ORGANIC CHEMISTRY-PRINT (LL)-W/WILEY
ORGANIC CHEMISTRY-PRINT (LL)-W/WILEY
4th Edition
ISBN: 9781119761105
Author: Klein
Publisher: WILEY
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Chapter 1.12, Problem 29ATS
Interpretation Introduction

Interpretation: Whether diphenyl ether exhibits molecular dipole moment or not should be identified and if it does then the direction of the net molecular dipole moment must be indicated.

Concept Introduction: The arrangement of electron pairs is identified according to VSEPR (Valence Shell Electron Pair Repulsion) theory wherein all the electron pairs are aligned in such a way that they are at maximum distance from each other. The structure of every molecule in VSEPR is explained by considering the steric number (combination of lone pairs and σ -bonds involved in molecule).

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Q3- Rank the following molecule according to their increasing stability. Where 1 is the least stable and 4 is the most stable. CH3 C(CH3)3 CH(CH3)2 Q4- Rank the following molecule according to their increasing dipole moment. Where 1 is the lowest dipole moment and 4 is the largest dipole moment. CI Br F
Account for the fact that among the chlorinated derivatives of methane, chloro- methane has the largest dipole moment and tetrachloromethane has the smallest dipole moment. Molecular Formula Dipole Moment (debyes, D) Name CH,CI CH,CI, Chloromethane 1.87 Dichloromethane 1.60 Trichloromethane CHCI, 1.01 Tetrachloromethane CCI,
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