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Concept explainers
(a)
Interpretation:
The effect of an increase in temperature on the electrical conductivity of silicon is to be determined.
Concept introduction:
Band theory is a model that defines the energy of the electrons in the solid and determines the conductivity of the solids. It is derived from the theory of the molecular orbital. The lower occupied molecular orbital is known as valence band and higher unoccupied molecular orbital are known as the conduction band. The solids can be classified on the basis of band theory as follows:
1. Conductors.
2. Semiconductor
3. Insulators
A periodic table is an arrangement of elements based on their
(b)
The effect of an increase in temperature on the electrical conductivity of lead is to be determined.
Concept introduction:
Band theory is a model that defines the energy of the electrons in the solid and determines the conductivity of the solids. It is derived from the theory of the molecular orbital. The lower occupied molecular orbital is known as valence band and higher unoccupied molecular orbital are known as the conduction band. The solids can be classified on the basis of band theory as follows:
1. Conductors.
2. Semiconductor
3. Insulators
A periodic table is an arrangement of elements based on their atomic number, properties, and electronic configuration. The table is arranged into groups and periods. The elements which are metallic in nature, occupy the large lower-left portion of the table. The non-metals occupy the small upper-right portion of the table. Metalloids like along the staircase line. Elements which appear in the same group have similar behavior.
(c)
The effect of an increase in temperature on the electrical conductivity of germanium is to be determined.
Concept introduction:
Band theory is a model that defines the energy of the electrons in the solid and determines the conductivity of the solids. It is derived from the theory of the molecular orbital. The lower occupied molecular orbital is known as valence band and higher unoccupied molecular orbital are known as the conduction band. The solids can be classified on the basis of band theory as follows:
1. Conductors.
2. Semiconductor
3. Insulators
A periodic table is an arrangement of elements based on their atomic number, properties, and electronic configuration. The table is arranged into groups and periods. The elements which are metallic in nature, occupy the large lower-left portion of the table. The non-metals occupy the small upper-right portion of the table. Metalloids like along the staircase line. Elements which appear in the same group have similar behavior.
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Chapter 12 Solutions
Loose Leaf for Chemistry: The Molecular Nature of Matter and Change
- Curved arrows are used to illustrate the flow of electrons. Follow the curved arrows and draw the structure of the missing reactants, intermediates, or products in the following mechanism. Include all lone pairs. Ignore stereochemistry. Ignore inorganic byproducts. H Br2 (1 equiv) H- Select to Draw Starting Alkene Draw Major Product I I H2O 四: ⑦.. Q Draw Major Charged Intermediate Iarrow_forwardNH (aq)+CNO (aq) → CO(NH2)2(s) Experiment [NH4] (M) [CNO] (M) Initial rate (M/s) 1 0.014 0.02 0.002 23 0.028 0.02 0.008 0.014 0.01 0.001 Calculate the rate contant for this reaction using the data provided in the table.arrow_forward2CIO2 + 20H-1 CIO31 + CIO2 + H2O Experiment [CIO2], M [OH-1], M 1 0.0500 0.100 23 2 0.100 0.100 3 0.100 0.0500 Initial Rate, M/s 0.0575 0.230 0.115 ... Given this date, calculate the overall order of this reaction.arrow_forward
- 2 3 .(be)_[Ɔ+(be)_OI ← (b²)_IƆO+ (be)_I Experiment [1-] M 0.005 [OCI-] 0.005 Initial Rate M/min 0.000275 0.0025 0.005 0.000138 0.0025 0.0025 0.000069 4 0.0025 0.0025 0.000140 Calculate the rate constant of this reaction using the table data.arrow_forward1 2 3 4 I(aq) +OCl(aq) → IO¯¯(aq) + Cl¯(aq) Experiment [I-] M 0.005 [OCI-] 0.005 Initial Rate M/min 0.000275 0.0025 0.005 0.000138 0.0025 0.0025 Calculate the overall order of this reaction using the table data. 0.0025 0.000069 0.0025 0.000140arrow_forwardH2O2(aq) +3 I¯(aq) +2 H+(aq) → 13(aq) +2 H₂O(l)· ••• Experiment [H2 O2]o (M) [I]o (M) [H+]。 (M) Initial rate (M/s) 1 0.15 0.15 0.05 0.00012 234 0.15 0.3 0.05 0.00024 0.3 0.15 0.05 0.00024 0.15 0.15 0.1 0.00048 Calculate the overall order of this reaction using the table data.arrow_forward
- The U. S. Environmental Protection Agency (EPA) sets limits on healthful levels of air pollutants. The maximum level that the EPA considers safe for lead air pollution is 1.5 μg/m³ Part A If your lungs were filled with air containing this level of lead, how many lead atoms would be in your lungs? (Assume a total lung volume of 5.40 L.) ΜΕ ΑΣΦ = 2.35 1013 ? atoms ! Check your rounding. Your final answer should be rounded to 2 significant figures in the last step. No credit lost. Try again.arrow_forwardY= - 0.039 (14.01) + 0.7949arrow_forwardSuppose 1.76 g of magnesium acetate (Mg (CH3CO2)2) are dissolved in 140. mL of water. Find the composition of the resulting electrolyte solution. In particular, list the chemical symbols (including any charge) of each dissolved ion in the table below. List only one ion per row. mEq Then, calculate the concentration of each ion in dwrite the concentration in the second column of each row. Be sure you round your answers to the L correct number of significant digits. ion Add Row mEq L x 5arrow_forward
- A pdf file of your hand drawn, stepwise mechanisms for the reactions. For each reaction in the assignment, you must write each mechanism three times (there are 10 reactions, so 30 mechanisms). (A) do the work on a tablet and save as a pdf., it is expected to write each mechanism out and NOT copy and paste the mechanism after writing it just once. Everything should be drawn out stepwise and every bond that is formed and broken in the process of the reaction, and is expected to see all relevant lone pair electrons and curved arrows.arrow_forwardNonearrow_forwardNonearrow_forward
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