(a)
Interpretation:
The IUPAC name for the given alcohol and its oxidation product has to be written.
(a)
Explanation of Solution
The given alcohol is,
Parent compound : pentane
Position of –OH : carbon – 3
Substituent : No substituent present
IUPAC Name : pentan-3-ol
Therefore, the
Pentan-3-ol is a secondary alcohol it undergoes oxidation reaction to produce 3-pentanone. The reaction can be shown as follows,
Parent compound : pentane
Position of
Substituent : No substituent present
IUPAC Name : pentan-3-one
Therefore, the IUPAC nomenclature for the given product is pentan-3-one.
(b)
Interpretation:
The IUPAC name for the given alcohol and its oxidation product has to be written.
(b)
Explanation of Solution
The given alcohol is,
Parent compound : propane
Position of –OH : carbon – 1
Substituent : No substituent present
IUPAC Name : propan-1-ol
Therefore, the IUPAC nomenclature for the given alcohol is propan-1-ol.
Propan-1-ol is a primary alcohol it undergoes oxidation reaction to produce propanal and forms propanoic acid on further oxidation. The reaction can be shown as follows,
Parent compound : propane
Position of
Substituent : No substituent present
IUPAC Name : propan-1-al
Therefore, the IUPAC nomenclature for the given product is propan-1-al.
(c)
Interpretation:
The IUPAC name for the given alcohol and its oxidation product has to be written.
(c)
Explanation of Solution
The given alcohol is,
Parent compound : pentane
Position of –OH : carbon – 2
Substituent : 4-methyl
IUPAC Name : 4-methylpentan-2-ol
Therefore, the IUPAC nomenclature for the given alcohol is 4-methylpentan-2-ol.
4-methylpentan-2-ol is a secondary alcohol it undergoes oxidation reaction to produce 4-methylpentan-2-one. The reaction can be shown as follows,
Parent compound : pentane
Position of
Substituent : 4-methyl
IUPAC Name : 4-methylpentan-2-one
Therefore, the IUPAC nomenclature for the given product is 4-methylpentan-2-one.
(d)
Interpretation:
The IUPAC name for the given alcohol and its oxidation product has to be written.
(d)
Explanation of Solution
The given alcohol is,
Parent compound : butane
Position of –OH : carbon – 2
Substituent : 2-methyl
IUPAC Name : 2-methylbutan-2-ol
Therefore, the IUPAC nomenclature for the given alcohol is 2-methylbutan-2-ol.
2-methylbutan-2-ol is a tertiary alcohol it does not undergoes oxidation reaction. Hence the it considered as N.R and it can be shown as follows,
(e)
Interpretation:
The IUPAC name for the given alcohol and its oxidation product has to be written.
(e)
Explanation of Solution
The given alcohol is,
Parent compound : propane
Position of –OH : carbon – 1
Substituent : 3-phenyl
IUPAC Name : 3-phenylpropan-1-ol
Therefore, the IUPAC nomenclature for the given alcohol is 3-phenylpropan-1-ol.
3-phenylpropan-1-ol is a primary alcohol it undergoes oxidation reaction to produce 3-phenylpropan-1-al and forms 3-phenylpropanoic acid on further oxidation. The reaction can be shown as follows,
Parent compound : propane
Position of
Substituent : 3-phenyl
IUPAC Name : 3-phenylpropan-1-al
Therefore, the IUPAC nomenclature for the given product is 3-phenylpropan-1-al.
Want to see more full solutions like this?
Chapter 12 Solutions
Connect 1-Semester Access Card for General, Organic, and Biochemistry
- In an electrolytic cell, indicate the formula that relates E0 to the temperature T.arrow_forward-- 14:33 A Candidate Identification docs.google.com 11. Compound A can transform into compound B through an organic reaction. From the structures below, mark the correct one: HO A تھے۔ די HO B ○ A) Compounds A and B are isomers. B) Both have the same number of chiral carbons. C) Compound A underwent an addition reaction of Cl2 and H2O to form compound B. D) Compound A underwent a substitution reaction forming the intermediate chlorohydrin to obtain compound B. E) Compound A underwent an addition reaction of Cl2 forming the chloronium ion and then added methanol to obtain compound B. 60arrow_forward-- 14:40 A Candidate Identification docs.google.com 13. The compound 1-bromo-hex-2-ene reacts with methanol to form two products. About this reaction, mark the correct statement: OCH3 CH3OH Br OCH3 + + HBr A B A) The two products formed will have the same percentage of formation. B) Product B will be formed by SN1 substitution reaction with the formation of an allylic carbocation. C) Product A will be formed by SN1 substitution reaction with the formation of a more stable carbocation than product B. D) Product A will be formed by an SN2 substitution reaction occurring in two stages, the first with slow kinetics and the second with fast kinetics. E) The two compounds were obtained by addition reaction, with compound B having the highest percentage of formation. 57arrow_forward
- -- ☑ 14:30 A Candidate Identification docs.google.com 10. Amoxicillin (figure X) is one of the most widely used antibiotics in the penicillin family. The discovery and synthesis of these antibiotics in the 20th century made the treatment of infections that were previously fatal routine. About amoxicillin, mark the correct one: HO NH2 H S -N. HO Figura X. Amoxicilina A) It has the organic functions amide, ester, phenol and amine. B) It has four chiral carbons and 8 stereoisomers. C) The substitution of the aromatic ring is of the ortho-meta type. D) If amoxicillin reacts with an alcohol it can form an ester. E) The structure has two tertiary amides. 62arrow_forwardThe environmental police of a Brazilian state received a report of contamination of a river by inorganic arsenic, due to the excessive use of pesticides on a plantation on the riverbanks. Arsenic (As) is extremely toxic in its many forms and oxidation states. In nature, especially in groundwater, it is found in the form of arsenate (AsO ₄ ³ ⁻ ), which can be electrochemically reduced to As ⁰ and collected at the cathode of a coulometric cell. In this case, Potentiostatic Coulometry (at 25°C) was performed in an alkaline medium (pH = 7.5 throughout the analysis) to quantify the species. What potential (E) should have been selected/applied to perform the analysis, considering that this is an exhaustive electrolysis technique (until 99.99% of all AsO ₄ ³ ⁻ has been reduced to As ⁰ at the electrode, or n( final) = 0.01% n( initial )) and that the concentration of AsO ₄ ³ ⁻ found in the initial sample was 0.15 mmol/L ? Data: AsO ₄ 3 ⁻ (aq) + 2 H ₂ O ( l ) + 2 e ⁻ → A s O ₂ ⁻ ( a…arrow_forward-- 14:17 15. Water-soluble proteins are denatured when there is a change in the pH of the environment in which they are found. This occurs due to the protonation and deprotonation of functional groups present in their structure. Choose the option that indicates the chemical bonds modified by pH in the protein represented in the following figure. E CH2 C-OH CH2 H₂C H₁C CH CH3 CH3 CH CH₂-S-S-CH₂- 910 H B -CH2-CH2-CH2-CH₂-NH3* −0—C—CH₂- ○ A) A, C e D. • В) Вес ○ C) DeE ○ D) B, De E ○ E) A, B e C 68arrow_forward
- Suppose sodium sulfate has been gradually added to 100 mL of a solution containing calcium ions and strontium ions, both at 0.15 mol/L. Indicate the alternative that presents the percentage of strontium ions that will have precipitated when the calcium sulfate begins to precipitate. Data: Kps of calcium sulfate: 2.4x10 ⁻ ⁵; Kps of strontium sulfate: 3.2x10 ⁻ ⁷ A) 20,2 % B) 36,6 % C) 62,9 % D) 87,5 % E) 98.7%arrow_forward14:43 A Candidate Identification docs.google.com 14. The following diagrams represent hypothetical membrane structures with their components numbered from 1 to 6. Based on the figures and your knowledge of biological membranes, select the correct alternative. | 3 5 || 人 2 500000 6 A) Structures 1, 3, 5, 2 and 4 are present in a constantly fluid arrangement that allows the selectivity of the movement ○ of molecules. Structure 4, present integrally or peripherally, is responsible for this selection, while the quantity of 6 regulates the fluidity. B) The membranes isolate the cell from the environment, but allow the passage of water-soluble molecules thanks to the presence of 2 and 3. The membrane in scheme is more fluid than that in 55arrow_forward12. Mark the correct statement about reactions a and b : a. Br + -OH Br b. + Br H₂O + Br -OH + H₂O A) The reactions are elimination reactions, with reaction "a" being of type E2 and reaction "b" being of type E1. B) Reaction "a" is an E2 type elimination occurring in one step and reaction "b" is an SN1 type substitution. C) Both reactions can result in the formation of carbocation, but in reaction "b" the most stable carbocation will be formed. D) Both reactions occur at the same rate ○ and have the same number of reaction steps. E) Reaction "b" is an E2 type elimination occurring in two steps and reaction "a" is an SN2 type substitution.arrow_forward
- Chloroform, long used as an anesthetic and now considered carcinogenic, has a heat of vaporization of 31.4 kJ/mol. During vaporization, its entropy increases by 94.2 J/mol.K. Therefore, select the alternative that indicates the temperature, in degrees Celsius, at which chloroform begins to boil under a pressure of 1 atm. A) 28 B) 40 C) 52 D) 60 E) 72arrow_forwardIf we assume a system with an anodic overpotential, the variation of n as a function of current density: 1. at low fields is linear 2. at higher fields, it follows Tafel's law Obtain the range of current densities for which the overpotential has the same value when calculated for 1 and 2 cases (maximum relative difference of 5% compared to the behavior for higher fields). To which overpotential range does this correspond? Data: i = 1.5 mA cm², T = 300°C, B = 0.64, R = 8.314 J K1 mol-1 and F = 96485 C mol-1.arrow_forwardAnswer by equation pleasearrow_forward
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
ChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill Education
Principles of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill Education
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY