a)
Interpretation:
The expected product between the
Answer to Problem 21VC
The ethyl chloride undergoes SN2 reaction with Na+SCH3- and NaOH to yield a product.
The product is CH3CH2SCH3, CH3CH2OH.
Here the leaving group is Cl.
The nucleophile is SCH3-,OH.
Hence it undergoes SN2 reaction.
Explanation of Solution
The ethyl chloride undergoes SN2 reaction with Na+SCH3- and NaOH to yield a product.
The product is CH3CH2SCH3, CH3CH2OH.
Here the leaving group is Cl.
The nucleophile is SCH3-,OH.
Hence it undergoes SN2 reaction.
The ethyl chloride undergoes SN2 reaction with Na+SCH3- and NaOH to yield a product.
The product is CH3CH2SCH3, CH3CH2OH.
Here the leaving group is Cl.
The nucleophile is SCH3-,OH.
Hence it undergoes SN2 reaction.
b)
Interpretation:
The expected product between the alkyl halide CH3CH2Cl+Na+SCH3- and NaOH is interpreted.
Answer to Problem 21VC
The alkyl halide undergoes SN1 reaction with Na+SCH3- to yield a SCH3 Substituited product.
The product is shown in the reaction.
In this reaction leaving group is Cl, the nucleophile is SCH3-
Explanation of Solution
The alkyl halide undergoes E1 reaction with NaOH to yield a
The product is shown here
The alkyl halide undergoes SN1reaction with Na+SCH3- to yield a SCH3 Substituited product.
The product is shown in the reaction.
In this reaction leaving group is Cl, the nucleophile is SCH3-
c)
Interpretation:
The expected product between the alkyl halide CH3CH2Cl+Na+SCH3- and NaOH is interpreted.
Answer to Problem 21VC
The benzylchloride undergoes SN1 reaction with Na+SCH3- to yield a product.
The product is shown here.
Here the leaving group is Cl.
The nucleophile is SCH3-Hence it undergoes SN1 reaction.
Explanation of Solution
The benzylchloride undergoes E1 reaction with NaOH to yield a product.
The product is shown here
The benzylchloride undergoes SN1 reaction with Na+SCH3- to yield a product.
The product is shown here.
Here the leaving group is Cl.
The nucleophile is SCH3- Hence it undergoes SN1 reaction.
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Chapter 11 Solutions
Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th
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Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning