Organic Chemistry, Ebook And Single-course Homework Access
Organic Chemistry, Ebook And Single-course Homework Access
6th Edition
ISBN: 9781319085841
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 12, Problem 12.7P
Interpretation Introduction

Interpretation:

The stretching frequency of CO bond vibration is to be stated.

Concept introduction:

Wavelength is the distance between the two crests or troughs of the wave. It is denoted by the symbol (λ). Frequency is defined as the number of waves passing through a point in unit time. It is denoted by the symbol (ν) Wavelength and frequency both are inversely proportional to each other.

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1. Using radii from Resource section 1 (p.901) and Born-Lande equation, calculate the lattice energy for PbS, which crystallizes in the NaCl structure. Then, use the Born-Haber cycle to obtain the value of lattice energy for PbS. You will need the following data following data: AH Pb(g) = 196 kJ/mol; AHƒ PbS = −98 kJ/mol; electron affinities for S(g)→S¯(g) is -201 kJ/mol; S¯(g) (g) is 640kJ/mol. Ionization energies for Pb are listed in Resource section 2, p.903. Remember that enthalpies of formation are calculated beginning with the elements in their standard states (S8 for sulfur). The formation of S2, AHF: S2 (g) = 535 kJ/mol. Compare the two values, and explain the difference. (8 points)
In the answer box, type the number of maximum stereoisomers possible for the following compound. A H H COH OH = H C Br H.C OH CH
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