The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated. Concept introduction: The sulphuric acid catalyzed dehydration reaction is used to convert alcohols into respective alkenes . The reaction of an alkene with m -CPBA followed by hydrolysis leads to the formation of diol with inversion of configuration.

Question

Want to see the full answer?

Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 11.14, Problem 11.38P

(a)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The sulphuric acid catalyzed dehydration reaction is used to convert alcohols into respective alkenes. The reaction of an alkene with m-CPBA followed by hydrolysis leads to the formation of diol with inversion of configuration.

(b)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The reaction of secondary alcohols with PCC leads to the formation of ketone. The Wittig reaction of ketone through phosphorous ylides leads to the addition of double bond (alkene). The reaction of an alkene with halogen acids leads to the addition of halogen group.

(c)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The reaction of secondary alcohols with PCC leads to the formation of ketone. The Wittig reaction of ketone through phosphorous ylides leads to the addition of double bond (alkene). The reaction of an alkene with m-CPBA in the presence of DCM leads to the formation of epoxide.

(d)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The reaction of secondary alcohols with PCC leads to the formation of ketone.

The conversion of an alcohol into an alkyl bromide is done by PBr3. The formation of Grignard reagent is done by reaction of an alkyl halide with Mg/THF.

The reaction of Grignard reagent with ketone yields an alcohol. The reaction of an alcohol with TsCl/Pyridine leads to the addition of tosyl group (tosylate ester). The reaction of tosylate ester with sodium methoxide yields ether.

(e)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The conversion of an alcohol into an alkyl bromide is done by PBr3. The conversion of bromine into cyano group is done by NaCN or CuCN/Pyridine. The hydrolysis (acidic or basic of) cyano group leads to the formation of carboxylic acid. The conversion of carboxylic acid into acyl chloride is done by SOCl2 or PCl3. The reduction of acyl chloride into R-CH2-OH is done by LiAlH4/ether followed by hydrolysis. The reaction of primary alcohols with PCC leads to the formation of an aldehyde. The reaction of Grignard reagent with an aldehyde yields an alcohol.

The reaction of an alcohol with TsCl/Pyridine leads to the addition of tosyl group (tosylate ester). The reaction of tosylate ester with sodium ethoxide yields ether.

(f)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The reaction of secondary alcohols with PCC leads to the formation of ketone. The conversion of an alcohol into an alkyl iodide is done by HI. The conversion of alkyl halide into alkyl nitrile is done by KCN. The conversion of bromine into cyano group is done by KCN. The hydrolysis (acidic or basic ) of cyano group leads to the formation of carboxylic acid. The conversion of carboxylic acid into acyl chloride is done by SOCl2 or PCl3. The reduction of acyl chloride into R-CH2-OH is done by LiAlH4/ether followed by hydrolysis. The reaction of primary alcohols with PCC leads to the formation of an aldehyde. The reaction of Grignard reagent with an aldehyde yields an alcohol. The conversion of an alcohol into an alkyl bromide is done by PBr3. The reaction of an alcohol with TsCl/Pyridine leads to the addition of tosyl group (tosylate ester). The reaction of tosylate ester with sodium methoxide yields ether.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

In the spectroscopic technique known as photoelectron spectroscopy (PES), ultraviolet radiation is directed at an atom or molecule. Electrons are ejected from the valence shell and their kinetic energies are measured. Since the energy of the incident ultraviolet photons is known and the kinetic energy of the ejected electron is measured, the ionization energy, I, can be deduced because total energy is conserved. (a) Show that the velocity, v, of the ejected electron and the frequency, n, of the incident radiation are related by hv = I + (1/2)mv^2? (b) Use this relation to calculate the ionization energy of a rubidium atom, knowing that light of wavelength 58.4 nm produces electrons with a velocity of 2,450 km/s Recall that 1 J = 1 kg.m^2/s^2

I) In Millikan's experiment, each droplet observed by the technicians contained an even number of electrons. If they had been unaware of this limitation, how would it have affected their report of an electron's charge?II) Millikan measured the charge of an electron in electrostatic units, esu. The data he collected included the following series of charges found on oil drops: 9.60 X 10^-10 esu, 1.92 X 10^-9 esu; 2.40 X 10^-9 esu; 2.88 X 10^-9 esu; and 4.80 X 10^-9 esu. (a) From this series, find the probable charge of the electron in electrostatic units. (b) Estimate the number of electrons in an oil drop with a charge of 6.72 X 10^-9 esu. The actual charge (in Coulombs) of an electron is 1.602 X 10^-19 C. What is the relationship between esu and Coulombs?

my ccc edu - Search X Quick Access X D2L Homepage - Spring 2025 x N Netflix X Dimensional Analysis - A x+ pp.aktiv.com Q ☆ X Question 59 of 70 The volume of 1 unit of plasma is 200.0 mL If the recommended dosage for adult patients is 10.0 mL per kg of body mass, how many units are needed for a patient with a body mass of 80.0 kg ? 80.0 kg 10.0 DAL 1 units X X 4.00 units 1 1 Jeg 200.0 DAL L 1 units X 200.0 mL = 4.00 units ADD FACTOR *( ) DELETE ANSWER RESET D 200.0 2.00 1.60 × 10³ 80.0 4.00 0.0400 0.250 10.0 8.00 & mL mL/kg kg units/mL L unit Q Search delete prt sc 111 110 19

Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 11.14, Problem 11.38P

(a)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The sulphuric acid catalyzed dehydration reaction is used to convert alcohols into respective alkenes. The reaction of an alkene with m-CPBA followed by hydrolysis leads to the formation of diol with inversion of configuration.

(b)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The reaction of secondary alcohols with PCC leads to the formation of ketone. The Wittig reaction of ketone through phosphorous ylides leads to the addition of double bond (alkene). The reaction of an alkene with halogen acids leads to the addition of halogen group.

(c)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The reaction of secondary alcohols with PCC leads to the formation of ketone. The Wittig reaction of ketone through phosphorous ylides leads to the addition of double bond (alkene). The reaction of an alkene with m-CPBA in the presence of DCM leads to the formation of epoxide.

(d)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The reaction of secondary alcohols with PCC leads to the formation of ketone.

The conversion of an alcohol into an alkyl bromide is done by PBr3. The formation of Grignard reagent is done by reaction of an alkyl halide with Mg/THF.

The reaction of Grignard reagent with ketone yields an alcohol. The reaction of an alcohol with TsCl/Pyridine leads to the addition of tosyl group (tosylate ester). The reaction of tosylate ester with sodium methoxide yields ether.

(e)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The conversion of an alcohol into an alkyl bromide is done by PBr3. The conversion of bromine into cyano group is done by NaCN or CuCN/Pyridine. The hydrolysis (acidic or basic of) cyano group leads to the formation of carboxylic acid. The conversion of carboxylic acid into acyl chloride is done by SOCl2 or PCl3. The reduction of acyl chloride into R-CH2-OH is done by LiAlH4/ether followed by hydrolysis. The reaction of primary alcohols with PCC leads to the formation of an aldehyde. The reaction of Grignard reagent with an aldehyde yields an alcohol.

The reaction of an alcohol with TsCl/Pyridine leads to the addition of tosyl group (tosylate ester). The reaction of tosylate ester with sodium ethoxide yields ether.

(f)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The reaction of secondary alcohols with PCC leads to the formation of ketone. The conversion of an alcohol into an alkyl iodide is done by HI. The conversion of alkyl halide into alkyl nitrile is done by KCN. The conversion of bromine into cyano group is done by KCN. The hydrolysis (acidic or basic ) of cyano group leads to the formation of carboxylic acid. The conversion of carboxylic acid into acyl chloride is done by SOCl2 or PCl3. The reduction of acyl chloride into R-CH2-OH is done by LiAlH4/ether followed by hydrolysis. The reaction of primary alcohols with PCC leads to the formation of an aldehyde. The reaction of Grignard reagent with an aldehyde yields an alcohol. The conversion of an alcohol into an alkyl bromide is done by PBr3. The reaction of an alcohol with TsCl/Pyridine leads to the addition of tosyl group (tosylate ester). The reaction of tosylate ester with sodium methoxide yields ether.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 11.14, Problem 11.38P

(a)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The sulphuric acid catalyzed dehydration reaction is used to convert alcohols into respective alkenes. The reaction of an alkene with m-CPBA followed by hydrolysis leads to the formation of diol with inversion of configuration.

(b)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The reaction of secondary alcohols with PCC leads to the formation of ketone. The Wittig reaction of ketone through phosphorous ylides leads to the addition of double bond (alkene). The reaction of an alkene with halogen acids leads to the addition of halogen group.

(c)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The reaction of secondary alcohols with PCC leads to the formation of ketone. The Wittig reaction of ketone through phosphorous ylides leads to the addition of double bond (alkene). The reaction of an alkene with m-CPBA in the presence of DCM leads to the formation of epoxide.

(d)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The reaction of secondary alcohols with PCC leads to the formation of ketone.

The conversion of an alcohol into an alkyl bromide is done by PBr3. The formation of Grignard reagent is done by reaction of an alkyl halide with Mg/THF.

The reaction of Grignard reagent with ketone yields an alcohol. The reaction of an alcohol with TsCl/Pyridine leads to the addition of tosyl group (tosylate ester). The reaction of tosylate ester with sodium methoxide yields ether.

(e)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The conversion of an alcohol into an alkyl bromide is done by PBr3. The conversion of bromine into cyano group is done by NaCN or CuCN/Pyridine. The hydrolysis (acidic or basic of) cyano group leads to the formation of carboxylic acid. The conversion of carboxylic acid into acyl chloride is done by SOCl2 or PCl3. The reduction of acyl chloride into R-CH2-OH is done by LiAlH4/ether followed by hydrolysis. The reaction of primary alcohols with PCC leads to the formation of an aldehyde. The reaction of Grignard reagent with an aldehyde yields an alcohol.

The reaction of an alcohol with TsCl/Pyridine leads to the addition of tosyl group (tosylate ester). The reaction of tosylate ester with sodium ethoxide yields ether.

(f)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The reaction of secondary alcohols with PCC leads to the formation of ketone. The conversion of an alcohol into an alkyl iodide is done by HI. The conversion of alkyl halide into alkyl nitrile is done by KCN. The conversion of bromine into cyano group is done by KCN. The hydrolysis (acidic or basic ) of cyano group leads to the formation of carboxylic acid. The conversion of carboxylic acid into acyl chloride is done by SOCl2 or PCl3. The reduction of acyl chloride into R-CH2-OH is done by LiAlH4/ether followed by hydrolysis. The reaction of primary alcohols with PCC leads to the formation of an aldehyde. The reaction of Grignard reagent with an aldehyde yields an alcohol. The conversion of an alcohol into an alkyl bromide is done by PBr3. The reaction of an alcohol with TsCl/Pyridine leads to the addition of tosyl group (tosylate ester). The reaction of tosylate ester with sodium methoxide yields ether.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 11.14, Problem 11.38P

(a)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The sulphuric acid catalyzed dehydration reaction is used to convert alcohols into respective alkenes. The reaction of an alkene with m-CPBA followed by hydrolysis leads to the formation of diol with inversion of configuration.

(b)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The reaction of secondary alcohols with PCC leads to the formation of ketone. The Wittig reaction of ketone through phosphorous ylides leads to the addition of double bond (alkene). The reaction of an alkene with halogen acids leads to the addition of halogen group.

(c)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The reaction of secondary alcohols with PCC leads to the formation of ketone. The Wittig reaction of ketone through phosphorous ylides leads to the addition of double bond (alkene). The reaction of an alkene with m-CPBA in the presence of DCM leads to the formation of epoxide.

(d)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The reaction of secondary alcohols with PCC leads to the formation of ketone.

The conversion of an alcohol into an alkyl bromide is done by PBr3. The formation of Grignard reagent is done by reaction of an alkyl halide with Mg/THF.

The reaction of Grignard reagent with ketone yields an alcohol. The reaction of an alcohol with TsCl/Pyridine leads to the addition of tosyl group (tosylate ester). The reaction of tosylate ester with sodium methoxide yields ether.

(e)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The conversion of an alcohol into an alkyl bromide is done by PBr3. The conversion of bromine into cyano group is done by NaCN or CuCN/Pyridine. The hydrolysis (acidic or basic of) cyano group leads to the formation of carboxylic acid. The conversion of carboxylic acid into acyl chloride is done by SOCl2 or PCl3. The reduction of acyl chloride into R-CH2-OH is done by LiAlH4/ether followed by hydrolysis. The reaction of primary alcohols with PCC leads to the formation of an aldehyde. The reaction of Grignard reagent with an aldehyde yields an alcohol.

The reaction of an alcohol with TsCl/Pyridine leads to the addition of tosyl group (tosylate ester). The reaction of tosylate ester with sodium ethoxide yields ether.

(f)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The reaction of secondary alcohols with PCC leads to the formation of ketone. The conversion of an alcohol into an alkyl iodide is done by HI. The conversion of alkyl halide into alkyl nitrile is done by KCN. The conversion of bromine into cyano group is done by KCN. The hydrolysis (acidic or basic ) of cyano group leads to the formation of carboxylic acid. The conversion of carboxylic acid into acyl chloride is done by SOCl2 or PCl3. The reduction of acyl chloride into R-CH2-OH is done by LiAlH4/ether followed by hydrolysis. The reaction of primary alcohols with PCC leads to the formation of an aldehyde. The reaction of Grignard reagent with an aldehyde yields an alcohol. The conversion of an alcohol into an alkyl bromide is done by PBr3. The reaction of an alcohol with TsCl/Pyridine leads to the addition of tosyl group (tosylate ester). The reaction of tosylate ester with sodium methoxide yields ether.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 11.14, Problem 11.38P

(a)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The sulphuric acid catalyzed dehydration reaction is used to convert alcohols into respective alkenes. The reaction of an alkene with m-CPBA followed by hydrolysis leads to the formation of diol with inversion of configuration.

(b)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The reaction of secondary alcohols with PCC leads to the formation of ketone. The Wittig reaction of ketone through phosphorous ylides leads to the addition of double bond (alkene). The reaction of an alkene with halogen acids leads to the addition of halogen group.

(c)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The reaction of secondary alcohols with PCC leads to the formation of ketone. The Wittig reaction of ketone through phosphorous ylides leads to the addition of double bond (alkene). The reaction of an alkene with m-CPBA in the presence of DCM leads to the formation of epoxide.

(d)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The reaction of secondary alcohols with PCC leads to the formation of ketone.

The conversion of an alcohol into an alkyl bromide is done by PBr3. The formation of Grignard reagent is done by reaction of an alkyl halide with Mg/THF.

The reaction of Grignard reagent with ketone yields an alcohol. The reaction of an alcohol with TsCl/Pyridine leads to the addition of tosyl group (tosylate ester). The reaction of tosylate ester with sodium methoxide yields ether.

(e)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The conversion of an alcohol into an alkyl bromide is done by PBr3. The conversion of bromine into cyano group is done by NaCN or CuCN/Pyridine. The hydrolysis (acidic or basic of) cyano group leads to the formation of carboxylic acid. The conversion of carboxylic acid into acyl chloride is done by SOCl2 or PCl3. The reduction of acyl chloride into R-CH2-OH is done by LiAlH4/ether followed by hydrolysis. The reaction of primary alcohols with PCC leads to the formation of an aldehyde. The reaction of Grignard reagent with an aldehyde yields an alcohol.

The reaction of an alcohol with TsCl/Pyridine leads to the addition of tosyl group (tosylate ester). The reaction of tosylate ester with sodium ethoxide yields ether.

(f)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The reaction of secondary alcohols with PCC leads to the formation of ketone. The conversion of an alcohol into an alkyl iodide is done by HI. The conversion of alkyl halide into alkyl nitrile is done by KCN. The conversion of bromine into cyano group is done by KCN. The hydrolysis (acidic or basic ) of cyano group leads to the formation of carboxylic acid. The conversion of carboxylic acid into acyl chloride is done by SOCl2 or PCl3. The reduction of acyl chloride into R-CH2-OH is done by LiAlH4/ether followed by hydrolysis. The reaction of primary alcohols with PCC leads to the formation of an aldehyde. The reaction of Grignard reagent with an aldehyde yields an alcohol. The conversion of an alcohol into an alkyl bromide is done by PBr3. The reaction of an alcohol with TsCl/Pyridine leads to the addition of tosyl group (tosylate ester). The reaction of tosylate ester with sodium methoxide yields ether.

Answer 6

Chapter 11.14, Problem 11.38P

(a)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The sulphuric acid catalyzed dehydration reaction is used to convert alcohols into respective alkenes. The reaction of an alkene with m-CPBA followed by hydrolysis leads to the formation of diol with inversion of configuration.

Answer 7

Chapter 11.14, Problem 11.38P

(a)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The sulphuric acid catalyzed dehydration reaction is used to convert alcohols into respective alkenes. The reaction of an alkene with m-CPBA followed by hydrolysis leads to the formation of diol with inversion of configuration.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The reaction of secondary alcohols with PCC leads to the formation of ketone. The Wittig reaction of ketone through phosphorous ylides leads to the addition of double bond (alkene). The reaction of an alkene with halogen acids leads to the addition of halogen group.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The reaction of secondary alcohols with PCC leads to the formation of ketone. The Wittig reaction of ketone through phosphorous ylides leads to the addition of double bond (alkene). The reaction of an alkene with halogen acids leads to the addition of halogen group.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The reaction of secondary alcohols with PCC leads to the formation of ketone. The Wittig reaction of ketone through phosphorous ylides leads to the addition of double bond (alkene). The reaction of an alkene with m-CPBA in the presence of DCM leads to the formation of epoxide.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The reaction of secondary alcohols with PCC leads to the formation of ketone. The Wittig reaction of ketone through phosphorous ylides leads to the addition of double bond (alkene). The reaction of an alkene with m-CPBA in the presence of DCM leads to the formation of epoxide.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The reaction of secondary alcohols with PCC leads to the formation of ketone.

The conversion of an alcohol into an alkyl bromide is done by PBr3. The formation of Grignard reagent is done by reaction of an alkyl halide with Mg/THF.

The reaction of Grignard reagent with ketone yields an alcohol. The reaction of an alcohol with TsCl/Pyridine leads to the addition of tosyl group (tosylate ester). The reaction of tosylate ester with sodium methoxide yields ether.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The reaction of secondary alcohols with PCC leads to the formation of ketone.

The conversion of an alcohol into an alkyl bromide is done by PBr3. The formation of Grignard reagent is done by reaction of an alkyl halide with Mg/THF.

The reaction of Grignard reagent with ketone yields an alcohol. The reaction of an alcohol with TsCl/Pyridine leads to the addition of tosyl group (tosylate ester). The reaction of tosylate ester with sodium methoxide yields ether.

Answer 14

(e)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The conversion of an alcohol into an alkyl bromide is done by PBr3. The conversion of bromine into cyano group is done by NaCN or CuCN/Pyridine. The hydrolysis (acidic or basic of) cyano group leads to the formation of carboxylic acid. The conversion of carboxylic acid into acyl chloride is done by SOCl2 or PCl3. The reduction of acyl chloride into R-CH2-OH is done by LiAlH4/ether followed by hydrolysis. The reaction of primary alcohols with PCC leads to the formation of an aldehyde. The reaction of Grignard reagent with an aldehyde yields an alcohol.

The reaction of an alcohol with TsCl/Pyridine leads to the addition of tosyl group (tosylate ester). The reaction of tosylate ester with sodium ethoxide yields ether.

Answer 15

(e)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The conversion of an alcohol into an alkyl bromide is done by PBr3. The conversion of bromine into cyano group is done by NaCN or CuCN/Pyridine. The hydrolysis (acidic or basic of) cyano group leads to the formation of carboxylic acid. The conversion of carboxylic acid into acyl chloride is done by SOCl2 or PCl3. The reduction of acyl chloride into R-CH2-OH is done by LiAlH4/ether followed by hydrolysis. The reaction of primary alcohols with PCC leads to the formation of an aldehyde. The reaction of Grignard reagent with an aldehyde yields an alcohol.

The reaction of an alcohol with TsCl/Pyridine leads to the addition of tosyl group (tosylate ester). The reaction of tosylate ester with sodium ethoxide yields ether.

Answer 16

(f)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The reaction of secondary alcohols with PCC leads to the formation of ketone. The conversion of an alcohol into an alkyl iodide is done by HI. The conversion of alkyl halide into alkyl nitrile is done by KCN. The conversion of bromine into cyano group is done by KCN. The hydrolysis (acidic or basic ) of cyano group leads to the formation of carboxylic acid. The conversion of carboxylic acid into acyl chloride is done by SOCl2 or PCl3. The reduction of acyl chloride into R-CH2-OH is done by LiAlH4/ether followed by hydrolysis. The reaction of primary alcohols with PCC leads to the formation of an aldehyde. The reaction of Grignard reagent with an aldehyde yields an alcohol. The conversion of an alcohol into an alkyl bromide is done by PBr3. The reaction of an alcohol with TsCl/Pyridine leads to the addition of tosyl group (tosylate ester). The reaction of tosylate ester with sodium methoxide yields ether.

Answer 17

(f)

Interpretation Introduction

Interpretation:

The synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents is to be stated.

Concept introduction:

The reaction of secondary alcohols with PCC leads to the formation of ketone. The conversion of an alcohol into an alkyl iodide is done by HI. The conversion of alkyl halide into alkyl nitrile is done by KCN. The conversion of bromine into cyano group is done by KCN. The hydrolysis (acidic or basic ) of cyano group leads to the formation of carboxylic acid. The conversion of carboxylic acid into acyl chloride is done by SOCl2 or PCl3. The reduction of acyl chloride into R-CH2-OH is done by LiAlH4/ether followed by hydrolysis. The reaction of primary alcohols with PCC leads to the formation of an aldehyde. The reaction of Grignard reagent with an aldehyde yields an alcohol. The conversion of an alcohol into an alkyl bromide is done by PBr3. The reaction of an alcohol with TsCl/Pyridine leads to the addition of tosyl group (tosylate ester). The reaction of tosylate ester with sodium methoxide yields ether.

Answer 18

Expert Solution & Answer

Answer 19

Expert Solution & Answer

Answer 20

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 21

Ch. 11.1 - Prob. 11.1P Ch. 11.2C - Prob. 11.2P Ch. 11.3 - Prob. 11.3P Ch. 11.3 - Prob. 11.4P Ch. 11.3 - Prob. 11.5P Ch. 11.3 - Suggest the most appropriate method for each of...Ch. 11.4 - A chronic alcoholic requires a much larger dose of...Ch. 11.4 - Unlike ethylene glycol, propylene glycol...Ch. 11.5 - Predict the major products of the following...Ch. 11.5 - Show how you would convert propan-1-ol to the...

Solution Summary: The author explains the synthesis of given compound with the use of cyclopentanol, alcohols that have no more than four carbon atoms as starting materials and any common reagents and solvents.

Want to see the full answer?

Chapter 11 Solutions