
Chemistry - Modified MasteringChemistry
7th Edition
ISBN: 9780133892321
Author: McMurry
Publisher: PEARSON
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Chapter 12, Problem 12.15P
Interpretation Introduction
Interpretation:
“Amount of
Concept introduction:
- The moles of solute per kilogram of solvent is known as molality of the solution.
- Colligative properties of ideal or dilute solutions are depending upon the number of solute particles.
- Relative lowering in vapour pressure is a colligative property, which is proportional to the molal concentration of the solution.
Given:
Solvent =
Vapour pressure lowering= 1.30 mmHg
Vapor pressure of water at
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-AG|F=2E|V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
Acidic solution
-0.93
+0.38
-0.51 -0.06
H3PO4 →H4P206 H3PO3 H3PO2 → P→ PH3
-0.28
-0.50
→
-0.50
Basic solution
3-1.12
-1.57
-2.05 -0.89
PO HPO →→H2PO2 P PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P2O6 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5 PH,
0.0
-0.5-
2 3 9 3
-1.5
-2.0
Pa
H,PO
H,PO
H,PO
-3
-1 0
2
4
Oxidation state, N
2
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
c) Elemental phosphorus tends to disproportionate under basic conditions. Use data in…
These two reactions appear to start with the same starting materials but result in different products. How do the chemicals know which product to form? Are both products formed, or is there some information missing that will direct them a particular way?
What would be the best choices for the missing reagents 1 and 3 in this synthesis?
1. PPh3
3
1
2
2. n-BuLi
• Draw the missing reagents in the drawing area below. You can draw them in any arrangement you like.
• Do not draw the missing reagent 2. If you draw 1 correctly, we'll know what it is.
• Note: if one of your reagents needs to contain a halogen, use bromine.
Explanation
Check
Click and drag to start drawing a structure.
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Chapter 12 Solutions
Chemistry - Modified MasteringChemistry
Ch. 12 - Prob. 12.1PCh. 12 - Prob. 12.2ACh. 12 - Prob. 12.3PCh. 12 - Prob. 12.4ACh. 12 - PRACTICE 12.5 A 50.0 mL sample of drinking water...Ch. 12 - APPLY 12.6 The legal limit for human exposure to...Ch. 12 - PRACTICE 12.7 What mass in grams of a 0.500 m...Ch. 12 - APPLY 12.8 What is the molality of a solution...Ch. 12 - PRACTICE 12.9 The density at 20°C of a 0.500 M...Ch. 12 - APPLY 12.10 The density at 20°C of a 0.258 m...
Ch. 12 - Prob. 12.11PCh. 12 - APPLY 12.12 Use the Henry’s law constant you...Ch. 12 - PRACTICE 12.13 What is the vapor pressure in mm Hg...Ch. 12 - APPLY 12.14 A solution made by dissolving 8.110 g...Ch. 12 - Prob. 12.15PCh. 12 - Conceptual APPLY 12.16 The following diagram shows...Ch. 12 - PRACTICE 12.17 What is the vapor pressure of the...Ch. 12 - Conceptual APPLY 12.18 The following diagram shows...Ch. 12 - Prob. 12.19PCh. 12 - APPLY 12.20 The following phase diagram shows a...Ch. 12 - Prob. 12.21PCh. 12 - APPLY 12.22 Cells in the human eye have an osmotic...Ch. 12 - PRACTICE 12.23 A solution prepared by dissolving...Ch. 12 - Prob. 12.24ACh. 12 - PROBLEM 12.25 What is the difference between a...Ch. 12 - PROBLEM 12.26 Urea has a high solubility in blood...Ch. 12 - Prob. 12.27PCh. 12 - Prob. 12.28PCh. 12 - Many people take vitamin supplements to promote...Ch. 12 - Prob. 12.30CPCh. 12 - Prob. 12.31CPCh. 12 - Prob. 12.32CPCh. 12 - Prob. 12.33CPCh. 12 - Prob. 12.34CPCh. 12 - Prob. 12.35CPCh. 12 - Prob. 12.36CPCh. 12 - Prob. 12.37CPCh. 12 - Prob. 12.38CPCh. 12 - Prob. 12.39CPCh. 12 - Prob. 12.40SPCh. 12 - 12.41 Why do ionic substances with higher lattice...Ch. 12 - Prob. 12.42SPCh. 12 - Prob. 12.43SPCh. 12 - Classify the strongest type of intermolecular...Ch. 12 - Classify the strongest type of intermolecular...Ch. 12 - Prob. 12.46SPCh. 12 - Prob. 12.47SPCh. 12 - Prob. 12.48SPCh. 12 - Prob. 12.49SPCh. 12 - Prob. 12.50SPCh. 12 - Prob. 12.51SPCh. 12 - Prob. 12.52SPCh. 12 - Prob. 12.53SPCh. 12 - Prob. 12.54SPCh. 12 - Pentyl alcohol (Problem 12.54) is miscible with...Ch. 12 - Prob. 12.56SPCh. 12 - 12.57 The dissolution of NH4ClO4(s) in water is...Ch. 12 - Prob. 12.58SPCh. 12 - Prob. 12.59SPCh. 12 - Prob. 12.60SPCh. 12 - Prob. 12.61SPCh. 12 - Prob. 12.62SPCh. 12 - Prob. 12.63SPCh. 12 - Prob. 12.64SPCh. 12 - Prob. 12.65SPCh. 12 - Prob. 12.66SPCh. 12 - Prob. 12.67SPCh. 12 - Prob. 12.68SPCh. 12 - Prob. 12.69SPCh. 12 - Prob. 12.70SPCh. 12 - Prob. 12.71SPCh. 12 - Prob. 12.72SPCh. 12 - Prob. 12.73SPCh. 12 - Prob. 12.74SPCh. 12 - Prob. 12.75SPCh. 12 - Ethylene glycol, C2H6O2, is the principal...Ch. 12 - Ethylene glycol, C2H6O2, is a colorless liquid...Ch. 12 - Prob. 12.78SPCh. 12 - Prob. 12.79SPCh. 12 - Prob. 12.80SPCh. 12 - Prob. 12.81SPCh. 12 - Prob. 12.82SPCh. 12 - Prob. 12.83SPCh. 12 - Prob. 12.84SPCh. 12 - Hydrogen sulfide, H2S, is a toxic gas responsible...Ch. 12 - Prob. 12.86SPCh. 12 - Prob. 12.87SPCh. 12 - Prob. 12.88SPCh. 12 - Prob. 12.89SPCh. 12 - Prob. 12.90SPCh. 12 - Prob. 12.91SPCh. 12 - Prob. 12.92SPCh. 12 - Prob. 12.93SPCh. 12 - Prob. 12.94SPCh. 12 - Prob. 12.95SPCh. 12 - Prob. 12.96SPCh. 12 - Prob. 12.97SPCh. 12 - Prob. 12.98SPCh. 12 - Prob. 12.99SPCh. 12 - Prob. 12.100SPCh. 12 - Prob. 12.101SPCh. 12 - Prob. 12.102SPCh. 12 - Prob. 12.103SPCh. 12 - Prob. 12.104SPCh. 12 - Prob. 12.105SPCh. 12 - Prob. 12.106SPCh. 12 - Prob. 12.107SPCh. 12 - Prob. 12.108SPCh. 12 - Prob. 12.109SPCh. 12 - Prob. 12.110SPCh. 12 - Prob. 12.111SPCh. 12 - Prob. 12.112SPCh. 12 - Prob. 12.113SPCh. 12 - Prob. 12.114SPCh. 12 - Prob. 12.115SPCh. 12 - Prob. 12.116SPCh. 12 - Prob. 12.117SPCh. 12 - Prob. 12.118SPCh. 12 - Prob. 12.119SPCh. 12 - Prob. 12.120SPCh. 12 - Prob. 12.121SPCh. 12 - Prob. 12.122SPCh. 12 - Prob. 12.123SPCh. 12 - Prob. 12.124SPCh. 12 - Prob. 12.125SPCh. 12 - Prob. 12.126SPCh. 12 - Prob. 12.127SPCh. 12 - Prob. 12.128SPCh. 12 - Prob. 12.129SPCh. 12 - Prob. 12.130CPCh. 12 - Prob. 12.131CPCh. 12 - Prob. 12.132CPCh. 12 - Prob. 12.133CPCh. 12 - Prob. 12.134CPCh. 12 - Prob. 12.135CPCh. 12 - Prob. 12.136CPCh. 12 - Prob. 12.137CPCh. 12 - Prob. 12.138CPCh. 12 - There’s actually much more in seawater than just...Ch. 12 - Prob. 12.140CPCh. 12 - Prob. 12.141CPCh. 12 - Prob. 12.142CPCh. 12 - Prob. 12.143CPCh. 12 - Prob. 12.144CPCh. 12 - What is the value of the van’t Hoff factor for KCI...Ch. 12 - Prob. 12.146CPCh. 12 - Prob. 12.147CPCh. 12 - Prob. 12.148CPCh. 12 - Prob. 12.149CPCh. 12 - Prob. 12.150CPCh. 12 - Prob. 12.151CPCh. 12 - An aqueous solution of a certain organic compound...Ch. 12 - Prob. 12.153CPCh. 12 - Prob. 12.154CPCh. 12 - Prob. 12.155CPCh. 12 - Prob. 12.156CPCh. 12 - Prob. 12.157CPCh. 12 - Prob. 12.158CPCh. 12 - Prob. 12.159CPCh. 12 - Prob. 12.160MPCh. 12 - Prob. 12.161MPCh. 12 - Prob. 12.162MPCh. 12 - Prob. 12.163MPCh. 12 - Prob. 12.164MP
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY