Organic Chemistry, Ebook And Single-course Homework Access
Organic Chemistry, Ebook And Single-course Homework Access
6th Edition
ISBN: 9781319085841
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 12, Problem 12.31AP
Interpretation Introduction

(a)

Interpretation:

The diagram for three different vibrational modes of water is to be drawn.

Concept introduction:

A molecule is made up of atoms that are bonded together by covalent bonds. These bonds have a to and fro movement. Vibrational spectroscopy is observed due to vibration in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Interpretation Introduction

(b)

Interpretation:

The different vibrations are to be classified as stretching or bending vibrations.

Concept introduction:

A molecule is made up of atoms that are bonded together by covalent bonds. These bonds have a to and fro movement. Vibrational spectroscopy is observed due to vibration in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

Interpretation Introduction

(c)

Interpretation:

The vibrations of water vapor in the IR spectrum are to be classified as stretching or bending vibrations.

Concept introduction:

A molecule is made up of atoms that are bonded together by covalent bonds. These bonds have a to and fro movement. Vibrational spectroscopy is observed due to vibration in a molecule. The molecule possessing vibrational spectrum undergoes a change in its dipole moment for a particular mode of vibration.

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Part II. two unbranched ketone have molecular formulla (C8H100). El-ms showed that both of them have a molecular ion peak at m/2 =128. However ketone (A) has a fragment peak at m/2 = 99 and 72 while ketone (B) snowed a fragment peak at m/2 = 113 and 58. 9) Propose the most plausible structures for both ketones b) Explain how you arrived at your conclusion by drawing the Structures of the distinguishing fragments for each ketone, including their fragmentation mechanisms.
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