Chemistry, Books a la Carte Plus Mastering Chemistry with eText -- Access Card Package (7th Edition)
7th Edition
ISBN: 9780133900811
Author: John E. McMurry, Robert C. Fay, Jill Kirsten Robinson
Publisher: PEARSON
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Chapter 12, Problem 12.32CP
(a)
Interpretation Introduction
To determine:
The approximate normal boiling point of pure ether
(b)
Interpretation Introduction
To determine:
The approximate molal concentration of the solute.
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Review of this week's reaction:
H₂NCN (cyanamide) + CH3NHCH2COOH (sarcosine) + NaCl, NH4OH, H₂O --->
H₂NC(=NH)N(CH3)CH2COOH (creatine)
Q7. Draw by hand the reaction of creatine synthesis listed above using line structures without showing
the Cs and some of the Hs, but include the lone pairs of electrons wherever they apply. (4 pts)
Q8. Considering the Zwitterion form of an amino acid, draw the Zwitterion form of Creatine. (2 pts)
Q9. Explain with drawing why the C-N bond shown in creatine structure below can or cannot rotate. (3
pts)
NH2(C=NH)-N(CH)CH2COOH
This bond
Q10. Draw two tautomers of creatine using line structures. (Note: this question is valid because problem
Q9 is valid). (4 pts)
Q11. Mechanism. After seeing and understanding the mechanism of creatine synthesis, students should
be ready to understand the first half of one of the Grignard reactions presented in a past…
Propose a synthesis pathway for the
following transformations. b) c) d)
The rate coefficient of the gas-phase reaction 2 NO2 + O3 → N2O5 + O2 is 2.0x104 mol–1 dm3 s–1 at 300 K. Indicate whether the order of the reaction is 0, 1, or 2.
Chapter 12 Solutions
Chemistry, Books a la Carte Plus Mastering Chemistry with eText -- Access Card Package (7th Edition)
Ch. 12 - Prob. 12.1PCh. 12 - Prob. 12.2ACh. 12 - Prob. 12.3PCh. 12 - Prob. 12.4ACh. 12 - PRACTICE 12.5 A 50.0 mL sample of drinking water...Ch. 12 - APPLY 12.6 The legal limit for human exposure to...Ch. 12 - PRACTICE 12.7 What mass in grams of a 0.500 m...Ch. 12 - APPLY 12.8 What is the molality of a solution...Ch. 12 - PRACTICE 12.9 The density at 20°C of a 0.500 M...Ch. 12 - APPLY 12.10 The density at 20°C of a 0.258 m...
Ch. 12 - Prob. 12.11PCh. 12 - APPLY 12.12 Use the Henry’s law constant you...Ch. 12 - PRACTICE 12.13 What is the vapor pressure in mm Hg...Ch. 12 - APPLY 12.14 A solution made by dissolving 8.110 g...Ch. 12 - Prob. 12.15PCh. 12 - Conceptual APPLY 12.16 The following diagram shows...Ch. 12 - PRACTICE 12.17 What is the vapor pressure of the...Ch. 12 - Conceptual APPLY 12.18 The following diagram shows...Ch. 12 - Prob. 12.19PCh. 12 - APPLY 12.20 The following phase diagram shows a...Ch. 12 - Prob. 12.21PCh. 12 - APPLY 12.22 Cells in the human eye have an osmotic...Ch. 12 - PRACTICE 12.23 A solution prepared by dissolving...Ch. 12 - Prob. 12.24ACh. 12 - PROBLEM 12.25 What is the difference between a...Ch. 12 - PROBLEM 12.26 Urea has a high solubility in blood...Ch. 12 - Prob. 12.27PCh. 12 - Prob. 12.28PCh. 12 - Many people take vitamin supplements to promote...Ch. 12 - Prob. 12.30CPCh. 12 - Prob. 12.31CPCh. 12 - Prob. 12.32CPCh. 12 - Prob. 12.33CPCh. 12 - Prob. 12.34CPCh. 12 - Prob. 12.35CPCh. 12 - Prob. 12.36CPCh. 12 - Prob. 12.37CPCh. 12 - Prob. 12.38CPCh. 12 - Prob. 12.39CPCh. 12 - Prob. 12.40SPCh. 12 - 12.41 Why do ionic substances with higher lattice...Ch. 12 - Prob. 12.42SPCh. 12 - Prob. 12.43SPCh. 12 - Classify the strongest type of intermolecular...Ch. 12 - Classify the strongest type of intermolecular...Ch. 12 - Prob. 12.46SPCh. 12 - Prob. 12.47SPCh. 12 - Prob. 12.48SPCh. 12 - Prob. 12.49SPCh. 12 - Prob. 12.50SPCh. 12 - Prob. 12.51SPCh. 12 - Prob. 12.52SPCh. 12 - Prob. 12.53SPCh. 12 - Prob. 12.54SPCh. 12 - Pentyl alcohol (Problem 12.54) is miscible with...Ch. 12 - Prob. 12.56SPCh. 12 - 12.57 The dissolution of NH4ClO4(s) in water is...Ch. 12 - Prob. 12.58SPCh. 12 - Prob. 12.59SPCh. 12 - Prob. 12.60SPCh. 12 - Prob. 12.61SPCh. 12 - Prob. 12.62SPCh. 12 - Prob. 12.63SPCh. 12 - Prob. 12.64SPCh. 12 - Prob. 12.65SPCh. 12 - Prob. 12.66SPCh. 12 - Prob. 12.67SPCh. 12 - Prob. 12.68SPCh. 12 - Prob. 12.69SPCh. 12 - Prob. 12.70SPCh. 12 - Prob. 12.71SPCh. 12 - Prob. 12.72SPCh. 12 - Prob. 12.73SPCh. 12 - Prob. 12.74SPCh. 12 - Prob. 12.75SPCh. 12 - Ethylene glycol, C2H6O2, is the principal...Ch. 12 - Ethylene glycol, C2H6O2, is a colorless liquid...Ch. 12 - Prob. 12.78SPCh. 12 - Prob. 12.79SPCh. 12 - Prob. 12.80SPCh. 12 - Prob. 12.81SPCh. 12 - Prob. 12.82SPCh. 12 - Prob. 12.83SPCh. 12 - Prob. 12.84SPCh. 12 - Hydrogen sulfide, H2S, is a toxic gas responsible...Ch. 12 - Prob. 12.86SPCh. 12 - Prob. 12.87SPCh. 12 - Prob. 12.88SPCh. 12 - Prob. 12.89SPCh. 12 - Prob. 12.90SPCh. 12 - Prob. 12.91SPCh. 12 - Prob. 12.92SPCh. 12 - Prob. 12.93SPCh. 12 - Prob. 12.94SPCh. 12 - Prob. 12.95SPCh. 12 - Prob. 12.96SPCh. 12 - Prob. 12.97SPCh. 12 - Prob. 12.98SPCh. 12 - Prob. 12.99SPCh. 12 - Prob. 12.100SPCh. 12 - Prob. 12.101SPCh. 12 - Prob. 12.102SPCh. 12 - Prob. 12.103SPCh. 12 - Prob. 12.104SPCh. 12 - Prob. 12.105SPCh. 12 - Prob. 12.106SPCh. 12 - Prob. 12.107SPCh. 12 - Prob. 12.108SPCh. 12 - Prob. 12.109SPCh. 12 - Prob. 12.110SPCh. 12 - Prob. 12.111SPCh. 12 - Prob. 12.112SPCh. 12 - Prob. 12.113SPCh. 12 - Prob. 12.114SPCh. 12 - Prob. 12.115SPCh. 12 - Prob. 12.116SPCh. 12 - Prob. 12.117SPCh. 12 - Prob. 12.118SPCh. 12 - Prob. 12.119SPCh. 12 - Prob. 12.120SPCh. 12 - Prob. 12.121SPCh. 12 - Prob. 12.122SPCh. 12 - Prob. 12.123SPCh. 12 - Prob. 12.124SPCh. 12 - Prob. 12.125SPCh. 12 - Prob. 12.126SPCh. 12 - Prob. 12.127SPCh. 12 - Prob. 12.128SPCh. 12 - Prob. 12.129SPCh. 12 - Prob. 12.130CPCh. 12 - Prob. 12.131CPCh. 12 - Prob. 12.132CPCh. 12 - Prob. 12.133CPCh. 12 - Prob. 12.134CPCh. 12 - Prob. 12.135CPCh. 12 - Prob. 12.136CPCh. 12 - Prob. 12.137CPCh. 12 - Prob. 12.138CPCh. 12 - There’s actually much more in seawater than just...Ch. 12 - Prob. 12.140CPCh. 12 - Prob. 12.141CPCh. 12 - Prob. 12.142CPCh. 12 - Prob. 12.143CPCh. 12 - Prob. 12.144CPCh. 12 - What is the value of the van’t Hoff factor for KCI...Ch. 12 - Prob. 12.146CPCh. 12 - Prob. 12.147CPCh. 12 - Prob. 12.148CPCh. 12 - Prob. 12.149CPCh. 12 - Prob. 12.150CPCh. 12 - Prob. 12.151CPCh. 12 - An aqueous solution of a certain organic compound...Ch. 12 - Prob. 12.153CPCh. 12 - Prob. 12.154CPCh. 12 - Prob. 12.155CPCh. 12 - Prob. 12.156CPCh. 12 - Prob. 12.157CPCh. 12 - Prob. 12.158CPCh. 12 - Prob. 12.159CPCh. 12 - Prob. 12.160MPCh. 12 - Prob. 12.161MPCh. 12 - Prob. 12.162MPCh. 12 - Prob. 12.163MPCh. 12 - Prob. 12.164MP
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY