(a) Interpretation: The α − cleavage process of CH 3 OCH 2 CH ( CH 3 ) 2 is to be predicted. The structure of the ion with mass = 45 is to be drawn. Concept introduction: Spectroscopy method is used to identify the structure of the substance. The mass spectroscopy is used to determine the molecular mass. In the mass spectrum, the molecular ion is the most important peak. The m / z of the molecular ion occurs at the molecular mass.

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Answer 1

Question

Chapter 12, Problem 12.21P

Interpretation Introduction

(a)

Interpretation:

The α− cleavage process of CH3OCH2CH(CH3)2 is to be predicted. The structure of the ion with mass =45 is to be drawn.

Concept introduction:

Spectroscopy method is used to identify the structure of the substance. The mass spectroscopy is used to determine the molecular mass. In the mass spectrum, the molecular ion is the most important peak. The m/z of the molecular ion occurs at the molecular mass.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the mass spectrum of methyl isobutyl ether does not show a peak due to inductive cleavage, in contrast to the mass spectrum of di-sec-butyl-ether is to be stated.

Concept introduction:

Spectroscopy method is used to identify the structure of the substance. The mass spectroscopy is used to determine the molecular mass. In the mass spectrum, the molecular ion is the most important peak. The m/z of the molecular ion occurs at the molecular mass.

Interpretation Introduction

(c)

Interpretation:

The major difference that is expected when comparing the CI mass spectrum of methyl isobutyl ether with its EI spectrum is to be stated.

Concept introduction:

The mass spectroscopy is used to determine the molecular mass. In the mass spectrum, the molecular ion is the most important peak. The m/z of the molecular ion occurs at the molecular mass.

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Show how you would accomplish the following transformations. More than one step may be required. ow all reagents and all intermediate structures [one ONLY] A. H Br H CH3 NHz CH3 CH3 B. CH3CH2C-Br CH3CH2C-CN CH3 CH3.

Show how you would accomplish the following transformations. More than one step may be required. now all reagents and all intermediate structures [one ONLY] A. H Br H CH3 NHz CH3 CH3 B. CH3CH2C-Br CH3 CH3CH2C-CN CH3

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Answer 2

Question

Chapter 12, Problem 12.21P

Interpretation Introduction

(a)

Interpretation:

The α− cleavage process of CH3OCH2CH(CH3)2 is to be predicted. The structure of the ion with mass =45 is to be drawn.

Concept introduction:

Spectroscopy method is used to identify the structure of the substance. The mass spectroscopy is used to determine the molecular mass. In the mass spectrum, the molecular ion is the most important peak. The m/z of the molecular ion occurs at the molecular mass.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the mass spectrum of methyl isobutyl ether does not show a peak due to inductive cleavage, in contrast to the mass spectrum of di-sec-butyl-ether is to be stated.

Concept introduction:

Spectroscopy method is used to identify the structure of the substance. The mass spectroscopy is used to determine the molecular mass. In the mass spectrum, the molecular ion is the most important peak. The m/z of the molecular ion occurs at the molecular mass.

Interpretation Introduction

(c)

Interpretation:

The major difference that is expected when comparing the CI mass spectrum of methyl isobutyl ether with its EI spectrum is to be stated.

Concept introduction:

The mass spectroscopy is used to determine the molecular mass. In the mass spectrum, the molecular ion is the most important peak. The m/z of the molecular ion occurs at the molecular mass.

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Answer 3

Question

Chapter 12, Problem 12.21P

Interpretation Introduction

(a)

Interpretation:

The α− cleavage process of CH3OCH2CH(CH3)2 is to be predicted. The structure of the ion with mass =45 is to be drawn.

Concept introduction:

Spectroscopy method is used to identify the structure of the substance. The mass spectroscopy is used to determine the molecular mass. In the mass spectrum, the molecular ion is the most important peak. The m/z of the molecular ion occurs at the molecular mass.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the mass spectrum of methyl isobutyl ether does not show a peak due to inductive cleavage, in contrast to the mass spectrum of di-sec-butyl-ether is to be stated.

Concept introduction:

Spectroscopy method is used to identify the structure of the substance. The mass spectroscopy is used to determine the molecular mass. In the mass spectrum, the molecular ion is the most important peak. The m/z of the molecular ion occurs at the molecular mass.

Interpretation Introduction

(c)

Interpretation:

The major difference that is expected when comparing the CI mass spectrum of methyl isobutyl ether with its EI spectrum is to be stated.

Concept introduction:

The mass spectroscopy is used to determine the molecular mass. In the mass spectrum, the molecular ion is the most important peak. The m/z of the molecular ion occurs at the molecular mass.

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Answer 4

Question

Chapter 12, Problem 12.21P

Interpretation Introduction

(a)

Interpretation:

The α− cleavage process of CH3OCH2CH(CH3)2 is to be predicted. The structure of the ion with mass =45 is to be drawn.

Concept introduction:

Spectroscopy method is used to identify the structure of the substance. The mass spectroscopy is used to determine the molecular mass. In the mass spectrum, the molecular ion is the most important peak. The m/z of the molecular ion occurs at the molecular mass.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the mass spectrum of methyl isobutyl ether does not show a peak due to inductive cleavage, in contrast to the mass spectrum of di-sec-butyl-ether is to be stated.

Concept introduction:

Spectroscopy method is used to identify the structure of the substance. The mass spectroscopy is used to determine the molecular mass. In the mass spectrum, the molecular ion is the most important peak. The m/z of the molecular ion occurs at the molecular mass.

Interpretation Introduction

(c)

Interpretation:

The major difference that is expected when comparing the CI mass spectrum of methyl isobutyl ether with its EI spectrum is to be stated.

Concept introduction:

The mass spectroscopy is used to determine the molecular mass. In the mass spectrum, the molecular ion is the most important peak. The m/z of the molecular ion occurs at the molecular mass.

Expert Solution & Answer

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Answer 5

Chapter 12, Problem 12.21P

Interpretation Introduction

(a)

Interpretation:

The α− cleavage process of CH3OCH2CH(CH3)2 is to be predicted. The structure of the ion with mass =45 is to be drawn.

Concept introduction:

Spectroscopy method is used to identify the structure of the substance. The mass spectroscopy is used to determine the molecular mass. In the mass spectrum, the molecular ion is the most important peak. The m/z of the molecular ion occurs at the molecular mass.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the mass spectrum of methyl isobutyl ether does not show a peak due to inductive cleavage, in contrast to the mass spectrum of di-sec-butyl-ether is to be stated.

Concept introduction:

Spectroscopy method is used to identify the structure of the substance. The mass spectroscopy is used to determine the molecular mass. In the mass spectrum, the molecular ion is the most important peak. The m/z of the molecular ion occurs at the molecular mass.

Interpretation Introduction

(c)

Interpretation:

The major difference that is expected when comparing the CI mass spectrum of methyl isobutyl ether with its EI spectrum is to be stated.

Concept introduction:

The mass spectroscopy is used to determine the molecular mass. In the mass spectrum, the molecular ion is the most important peak. The m/z of the molecular ion occurs at the molecular mass.

Answer 6

Chapter 12, Problem 12.21P

Interpretation Introduction

(a)

Interpretation:

The α− cleavage process of CH3OCH2CH(CH3)2 is to be predicted. The structure of the ion with mass =45 is to be drawn.

Concept introduction:

Spectroscopy method is used to identify the structure of the substance. The mass spectroscopy is used to determine the molecular mass. In the mass spectrum, the molecular ion is the most important peak. The m/z of the molecular ion occurs at the molecular mass.

Answer 7

Chapter 12, Problem 12.21P

Interpretation Introduction

(a)

Interpretation:

The α− cleavage process of CH3OCH2CH(CH3)2 is to be predicted. The structure of the ion with mass =45 is to be drawn.

Concept introduction:

Spectroscopy method is used to identify the structure of the substance. The mass spectroscopy is used to determine the molecular mass. In the mass spectrum, the molecular ion is the most important peak. The m/z of the molecular ion occurs at the molecular mass.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The reason as to why the mass spectrum of methyl isobutyl ether does not show a peak due to inductive cleavage, in contrast to the mass spectrum of di-sec-butyl-ether is to be stated.

Concept introduction:

Spectroscopy method is used to identify the structure of the substance. The mass spectroscopy is used to determine the molecular mass. In the mass spectrum, the molecular ion is the most important peak. The m/z of the molecular ion occurs at the molecular mass.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The reason as to why the mass spectrum of methyl isobutyl ether does not show a peak due to inductive cleavage, in contrast to the mass spectrum of di-sec-butyl-ether is to be stated.

Concept introduction:

Spectroscopy method is used to identify the structure of the substance. The mass spectroscopy is used to determine the molecular mass. In the mass spectrum, the molecular ion is the most important peak. The m/z of the molecular ion occurs at the molecular mass.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The major difference that is expected when comparing the CI mass spectrum of methyl isobutyl ether with its EI spectrum is to be stated.

Concept introduction:

The mass spectroscopy is used to determine the molecular mass. In the mass spectrum, the molecular ion is the most important peak. The m/z of the molecular ion occurs at the molecular mass.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The major difference that is expected when comparing the CI mass spectrum of methyl isobutyl ether with its EI spectrum is to be stated.

Concept introduction:

The mass spectroscopy is used to determine the molecular mass. In the mass spectrum, the molecular ion is the most important peak. The m/z of the molecular ion occurs at the molecular mass.

Answer 12

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Answer 13

Expert Solution & Answer

Answer 14

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Answer 15

Ch. 12 - Prob. 12.1P Ch. 12 - Prob. 12.2P Ch. 12 - Prob. 12.3P Ch. 12 - Prob. 12.4P Ch. 12 - Prob. 12.5P Ch. 12 - Prob. 12.6P Ch. 12 - Prob. 12.7P Ch. 12 - Prob. 12.8P Ch. 12 - Prob. 12.9P Ch. 12 - Prob. 12.10P

Solution Summary: The author explains the alpha - cleavage process of methyl isobutyl ether and the structure of the ion with mass =45.

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Chapter 12 Solutions