
Concept explainers
(a)
Interpretation:
Equation for hydration of given
Concept Introduction:
Addition of water molecule to an unsaturated bond present in hydrocarbon is known as hydration. During hydration, the unsaturated bond present is broken and a carbon‑hydrogen, carbon‑hydroxyl bond is formed.
General structure of alkene can be given as,
Alkene on hydration gives alcohol. As there is only one unsaturated bond present in alkene, only one molecule of water is consumed. The general equation for the hydration of alkene can be given as,
If the alkene is symmetrical only one product is formed. If the alkene is unsymmetrical, then the product is formed according the Markovnikov’s rule. According to this rule, in hydration reaction, the hydrogen atom gets attached to the carbon atom in the unsaturated bond which has more number of hydrogen atoms or less number of substituents.
(b)
Interpretation:
Equation for hydration of given alkene has to be written and the major product has to be predicted.
Concept Introduction:
Refer part (a).
(c)
Interpretation:
Equation for hydration of given alkene has to be written and the major product has to be predicted.
Concept Introduction:
Refer part (a).
(d)
Interpretation:
Equation for hydration of given alkene has to be written and the major product has to be predicted.
Concept Introduction:
Refer part (a).

Want to see the full answer?
Check out a sample textbook solution
Chapter 11 Solutions
General, Organic, and Biochemistry
- (c) (4pts) Mechanism: heat (E1) CH3OH + 1.5pts each _E1 _ (1pt) Br CH3OH (d) (4pts) Mechanism: SN1 (1pt) (e) (3pts) 1111 I H 10 Ill!! H LDA THF (solvent) Mechanism: E2 (1pt) NC (f) Bri!!!!! CH3 NaCN (3pts) acetone Mechanism: SN2 (1pt) (SN1) -OCH3 OCH3 1.5pts each 2pts for either product 1pt if incorrect stereochemistry H Br (g) “,、 (3pts) H CH3OH +21 Mechanism: SN2 (1pt) H CH3 2pts 1pt if incorrect stereochemistry H 2pts 1pt if incorrect stereochemistryarrow_forwardA mixture of butyl acrylate and 4'-chloropropiophenone has been taken for proton NMR analysis. Based on this proton NMR, determine the relative percentage of each compound in the mixturearrow_forwardQ5: Label each chiral carbon in the following molecules as R or S. Make sure the stereocenter to which each of your R/S assignments belong is perfectly clear to the grader. (8pts) R OCH 3 CI H S 2pts for each R/S HO R H !!! I OH CI HN CI R Harrow_forward
- Calculate the proton and carbon chemical shifts for this structurearrow_forwardA. B. b. Now consider the two bicyclic molecules A. and B. Note that A. is a dianion and B. is a neutral molecule. One of these molecules is a highly reactive compound first characterized in frozen noble gas matrices, that self-reacts rapidly at temperatures above liquid nitrogen temperature. The other compound was isolated at room temperature in the early 1960s, and is a stable ligand used in organometallic chemistry. Which molecule is the more stable molecule, and why?arrow_forwardWhere are the chiral centers in this molecule? Also is this compound meso yes or no?arrow_forward
- PLEASE HELP! URGENT!arrow_forwardWhere are the chiral centers in this molecule? Also is this compound meso yes or no?arrow_forwardA mixture of C7H12O2, C9H9OCl, biphenyl and acetone was put together in a gas chromatography tube. Please decide from the GC resutls which correspond to the peak for C7,C9 and biphenyl and explain the reasoning based on GC results. Eliminate unnecessary peaks from Gas Chromatography results.arrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY





