
General Chemistry
11th Edition
ISBN: 9781305859142
Author: Ebbing, Darrell D., Gammon, Steven D.
Publisher: Cengage Learning,
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Question
Chapter 12, Problem 12.4QP
Interpretation Introduction
Interpretation:
The wide range of solubility of ionic compounds in water has to be explained.
Concept Introduction:
- Solubility of an ionic compound is primarily influenced by – lattice energy, hydration energy and ion-dipole interaction.
- The energy released when gaseous state ions of unlike charges that are infinitely farther apart combine to form a stable ionic solid is called Lattice energy. Conversely, the energy required to break the electrostatic force of attraction between the ions of unlike charges in the ionic solid and revert them to gaseous state is also termed as Lattice energy of an ionic solid.
- Hydration energy refers to the quantity of energy released when one mole of ion gets hydrated at constant pressure. Hydration energy of an ion depends upon its ionic size.
- Ion-dipole attraction is the attractive force between ion (from the solute) and a dipole (from polar solvent).
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Chapter 12 Solutions
General Chemistry
Ch. 12.1 - Prob. 12.1ECh. 12.1 - Identify the solute(s) and solvent(s) in the...Ch. 12.2 - Prob. 12.2CCCh. 12.2 - Which of the following compounds is likely to be...Ch. 12.2 - Which ion has the larger hydration energy, Na+ or...Ch. 12.2 - Prob. 12.3CCCh. 12.3 - A liter of water at 25C dissolves 0.0404 g O2 when...Ch. 12.3 - Most fish have a very difficult time surviving at...Ch. 12.4 - An experiment calls for 35.0 g of hydrochloric...Ch. 12.4 - Toluene, C6H5CH3, is a liquid compound similar to...
Ch. 12.4 - Prob. 12.7ECh. 12.4 - A solution is 0.120 m methanol dissolved in...Ch. 12.4 - A solution is 0.250 mole fraction methanol, CH3OH,...Ch. 12.4 - Urea, (NH2)2CO, is used as a fertilizer (sec the...Ch. 12.4 - Prob. 12.11ECh. 12.5 - Naphthalene, C10H8, is used to make mothballs....Ch. 12.5 - Prob. 12.5CCCh. 12.6 - How many grams of ethylene glycol, CH2OHCH2OH,...Ch. 12.6 - A 0.930-g sample of ascorbic acid (vitamin C) was...Ch. 12.6 - A 0.205-g sample of white phosphorus was dissolved...Ch. 12.7 - Calculate the osmotic pressure at 20C of an...Ch. 12.7 - Prob. 12.6CCCh. 12.8 - Prob. 12.17ECh. 12.8 - Each of the following substances is dissolved in a...Ch. 12.9 - Prob. 12.18ECh. 12.9 - If electrodes that are connected to a direct...Ch. 12 - Prob. 12.1QPCh. 12 - Prob. 12.2QPCh. 12 - Explain in terms of intermolecular attractions why...Ch. 12 - Prob. 12.4QPCh. 12 - Using the concept of hydration, describe the...Ch. 12 - What is the usual solubility behavior of an ionic...Ch. 12 - Give one example of each: a salt whose heat of...Ch. 12 - What do you expect to happen to a concentration of...Ch. 12 - Prob. 12.9QPCh. 12 - Pressure has an effect on the solubility of oxygen...Ch. 12 - Prob. 12.11QPCh. 12 - When two beakers containing different...Ch. 12 - Prob. 12.13QPCh. 12 - Prob. 12.14QPCh. 12 - Prob. 12.15QPCh. 12 - Prob. 12.16QPCh. 12 - One can often see sunbeams passing through the...Ch. 12 - Prob. 12.18QPCh. 12 - Explain on the basis that like dissolves like why...Ch. 12 - Prob. 12.20QPCh. 12 - Calculate the number of moles of barium chloride...Ch. 12 - Prob. 12.22QPCh. 12 - If 291g of a compound is added to 1.02 kg of water...Ch. 12 - A 5.1-g sample of CaCl2 is dissolved in a beaker...Ch. 12 - Consider two hypothetical pure substances, AB(s)...Ch. 12 - Equal numbers of moles of two soluble, substances,...Ch. 12 - Even though the oxygen demands of trout and bass...Ch. 12 - You want to purchase a salt to melt snow and ice...Ch. 12 - Prob. 12.29QPCh. 12 - Prob. 12.30QPCh. 12 - Prob. 12.31QPCh. 12 - Consider the following dilute NaCl(aq) solutions....Ch. 12 - Prob. 12.33QPCh. 12 - Prob. 12.34QPCh. 12 - If l-mol samples of urea, a nonelectrolyte, sodium...Ch. 12 - Prob. 12.36QPCh. 12 - Prob. 12.37QPCh. 12 - Prob. 12.38QPCh. 12 - Prob. 12.39QPCh. 12 - Prob. 12.40QPCh. 12 - Arrange the following substances in order of...Ch. 12 - Indicate which of the following is more soluble in...Ch. 12 - Prob. 12.43QPCh. 12 - Which of the following ions would be expected to...Ch. 12 - Arrange the following alkaline-earth-metal iodates...Ch. 12 - Explain the trends in solubility (grams per 100 mL...Ch. 12 - The solubility of carbon dioxide in water is 0.161...Ch. 12 - Prob. 12.48QPCh. 12 - Prob. 12.49QPCh. 12 - Prob. 12.50QPCh. 12 - Prob. 12.51QPCh. 12 - Prob. 12.52QPCh. 12 - Vanillin, C2H2O3, occurs naturally in vanilla...Ch. 12 - Lauryl alcohol, C12H25OH, is prepared from coconut...Ch. 12 - Fructose, C6H12O6, is a sugar occurring in honey...Ch. 12 - Caffeine. C8H10N4O2, is a stimulant found in tea...Ch. 12 - A 100.0-g sample of a brand of rubbing alcohol...Ch. 12 - An automobile antifreeze solution contains 2.50 kg...Ch. 12 - Prob. 12.59QPCh. 12 - Prob. 12.60QPCh. 12 - Concentrated hydrochloric acid contains 1.00 mol...Ch. 12 - Concentrated aqueous ammonia contains 1.00 mol NH3...Ch. 12 - Prob. 12.63QPCh. 12 - Prob. 12.64QPCh. 12 - A solution of vinegar is 0.763 M acetic arid,...Ch. 12 - A beverage contains tartaric acid, H2C4H4O6, a...Ch. 12 - Calculate the vapor pressure at 35C of a solution...Ch. 12 - What is the vapor pressure at 23C of a solution of...Ch. 12 - What is the boiling point of a solution of 0.133 g...Ch. 12 - A solution was prepared by dissolving 0.800 g of...Ch. 12 - An aqueous solution of a molecular compound...Ch. 12 - Urea, (NH2)2CO, is dissolved in 250.0 g of water....Ch. 12 - Prob. 12.73QPCh. 12 - Prob. 12.74QPCh. 12 - Safrole is contained in oil of sassafras and was...Ch. 12 - Butylated hydroxytoluene (BHT) is used as an...Ch. 12 - Prob. 12.77QPCh. 12 - Prob. 12.78QPCh. 12 - What is the freezing point of 0.0075 m aqueous...Ch. 12 - What is the freezing point of 0.0088 m aqueous...Ch. 12 - Prob. 12.81QPCh. 12 - In a mountainous location, the boiling point of...Ch. 12 - Prob. 12.83QPCh. 12 - Prob. 12.84QPCh. 12 - Prob. 12.85QPCh. 12 - Prob. 12.86QPCh. 12 - A gaseous mixture consists of 87.0 mole percent N2...Ch. 12 - A natural gas mixture consists of 88.0 mole...Ch. 12 - Prob. 12.89QPCh. 12 - Prob. 12.90QPCh. 12 - A 55-g sample of a gaseous fuel mixture contains...Ch. 12 - Prob. 12.92QPCh. 12 - A liquid solution consists of 0.30 mole fraction...Ch. 12 - What is the total vapor pressure at 20C of a...Ch. 12 - A sample of potassium aluminum sulfate 12-hydrate....Ch. 12 - A sample of aluminum sulfate 18-hydrate,...Ch. 12 - Urea, (NH2)2CO, has been used to melt ice from...Ch. 12 - Calcium chloride, CaCl2, has been used to melt ice...Ch. 12 - Prob. 12.99QPCh. 12 - Prob. 12.100QPCh. 12 - Which aqueous solution has the lower freezing...Ch. 12 - Which aqueous solution has the lower boiling...Ch. 12 - Commercially, sulfuric acid is usually obtained as...Ch. 12 - Prob. 12.104QPCh. 12 - A compound of manganese, carbon, and oxygen...Ch. 12 - A compound of cobalt, carbon, and oxygen contains...Ch. 12 - The carbohydrate digitoxose contains 48.64% carbon...Ch. 12 - Analysis of a compound gave 39.50% C, 2.21% H, and...Ch. 12 - Fish blood has an osmotic pressure equal to that...Ch. 12 - Prob. 12.110QPCh. 12 - Prob. 12.111QPCh. 12 - Prob. 12.112QPCh. 12 - How are phospholipids similar in structure to a...Ch. 12 - Prob. 12.114QPCh. 12 - Two samples of sodium chloride solutions are...Ch. 12 - Prob. 12.116QPCh. 12 - You have an aqueous, dilute solution of a...Ch. 12 - Prob. 12.118QPCh. 12 - Prob. 12.119QPCh. 12 - Prob. 12.120QPCh. 12 - When 79.3 g of a particular compound is dissolved...Ch. 12 - What is the boiling point of a solution made by...Ch. 12 - Prob. 12.123QPCh. 12 - Prob. 12.124QPCh. 12 - Prob. 12.125QPCh. 12 - Prob. 12.126QPCh. 12 - Prob. 12.127QPCh. 12 - Prob. 12.128QPCh. 12 - An aqueous solution is 0.797 M magnesium chloride....Ch. 12 - A CaCl2 solution at 25C has an osmotic pressure of...Ch. 12 - Prob. 12.131QPCh. 12 - Prob. 12.132QPCh. 12 - The lattice enthalpy of sodium chloride, H for...Ch. 12 - Prob. 12.134QPCh. 12 - Prob. 12.135QPCh. 12 - Prob. 12.136QPCh. 12 - Prob. 12.137QPCh. 12 - An aqueous solution is 20.0% by mass of sodium...Ch. 12 - Prob. 12.139QPCh. 12 - The freezing point of 0.109 m aqueous formic acid...Ch. 12 - A compound of carbon, hydrogen, and oxygen was...Ch. 12 - A compound of carbon, hydrogen, and oxygen was...
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