General, Organic, and Biochemistry
10th Edition
ISBN: 9781260506198
Author: Denniston, Katherine
Publisher: MCGRAW-HILL HIGHER EDUCATION
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Question
Chapter 11, Problem 11.67QP
(a)
Interpretation Introduction
Interpretation:
Balanced equation for the hydrogenation of 2-butyne has to be written.
Concept Introduction:
Addition of hydrogen molecule to an unsaturated bond present in hydrocarbon is known as hydrogenation. During hydrogenation, the unsaturated bond present is broken and a carbon‑hydrogen bond is formed. Hydrogenation can be accomplished by use of metal catalyst such as platinum, nickel, or palladium.
Balanced equation is the one that contains same number of atoms of different kind equal on both sides of the equation.
(b)
Interpretation Introduction
Interpretation:
Balanced equation for the halogenation of 2-pentyne has to be written.
Concept Introduction:
Addition of halogen molecule to an unsaturated bond present in hydrocarbon is known as halogenation. During halogenation, the unsaturated bond present is broken and a carbon‑halogen bond is formed.
Balanced equation is the one that contains same number of atoms of different kind equal on both sides of the equation.
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3.
a.
Use the MS to propose at least two possible molecular formulas.
For an unknown compound:
101.
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62.0
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64.0
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74.0
40
75.0
76.0
20
20
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80
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160
180
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m/z
99.5
68564810898409581251883040
115.0
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77404799
17417M
117.0
12.9
118.0
33.5
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2.1
159.0
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Relative Intensity
2
2
8
ō (ppm)
6
2
Solve the structure and assign each of the following spectra (IR and C-NMR)
1.
For an unknown compound with a molecular formula of C8H100:
a.
What is the DU? (show your work)
b.
Solve the structure and assign each of the following spectra.
8
6
2
ō (ppm)
4
2
0
200
150
100
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ō (ppm)
LOD
D
4000
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HAVENUMBERI -11
Chapter 11 Solutions
General, Organic, and Biochemistry
Ch. 11.2 - Name each of the following alkenes and alkynes...Ch. 11.2 - Prob. 11.2PPCh. 11.2 - Prob. 11.1QCh. 11.2 - Prob. 11.2QCh. 11.3 - Prob. 11.3PPCh. 11.3 - Prob. 11.4PPCh. 11.3 - Prob. 11.5PPCh. 11.3 - Prob. 11.3QCh. 11.3 - Prob. 11.4QCh. 11.3 - Prob. 11.5Q
Ch. 11.3 - Draw each of the cis-trans isomers in Question...Ch. 11.3 - Prob. 11.7QCh. 11.3 - Prob. 11.8QCh. 11.5 - Prob. 11.6PPCh. 11.5 - Prob. 11.7PPCh. 11.5 - Prob. 11.9QCh. 11.5 - Write balanced equations for the hydrogenation of...Ch. 11.5 - Prob. 11.11QCh. 11.5 - Prob. 11.12QCh. 11.5 - Prob. 11.8PPCh. 11.5 - Prob. 11.13QCh. 11.5 - Prob. 11.14QCh. 11.5 - Prob. 11.15QCh. 11.5 - Prob. 11.16QCh. 11.5 - Prob. 11.9PPCh. 11.5 - Prob. 11.17QCh. 11.5 - Prob. 11.18QCh. 11.5 - Prob. 11.19QCh. 11.5 - Prob. 11.20QCh. 11.5 - Write a balanced equation for the hydrobromination...Ch. 11.6 - Name the following compounds using the IUPAC and...Ch. 11.6 - Prob. 11.21QCh. 11.6 - Prob. 11.22QCh. 11 - Prob. 11.23QPCh. 11 - Prob. 11.24QPCh. 11 - Prob. 11.25QPCh. 11 - Prob. 11.26QPCh. 11 - Prob. 11.27QPCh. 11 - Prob. 11.28QPCh. 11 - Prob. 11.29QPCh. 11 - Prob. 11.30QPCh. 11 - Prob. 11.31QPCh. 11 - Prob. 11.32QPCh. 11 - Prob. 11.33QPCh. 11 - Prob. 11.34QPCh. 11 - Prob. 11.35QPCh. 11 - Prob. 11.36QPCh. 11 - Prob. 11.37QPCh. 11 - Prob. 11.38QPCh. 11 - Prob. 11.39QPCh. 11 - Prob. 11.40QPCh. 11 - Prob. 11.41QPCh. 11 - Prob. 11.42QPCh. 11 - Prob. 11.43QPCh. 11 - Prob. 11.44QPCh. 11 - Prob. 11.45QPCh. 11 - Prob. 11.46QPCh. 11 - Which of the following alkenes can exist as...Ch. 11 - Prob. 11.48QPCh. 11 - Prob. 11.49QPCh. 11 - Prob. 11.50QPCh. 11 - Prob. 11.51QPCh. 11 - Prob. 11.52QPCh. 11 - Prob. 11.53QPCh. 11 - Prob. 11.54QPCh. 11 - Prob. 11.55QPCh. 11 - Prob. 11.56QPCh. 11 - Prob. 11.57QPCh. 11 - Prob. 11.58QPCh. 11 - Prob. 11.59QPCh. 11 - Prob. 11.60QPCh. 11 - Prob. 11.61QPCh. 11 - Prob. 11.62QPCh. 11 - Prob. 11.63QPCh. 11 - Prob. 11.64QPCh. 11 - Prob. 11.65QPCh. 11 - Prob. 11.66QPCh. 11 - Prob. 11.67QPCh. 11 - Prob. 11.68QPCh. 11 - Prob. 11.69QPCh. 11 - Prob. 11.70QPCh. 11 - Prob. 11.71QPCh. 11 - Prob. 11.72QPCh. 11 - Prob. 11.73QPCh. 11 - Prob. 11.74QPCh. 11 - Prob. 11.75QPCh. 11 - Prob. 11.76QPCh. 11 - Prob. 11.77QPCh. 11 - Prob. 11.78QPCh. 11 - Prob. 11.79QPCh. 11 - Prob. 11.80QPCh. 11 - Prob. 11.81QPCh. 11 - Prob. 11.82QPCh. 11 - Prob. 11.83QPCh. 11 - Write an equation for the addition reaction that...Ch. 11 - Prob. 11.85QPCh. 11 - Draw the structure of each of the following...Ch. 11 - Prob. 11.87QPCh. 11 - Prob. 11.88QPCh. 11 - Prob. 11.89QPCh. 11 - Prob. 11.90QPCh. 11 - Prob. 11.91QPCh. 11 - Prob. 11.92QPCh. 11 - Draw each of the following compounds, using...Ch. 11 - Prob. 11.94QPCh. 11 - Prob. 11.95QPCh. 11 - Prob. 11.96QPCh. 11 - Prob. 11.97QPCh. 11 - Prob. 11.98QPCh. 11 - Prob. 11.99QPCh. 11 - Prob. 11.100QPCh. 11 - Prob. 11.101QPCh. 11 - Prob. 11.102QPCh. 11 - Prob. 11.103QPCh. 11 - What biological molecules contain purine rings?
Ch. 11 - Prob. 1MCPCh. 11 - Prob. 3MCPCh. 11 - Prob. 5MCPCh. 11 - Prob. 6MCPCh. 11 - Prob. 7MCPCh. 11 - Prob. 8MCPCh. 11 - Prob. 9MCPCh. 11 - Prob. 10MCP
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