The following phenomenon has to be explained – Solid argon of melting point -189 .2°C and boiling point -185 .7°C can be prepared by immersing a flask containing argon gas in liquid nitrogen ( b .p . -195 .8°C ) until it liquefies and then connecting the flask to a vacuum pump.
The following phenomenon has to be explained – Solid argon of melting point -189 .2°C and boiling point -185 .7°C can be prepared by immersing a flask containing argon gas in liquid nitrogen ( b .p . -195 .8°C ) until it liquefies and then connecting the flask to a vacuum pump.
Solution Summary: The author explains that the melting point of cyclohexane increases with increasing pressure exerted on it.
Solid argon of melting point
-189.2°C and boiling point -185.7°C can be prepared by immersing a flask containing argon gas in liquid nitrogen
(b.p. -195.8°C) until it liquefies and then connecting the flask to a vacuum pump.
(b)
Interpretation Introduction
Interpretation:
The following phenomenon has to be explained –
The melting point of cyclohexane
(C6H12) increases with increasing pressure exerted on the solid cyclohexane.
(c)
Interpretation Introduction
Interpretation:
The following phenomenon has to be explained –
Certain high-altitude clouds contain water droplets at
-10°C.
(d)
Interpretation Introduction
Interpretation:
The following phenomenon has to be explained –
When a piece of dry ice is added to a beaker of water, fog forms above the water.
(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to
glucose, C6H12O6, and fructose C6H12O6, in acidic solution:
C12H22O11 + H2O → C6H12O6 + C6H12O6
[sucrose]/mol dm³
t/min
0
0.316
14
0.300
39
0.274
60
0.256
80
0.238
110
0.211
(i) Graphically prove the order of the reaction and determine the rate constant of the
reaction.
(ii) Determine the half-life, t½ for the hydrolysis of sucrose.
(III) adsorbent
(b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous
solution was examined. The adsorption was modelled using a modified Langmuir
isotherm, yielding the following values of Kat pH = 6.5:
(ii)
T/K
10-10 K
280
2.505
295
1.819
310
1.364
325
1.050
Determine the enthalpy of adsorption, AadsHⓇ.
If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above
conditions, determine Aads Gº.
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.