPCh. 12 - Prob. 12.162MPCh. 12 - Prob. 12.163MPCh. 12 - Prob. 12.164MP
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY