Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th
Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th
9th Edition
ISBN: 9781305082144
Author: John E. McMurry
Publisher: Cengage Learning
Question
Book Icon
Chapter 11.SE, Problem 54AP
Interpretation Introduction

a)

Interpretation:

The actual product has to be identified.

Concept introduction:

Elimination reaction:An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

E1 elimination: Alkyl halide forms carbocation by the removal of bromine followed by the abstraction of the proton from the β-carbon atom in two steps which leads to the product as an alkene

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 11.SE, Problem 54AP , additional homework tip  1

E2 elimination:Alkyl halide forms an alkene from the abstraction of the proton from the β-carbon atom followed by elimination of the bromine in a single step.

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 11.SE, Problem 54AP , additional homework tip  2

Interpretation Introduction

b)

Interpretation:

The actual product has to be identified.

Concept introduction:

Elimination reaction:An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

E1 elimination: Alkyl halide forms carbocation by the removal of bromine followed by the abstraction of the proton from the β-carbon atom in two steps which leads to the product as an alkene

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 11.SE, Problem 54AP , additional homework tip  3

E2 elimination:Alkyl halide forms an alkene from the abstraction of the proton from the β-carbon atom followed by elimination of the bromine in a single step.

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 11.SE, Problem 54AP , additional homework tip  4

Interpretation Introduction

c)

Interpretation:

The actual product has to be identified.

Concept introduction:

Elimination reaction:An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

E1 elimination: Alkyl halide forms carbocation by the removal of bromine followed by the abstraction of the proton from the β-carbon atom in two steps which leads to the product as an alkene

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 11.SE, Problem 54AP , additional homework tip  5

E2 elimination:Alkyl halide forms an alkene from the abstraction of the proton from the β-carbon atom followed by elimination of the bromine in a single step.

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th, Chapter 11.SE, Problem 54AP , additional homework tip  6

Blurred answer
Students have asked these similar questions
Learning Goal: This question reviews the format for writing an element's written symbol. Recall that written symbols have a particular format. Written symbols use a form like this: 35 Cl 17 In this form the mass number, 35, is a stacked superscript. The atomic number, 17, is a stacked subscript. "CI" is the chemical symbol for the element chlorine. A general way to show this form is: It is also correct to write symbols by leaving off the atomic number, as in the following form: atomic number mass number Symbol 35 Cl or mass number Symbol This is because if you write the element symbol, such as Cl, you know the atomic number is 17 from that symbol. Remember that the atomic number, or number of protons in the nucleus, is what defines the element. Thus, if 17 protons are in the nucleus, the element can only be chlorine. Sometimes you will only see 35 C1, where the atomic number is not written. Watch this video to review the format for written symbols. In the following table each column…
need help please and thanks dont understand only need help with C-F Learning Goal: As discussed during the lecture, the enzyme HIV-1 reverse transcriptae (HIV-RT) plays a significant role for the HIV virus and is an important drug target. Assume a concentration [E] of 2.00 µM (i.e. 2.00 x 10-6 mol/l) for HIV-RT. Two potential drug molecules, D1 and D2, were identified, which form stable complexes with the HIV-RT. The dissociation constant of the complex ED1 formed by HIV-RT and the drug D1 is 1.00 nM (i.e. 1.00 x 10-9). The dissociation constant of the complex ED2 formed by HIV-RT and the drug D2 is 100 nM (i.e. 1.00 x 10-7).   Part A - Difference in binding free eenergies Compute the difference in binding free energy (at a physiological temperature T=310 K) for the complexes. Provide the difference as a positive numerical expression with three significant figures in kJ/mol. The margin of error is 2%.   Part B - Compare difference in free energy to the thermal…
need help please and thanks dont understand only need help with C-F Learning Goal: As discussed during the lecture, the enzyme HIV-1 reverse transcriptae (HIV-RT) plays a significant role for the HIV virus and is an important drug target. Assume a concentration [E] of 2.00 µM (i.e. 2.00 x 10-6 mol/l) for HIV-RT. Two potential drug molecules, D1 and D2, were identified, which form stable complexes with the HIV-RT. The dissociation constant of the complex ED1 formed by HIV-RT and the drug D1 is 1.00 nM (i.e. 1.00 x 10-9). The dissociation constant of the complex ED2 formed by HIV-RT and the drug D2 is 100 nM (i.e. 1.00 x 10-7).   Part A - Difference in binding free eenergies Compute the difference in binding free energy (at a physiological temperature T=310 K) for the complexes. Provide the difference as a positive numerical expression with three significant figures in kJ/mol. The margin of error is 2%.   Part B - Compare difference in free energy to the thermal…

Chapter 11 Solutions

Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th

Ch. 11.5 - Rank the following substances in order of their...Ch. 11.5 - 3-Bromo-1-butene and 1-bromo-2-butene undergo SN1...Ch. 11.5 - Prob. 13PCh. 11.6 - Review the mechanism of geraniol biosynthesis...Ch. 11.7 - Prob. 15PCh. 11.7 - What alkyl halides might the following alkenes...Ch. 11.8 - Prob. 17PCh. 11.8 - Prob. 18PCh. 11.9 - Prob. 19PCh. 11.12 - Prob. 20PCh. 11.SE - Prob. 21VCCh. 11.SE - From what alkyl bromide was the following alkyl...Ch. 11.SE - Prob. 23VCCh. 11.SE - Prob. 24VCCh. 11.SE - Prob. 25MPCh. 11.SE - Prob. 26MPCh. 11.SE - Prob. 27MPCh. 11.SE - Prob. 28MPCh. 11.SE - Prob. 29MPCh. 11.SE - Prob. 30MPCh. 11.SE - Prob. 31MPCh. 11.SE - Prob. 32MPCh. 11.SE - Metabolism of S-adenosylhomocysteine (Section...Ch. 11.SE - Reaction of iodoethane with CN- yields a small...Ch. 11.SE - One step in the urea cycle for ridding the body of...Ch. 11.SE - Prob. 36MPCh. 11.SE - Prob. 37MPCh. 11.SE - Propose a mechanism for the following reaction, an...Ch. 11.SE - Prob. 39APCh. 11.SE - The following Walden cycle has been carried out....Ch. 11.SE - Prob. 41APCh. 11.SE - Which reactant in each of the following pairs is...Ch. 11.SE - Prob. 43APCh. 11.SE - Prob. 44APCh. 11.SE - Prob. 45APCh. 11.SE - Prob. 46APCh. 11.SE - Prob. 47APCh. 11.SE - Prob. 48APCh. 11.SE - Propose structures for compounds that fit the...Ch. 11.SE - What products would you expect from the reaction...Ch. 11.SE - Prob. 51APCh. 11.SE - Prob. 52APCh. 11.SE - Prob. 53APCh. 11.SE - Prob. 54APCh. 11.SE - Prob. 55APCh. 11.SE - Order each of the following sets of compounds with...Ch. 11.SE - Order each of the following sets of compounds with...Ch. 11.SE - Prob. 58APCh. 11.SE - Prob. 59APCh. 11.SE - Ethers can often be prepared by SN2 reaction of...Ch. 11.SE - Show the stereochemistry of the epoxide (see...Ch. 11.SE - Prob. 62APCh. 11.SE - In addition to not undergoing substitution...Ch. 11.SE - The tosylate of (2R, 3S)-3-phenyl-2-butanol...Ch. 11.SE - Prob. 65APCh. 11.SE - Prob. 66APCh. 11.SE - Prob. 67APCh. 11.SE - Prob. 68APCh. 11.SE - Prob. 69APCh. 11.SE - (S)-2-Butanol slowly racemizes on standing in...Ch. 11.SE - Reaction of HBr with (R)-3-methyl-3-hexanol leads...Ch. 11.SE - Treatment of 1-bromo-2-deuterio-2-phenylethane...Ch. 11.SE - Prob. 73APCh. 11.SE - Prob. 74APCh. 11.SE - In light of your answer to Problem 11-74, explain...Ch. 11.SE - Prob. 76APCh. 11.SE - Compound X is optically inactive and has the...Ch. 11.SE - When a primary alcohol is treated with...Ch. 11.SE - Prob. 79APCh. 11.SE - Amines are converted into alkenes by a two-step...Ch. 11.SE - The antipsychotic drug flupentixol is prepared by...
Knowledge Booster
Background pattern image
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
  • Text book image
    Organic Chemistry
    Chemistry
    ISBN:9781305080485
    Author:John E. McMurry
    Publisher:Cengage Learning
    Text book image
    Organic Chemistry
    Chemistry
    ISBN:9781305580350
    Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
    Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9781305080485
Author:John E. McMurry
Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning