a) Interpretation: The product formed during the S N 2 reaction of 1-bromobutane with NaI Concept introduction: In S N 2 reaction the nucleophile plays a major role in the product formation. If a nucleophile is negatively charged then the product will be neutral. If a nucleophile is neutral then it results in the positively charge product.

Question

The table includes macrostates characterized by 4 energy levels (&) that are equally spaced but with different degrees of occupation. a) Calculate the energy of all the macrostates (in joules). See if they all have the same energy and number of particles. b) Calculate the macrostate that is most likely to exist. For this macrostate, show that the population of the levels is consistent with the Boltzmann distribution. macrostate 1 macrostate 2 macrostate 3 ε/k (K) Populations Populations Populations 300 5 3 4 200 7 9 8 100 15 17 16 0 33 31 32 DATO: k = 1,38×10-23 J K-1

Answer 1

Question

Chapter 11.3, Problem 4P

Interpretation Introduction

a)

Interpretation:

The product formed during the S_N2 reaction of 1-bromobutane with

NaI

Concept introduction:

In S_N2 reaction the nucleophile plays a major role in the product formation. If a nucleophile is negatively charged then the product will be neutral. If a nucleophile is neutral then it results in the positively charge product.

Interpretation Introduction

b)

Interpretation:

The product formed during the S_N2 reaction of 1-bromobutane with

KOH

Concept introduction:

In S_N2 reaction the nucleophile plays a major role in the product formation. If a nucleophile is negatively charged then the product will be neutral. If a nucleophile is neutral then it results in the positively charge product.

Interpretation Introduction

c)

Interpretation:

The product formed during the S_N2 reaction of 1-bromobutane with

CH≡CLi

Concept introduction:

In S_N2 reaction the nucleophile plays a major role in the product formation. If a nucleophile is negatively charged then the product will be neutral. If a nucleophile is neutral then it results in the positively charge product.

Interpretation Introduction

d)

Interpretation:

The product formed during the S_N2 reaction of 1-bromobutane with

NH₃ is to be stated.

Concept introduction:

In S_N2 reaction the nucleophile plays a major role in the product formation. If a nucleophile is negatively charged then the product will be neutral. If a nucleophile is neutral then it results in the positively charge product.

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The table includes macrostates characterized by 4 energy levels (&) that are equally spaced but with different degrees of occupation. a) Calculate the energy of all the macrostates (in joules). See if they all have the same energy and number of particles. b) Calculate the macrostate that is most likely to exist. For this macrostate, show that the population of the levels is consistent with the Boltzmann distribution. macrostate 1 macrostate 2 macrostate 3 ε/k (K) Populations Populations Populations 300 5 3 4 200 7 9 8 100 15 17 16 0 33 31 32 DATO: k = 1,38×10-23 J K-1

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In an experiment, the viscosity of water was measured at different temperatures and the table was constructed from the data obtained. a) Calculate the activation energy of viscous flow (kJ/mol). b) Calculate the viscosity at 30°C. T/°C 0 20 40 60 80 η/cpoise 1,972 1,005 0,656 0,469 0,356

Answer 2

Question

Chapter 11.3, Problem 4P

Interpretation Introduction

a)

Interpretation:

The product formed during the S_N2 reaction of 1-bromobutane with

NaI

Concept introduction:

In S_N2 reaction the nucleophile plays a major role in the product formation. If a nucleophile is negatively charged then the product will be neutral. If a nucleophile is neutral then it results in the positively charge product.

Interpretation Introduction

b)

Interpretation:

The product formed during the S_N2 reaction of 1-bromobutane with

KOH

Concept introduction:

In S_N2 reaction the nucleophile plays a major role in the product formation. If a nucleophile is negatively charged then the product will be neutral. If a nucleophile is neutral then it results in the positively charge product.

Interpretation Introduction

c)

Interpretation:

The product formed during the S_N2 reaction of 1-bromobutane with

CH≡CLi

Concept introduction:

In S_N2 reaction the nucleophile plays a major role in the product formation. If a nucleophile is negatively charged then the product will be neutral. If a nucleophile is neutral then it results in the positively charge product.

Interpretation Introduction

d)

Interpretation:

The product formed during the S_N2 reaction of 1-bromobutane with

NH₃ is to be stated.

Concept introduction:

In S_N2 reaction the nucleophile plays a major role in the product formation. If a nucleophile is negatively charged then the product will be neutral. If a nucleophile is neutral then it results in the positively charge product.

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Answer 3

Question

Chapter 11.3, Problem 4P

Interpretation Introduction

a)

Interpretation:

The product formed during the S_N2 reaction of 1-bromobutane with

NaI

Concept introduction:

In S_N2 reaction the nucleophile plays a major role in the product formation. If a nucleophile is negatively charged then the product will be neutral. If a nucleophile is neutral then it results in the positively charge product.

Interpretation Introduction

b)

Interpretation:

The product formed during the S_N2 reaction of 1-bromobutane with

KOH

Concept introduction:

In S_N2 reaction the nucleophile plays a major role in the product formation. If a nucleophile is negatively charged then the product will be neutral. If a nucleophile is neutral then it results in the positively charge product.

Interpretation Introduction

c)

Interpretation:

The product formed during the S_N2 reaction of 1-bromobutane with

CH≡CLi

Concept introduction:

In S_N2 reaction the nucleophile plays a major role in the product formation. If a nucleophile is negatively charged then the product will be neutral. If a nucleophile is neutral then it results in the positively charge product.

Interpretation Introduction

d)

Interpretation:

The product formed during the S_N2 reaction of 1-bromobutane with

NH₃ is to be stated.

Concept introduction:

In S_N2 reaction the nucleophile plays a major role in the product formation. If a nucleophile is negatively charged then the product will be neutral. If a nucleophile is neutral then it results in the positively charge product.

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Answer 4

Question

Chapter 11.3, Problem 4P

Interpretation Introduction

a)

Interpretation:

The product formed during the S_N2 reaction of 1-bromobutane with

NaI

Concept introduction:

In S_N2 reaction the nucleophile plays a major role in the product formation. If a nucleophile is negatively charged then the product will be neutral. If a nucleophile is neutral then it results in the positively charge product.

Interpretation Introduction

b)

Interpretation:

The product formed during the S_N2 reaction of 1-bromobutane with

KOH

Concept introduction:

In S_N2 reaction the nucleophile plays a major role in the product formation. If a nucleophile is negatively charged then the product will be neutral. If a nucleophile is neutral then it results in the positively charge product.

Interpretation Introduction

c)

Interpretation:

The product formed during the S_N2 reaction of 1-bromobutane with

CH≡CLi

Concept introduction:

In S_N2 reaction the nucleophile plays a major role in the product formation. If a nucleophile is negatively charged then the product will be neutral. If a nucleophile is neutral then it results in the positively charge product.

Interpretation Introduction

d)

Interpretation:

The product formed during the S_N2 reaction of 1-bromobutane with

NH₃ is to be stated.

Concept introduction:

In S_N2 reaction the nucleophile plays a major role in the product formation. If a nucleophile is negatively charged then the product will be neutral. If a nucleophile is neutral then it results in the positively charge product.

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Answer 5

Chapter 11.3, Problem 4P

Interpretation Introduction

a)

Interpretation:

The product formed during the S_N2 reaction of 1-bromobutane with

NaI

Concept introduction:

In S_N2 reaction the nucleophile plays a major role in the product formation. If a nucleophile is negatively charged then the product will be neutral. If a nucleophile is neutral then it results in the positively charge product.

Interpretation Introduction

b)

Interpretation:

The product formed during the S_N2 reaction of 1-bromobutane with

KOH

Concept introduction:

In S_N2 reaction the nucleophile plays a major role in the product formation. If a nucleophile is negatively charged then the product will be neutral. If a nucleophile is neutral then it results in the positively charge product.

Interpretation Introduction

c)

Interpretation:

The product formed during the S_N2 reaction of 1-bromobutane with

CH≡CLi

Concept introduction:

In S_N2 reaction the nucleophile plays a major role in the product formation. If a nucleophile is negatively charged then the product will be neutral. If a nucleophile is neutral then it results in the positively charge product.

Interpretation Introduction

d)

Interpretation:

The product formed during the S_N2 reaction of 1-bromobutane with

NH₃ is to be stated.

Concept introduction:

In S_N2 reaction the nucleophile plays a major role in the product formation. If a nucleophile is negatively charged then the product will be neutral. If a nucleophile is neutral then it results in the positively charge product.

Answer 6

Chapter 11.3, Problem 4P

Interpretation Introduction

a)

Interpretation:

The product formed during the S_N2 reaction of 1-bromobutane with

NaI

Concept introduction:

In S_N2 reaction the nucleophile plays a major role in the product formation. If a nucleophile is negatively charged then the product will be neutral. If a nucleophile is neutral then it results in the positively charge product.

Answer 7

Chapter 11.3, Problem 4P

Interpretation Introduction

a)

Interpretation:

The product formed during the S_N2 reaction of 1-bromobutane with

NaI

Concept introduction:

In S_N2 reaction the nucleophile plays a major role in the product formation. If a nucleophile is negatively charged then the product will be neutral. If a nucleophile is neutral then it results in the positively charge product.

Answer 8

Interpretation Introduction

b)

Interpretation:

The product formed during the S_N2 reaction of 1-bromobutane with

KOH

Concept introduction:

In S_N2 reaction the nucleophile plays a major role in the product formation. If a nucleophile is negatively charged then the product will be neutral. If a nucleophile is neutral then it results in the positively charge product.

Answer 9

Interpretation Introduction

b)

Interpretation:

The product formed during the S_N2 reaction of 1-bromobutane with

KOH

Concept introduction:

In S_N2 reaction the nucleophile plays a major role in the product formation. If a nucleophile is negatively charged then the product will be neutral. If a nucleophile is neutral then it results in the positively charge product.

Answer 10

Interpretation Introduction

c)

Interpretation:

The product formed during the S_N2 reaction of 1-bromobutane with

CH≡CLi

Concept introduction:

In S_N2 reaction the nucleophile plays a major role in the product formation. If a nucleophile is negatively charged then the product will be neutral. If a nucleophile is neutral then it results in the positively charge product.

Answer 11

Interpretation Introduction

c)

Interpretation:

The product formed during the S_N2 reaction of 1-bromobutane with

CH≡CLi

Concept introduction:

In S_N2 reaction the nucleophile plays a major role in the product formation. If a nucleophile is negatively charged then the product will be neutral. If a nucleophile is neutral then it results in the positively charge product.

Answer 12

Interpretation Introduction

d)

Interpretation:

The product formed during the S_N2 reaction of 1-bromobutane with

NH₃ is to be stated.

Concept introduction:

In S_N2 reaction the nucleophile plays a major role in the product formation. If a nucleophile is negatively charged then the product will be neutral. If a nucleophile is neutral then it results in the positively charge product.

Answer 13

Interpretation Introduction

d)

Interpretation:

The product formed during the S_N2 reaction of 1-bromobutane with

NH₃ is to be stated.

Concept introduction:

In S_N2 reaction the nucleophile plays a major role in the product formation. If a nucleophile is negatively charged then the product will be neutral. If a nucleophile is neutral then it results in the positively charge product.

Answer 14

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Answer 25

Ch. 11.1 - Prob. 1P Ch. 11.2 - Prob. 2P Ch. 11.2 - Prob. 3P Ch. 11.3 - Prob. 4P Ch. 11.3 - Prob. 5P Ch. 11.3 - Rank the following compounds in order of their...Ch. 11.3 - Organic solvents like benzene, ether, and...Ch. 11.4 - Prob. 8P Ch. 11.4 - Prob. 9P Ch. 11.4 - Prob. 10P

Solution Summary: The author describes the product formed during the S N 2 reaction of 1-bromobutane with NaI.

Chapter 11 Solutions