GENERAL ORGANIC+BIO...(LL)-W/MOD.ACCESS
3rd Edition
ISBN: 9780134466699
Author: FROST
Publisher: PEARSON
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Chapter 12, Problem 12.21PP
Summary Introduction
To determine:
The ATP molecules that are produced when one molecule of glucose undergoes glycolysis.
Introduction:
The glycolysis is the process of conversion of glucose to pyruvate. A glycolysis includes 10
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5.
Use the MS data to answer the questions on the next page.
14.0
1.4
15.0
8.1
100-
MS-IW-5644
26.0
2.8
27.0
6.7
28.0
1.8
29.0
80
4.4
38.0
1.0
39.0
1.5
41.0
1.2
42.0
11.2
43.0
100.0
44.0
4.3
79.0
1.9
80.0
2.6
Relative Intensity
40
81.0
1.9
82.0
2.5
93.0
8.7
20-
95.0
8.2
121.0
2.0
123.0
2.0
136.0
11.8
0
138.0
11.5
20
40
8.
60
a.
Br
- 0
80
100
120
140
160
180
200
220
m/z
Identify the m/z of the base peak and molecular ion.
2
b.
Draw structures for each of the following fragments (include electrons and charges): 43.0, 93.0,
95.0, 136.0, and 138.0 m/z.
C.
Draw a reasonable a-fragmentation mechanism for the fragmentation of the molecular ion to
fragment 43.0 m/z. Be sure to include all electrons and formal charges.
6. Using the values provided in Appendix E of your lab manual, calculate the monoisotopic mass for the pyridinium
ion (CsH6N) and show your work.
None
Stereochemistry: Three possible answers- diastereomers, enantiomers
OH
CH₂OH
I
-c=0
21108 1101
41745 HOR
CH₂OH
IL
Но
CH₂OH
TIL
a. Compounds I and III have this relationship with each other: enantiomers
b. Compounds II and IV have this relationship with each other:
c. Compounds I and II have this relationship with each other:
d. *Draw one structure that is a stereoisomer of II, but neither a
diastereomer nor an enantiomer. (more than one correct answer)
Chapter 12 Solutions
GENERAL ORGANIC+BIO...(LL)-W/MOD.ACCESS
Ch. 12 - Prob. 12.1PPCh. 12 - How can you identify an anabolic reaction?Ch. 12 - Prob. 12.3PPCh. 12 - Prob. 12.4PPCh. 12 - Prob. 12.5PPCh. 12 - Prob. 12.6PPCh. 12 - Prob. 12.7PPCh. 12 - Prob. 12.8PPCh. 12 - Prob. 12.9PPCh. 12 - Prob. 12.10PP
Ch. 12 - Prob. 12.11PPCh. 12 - Prob. 12.12PPCh. 12 - Name a carbohydrate (if any) that undergoes...Ch. 12 - Prob. 12.14PPCh. 12 - Prob. 12.15PPCh. 12 - Prob. 12.16PPCh. 12 - Prob. 12.17PPCh. 12 - Prob. 12.18PPCh. 12 - Prob. 12.19PPCh. 12 - Prob. 12.20PPCh. 12 - Prob. 12.21PPCh. 12 - Prob. 12.22PPCh. 12 - Prob. 12.23PPCh. 12 - Prob. 12.24PPCh. 12 - Prob. 12.25PPCh. 12 - Prob. 12.26PPCh. 12 - Prob. 12.27PPCh. 12 - Prob. 12.28PPCh. 12 - Prob. 12.29PPCh. 12 - Prob. 12.30PPCh. 12 - Prob. 12.31PPCh. 12 - Prob. 12.32PPCh. 12 - Prob. 12.33PPCh. 12 - Prob. 12.34PPCh. 12 - Prob. 12.35PPCh. 12 - Prob. 12.36PPCh. 12 - Prob. 12.37PPCh. 12 - Prob. 12.38PPCh. 12 - Prob. 12.39PPCh. 12 - Prob. 12.40PPCh. 12 - Prob. 12.41PPCh. 12 - Prob. 12.42PPCh. 12 - Prob. 12.43PPCh. 12 - Prob. 12.44PPCh. 12 - Prob. 12.45PPCh. 12 - Prob. 12.46PPCh. 12 - Prob. 12.47PPCh. 12 - Prob. 12.48PPCh. 12 - Prob. 12.49PPCh. 12 - Prob. 12.50PPCh. 12 - Prob. 12.51PPCh. 12 - Arachidic acid is a saturated C20 fatty acid. a....Ch. 12 - Prob. 12.53PPCh. 12 - Prob. 12.54PPCh. 12 - Prob. 12.55PPCh. 12 - Prob. 12.56PPCh. 12 - Prob. 12.57PPCh. 12 - Prob. 12.58PPCh. 12 - Prob. 12.59APCh. 12 - Prob. 12.60APCh. 12 - Prob. 12.61APCh. 12 - Prob. 12.62APCh. 12 - Identify the type of foodcarbohydrate, fat, or...Ch. 12 - Prob. 12.64APCh. 12 - Prob. 12.65APCh. 12 - Prob. 12.66APCh. 12 - Prob. 12.67APCh. 12 - Prob. 12.68APCh. 12 - Prob. 12.69APCh. 12 - Prob. 12.70APCh. 12 - Prob. 12.71APCh. 12 - Prob. 12.72APCh. 12 - Prob. 12.73APCh. 12 - Prob. 12.74APCh. 12 - Prob. 12.75APCh. 12 - Prob. 12.76APCh. 12 - Prob. 12.77APCh. 12 - Prob. 12.78APCh. 12 - Prob. 12.79APCh. 12 - Prob. 12.80APCh. 12 - Prob. 12.81APCh. 12 - Prob. 12.82APCh. 12 - Prob. 12.83APCh. 12 - Prob. 12.84APCh. 12 - Prob. 12.85APCh. 12 - Prob. 12.86APCh. 12 - Prob. 12.87APCh. 12 - Prob. 12.88APCh. 12 - Prob. 12.89CPCh. 12 - Prob. 12.90CPCh. 12 - Laurie acid, a saturated Cl2 fatty acid, is found...Ch. 12 - A person is brought to the emergency room in what...Ch. 12 - Prob. 12.93CPCh. 12 - Prob. 12.94CPCh. 12 - Prob. 1IA.1QCh. 12 - Prob. 1IA.2QCh. 12 - Prob. 1IA.3QCh. 12 - Prob. 1IA.4QCh. 12 - Prob. 1IA.5QCh. 12 - Prob. 1IA.6QCh. 12 - Prob. 1IA.7QCh. 12 - Prob. 1IA.8QCh. 12 - Prob. 2IA.1QCh. 12 - Prob. 2IA.2QCh. 12 - Prob. 2IA.3QCh. 12 - Prob. 2IA.4QCh. 12 - Prob. 3IA.1QCh. 12 - Prob. 3IA.2QCh. 12 - Prob. 3IA.3QCh. 12 - Prob. 3IA.4QCh. 12 - Prob. 3IA.5QCh. 12 - Prob. 1ICCh. 12 - Prob. 2ICCh. 12 - Prob. 3IC
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