![Organic Chemistry](https://www.bartleby.com/isbn_cover_images/9781119316152/9781119316152_largeCoverImage.jpg)
(a)
Interpretation: For the given set of compounds, the net molecular dipole moment has to be indicated.
Concept Introduction: Dipole moment is the measure of net molecular polarity. Dipole moment can be determined experimentally and its value can give an idea of the polar character of a molecule. It is a vector quantity as it has a direction as well as magnitude.
The direction of dipole moment is usually represented by an arrow pointing from positive end towards the negative end. The sum of all vectors in a compound is called the molecular dipole moment. It can be given by considering both magnitude and the direction of each individual dipole moment involved in that compound.
If dipole moments of the individual bonds are equal in magnitude but in opposite direction, there is no net molecular dipole moment. If dipole moments of the individual bonds aren’t in opposite direction, there is a net molecular dipole moment.
According to VSEPR (Valence Shell Electron Pair Repulsion) theory, each molecule gets a unique structure. That structure is explained by considering steric number of that molecule. The steric number is the combination of both number of σ-bonds and number of lone pairs involved in a particular molecule.
σ-bonds are formed by the mutual sharing of electrons between the two atoms. As a result, bond between two atoms is formed. This type of bond is called covalent bond. In this process, bonding electron pairs are involved. Non-bonding electrons are not involved in the bond formation. They are called lone pairs.
The geometry of the central atom will be determined by counting the steric number followed by the hybridization state of that central atom and finally electronic arrangement of atoms in space.
If the steric number is 4, the central atom has sp3 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be tetrahedral. If the steric number is 3, the central atom has sp2 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be trigonal planar. If the steric number is 2, the central atom has sp hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be linear.
To find: Indicate the direction of the net molecular dipole moment for the compound CHCl3
(b)
Interpretation: For the given set of compounds, the net molecular dipole moment has to be indicated.
Concept Introduction: Dipole moment is the measure of net molecular polarity. Dipole moment can be determined experimentally and its value can give an idea of the polar character of a molecule. It is a vector quantity as it has a direction as well as magnitude.
The direction of dipole moment is usually represented by an arrow pointing from positive end towards the negative end. The sum of all vectors in a compound is called the molecular dipole moment. It can be given by considering both magnitude and the direction of each individual dipole moment involved in that compound.
If dipole moments of the individual bonds are equal in magnitude but in opposite direction, there is no net molecular dipole moment. If dipole moments of the individual bonds aren’t in opposite direction, there is a net molecular dipole moment.
According to VSEPR (Valence Shell Electron Pair Repulsion) theory, each molecule gets a unique structure. That structure is explained by considering steric number of that molecule. The steric number is the combination of both number of σ-bonds and number of lone pairs involved in a particular molecule.
σ-bonds are formed by the mutual sharing of electrons between the two atoms. As a result, bond between two atoms is formed. This type of bond is called covalent bond. In this process, bonding electron pairs are involved. Non-bonding electrons are not involved in the bond formation. They are called lone pairs.
The geometry of the central atom will be determined by counting the steric number followed by the hybridization state of that central atom and finally electronic arrangement of atoms in space.
If the steric number is 4, the central atom has sp3 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be tetrahedral. If the steric number is 3, the central atom has sp2 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be trigonal planar. If the steric number is 2, the central atom has sp hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be linear.
To find: Indicate the direction of the net molecular dipole moment for the compound (b)
(c)
Interpretation: For the given set of compounds, the net molecular dipole moment has to be indicated.
Concept Introduction: Dipole moment is the measure of net molecular polarity. Dipole moment can be determined experimentally and its value can give an idea of the polar character of a molecule. It is a vector quantity as it has a direction as well as magnitude.
The direction of dipole moment is usually represented by an arrow pointing from positive end towards the negative end. The sum of all vectors in a compound is called the molecular dipole moment. It can be given by considering both magnitude and the direction of each individual dipole moment involved in that compound.
If dipole moments of the individual bonds are equal in magnitude but in opposite direction, there is no net molecular dipole moment. If dipole moments of the individual bonds aren’t in opposite direction, there is a net molecular dipole moment.
According to VSEPR (Valence Shell Electron Pair Repulsion) theory, each molecule gets a unique structure. That structure is explained by considering steric number of that molecule. The steric number is the combination of both number of σ-bonds and number of lone pairs involved in a particular molecule.
σ-bonds are formed by the mutual sharing of electrons between the two atoms. As a result, bond between two atoms is formed. This type of bond is called covalent bond. In this process, bonding electron pairs are involved. Non-bonding electrons are not involved in the bond formation. They are called lone pairs.
The geometry of the central atom will be determined by counting the steric number followed by the hybridization state of that central atom and finally electronic arrangement of atoms in space.
If the steric number is 4, the central atom has sp3 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be tetrahedral. If the steric number is 3, the central atom has sp2 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be trigonal planar. If the steric number is 2, the central atom has sp hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be linear.
To find: Indicate the direction of the net molecular dipole moment for the compound (c)
(d)
Interpretation: For the given set of compounds, the net molecular dipole moment has to be indicated.
Concept Introduction: Dipole moment is the measure of net molecular polarity. Dipole moment can be determined experimentally and its value can give an idea of the polar character of a molecule. It is a vector quantity as it has a direction as well as magnitude.
The direction of dipole moment is usually represented by an arrow pointing from positive end towards the negative end. The sum of all vectors in a compound is called the molecular dipole moment. It can be given by considering both magnitude and the direction of each individual dipole moment involved in that compound.
If dipole moments of the individual bonds are equal in magnitude but in opposite direction, there is no net molecular dipole moment. If dipole moments of the individual bonds aren’t in opposite direction, there is a net molecular dipole moment.
According to VSEPR (Valence Shell Electron Pair Repulsion) theory, each molecule gets a unique structure. That structure is explained by considering steric number of that molecule. The steric number is the combination of both number of σ-bonds and number of lone pairs involved in a particular molecule.
σ-bonds are formed by the mutual sharing of electrons between the two atoms. As a result, bond between two atoms is formed. This type of bond is called covalent bond. In this process, bonding electron pairs are involved. Non-bonding electrons are not involved in the bond formation. They are called lone pairs.
The geometry of the central atom will be determined by counting the steric number followed by the hybridization state of that central atom and finally electronic arrangement of atoms in space.
If the steric number is 4, the central atom has sp3 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be tetrahedral. If the steric number is 3, the central atom has sp2 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be trigonal planar. If the steric number is 2, the central atom has sp hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be linear.
To find: Indicate the direction of the net molecular dipole moment for the compound (d)
(e)
Interpretation: For the given set of compounds, the net molecular dipole moment has to be indicated.
Concept Introduction: Dipole moment is the measure of net molecular polarity. Dipole moment can be determined experimentally and its value can give an idea of the polar character of a molecule. It is a vector quantity as it has a direction as well as magnitude.
The direction of dipole moment is usually represented by an arrow pointing from positive end towards the negative end. The sum of all vectors in a compound is called the molecular dipole moment. It can be given by considering both magnitude and the direction of each individual dipole moment involved in that compound.
If dipole moments of the individual bonds are equal in magnitude but in opposite direction, there is no net molecular dipole moment. If dipole moments of the individual bonds aren’t in opposite direction, there is a net molecular dipole moment.
According to VSEPR (Valence Shell Electron Pair Repulsion) theory, each molecule gets a unique structure. That structure is explained by considering steric number of that molecule. The steric number is the combination of both number of σ-bonds and number of lone pairs involved in a particular molecule.
σ-bonds are formed by the mutual sharing of electrons between the two atoms. As a result, bond between two atoms is formed. This type of bond is called covalent bond. In this process, bonding electron pairs are involved. Non-bonding electrons are not involved in the bond formation. They are called lone pairs.
The geometry of the central atom will be determined by counting the steric number followed by the hybridization state of that central atom and finally electronic arrangement of atoms in space.
If the steric number is 4, the central atom has sp3 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be tetrahedral. If the steric number is 3, the central atom has sp2 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be trigonal planar. If the steric number is 2, the central atom has sp hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be linear.
To find: Indicate the direction of the net molecular dipole moment for the compound (e)
(f)
Interpretation: For the given set of compounds, the net molecular dipole moment has to be indicated.
Concept Introduction: Dipole moment is the measure of net molecular polarity. Dipole moment can be determined experimentally and its value can give an idea of the polar character of a molecule. It is a vector quantity as it has a direction as well as magnitude.
The direction of dipole moment is usually represented by an arrow pointing from positive end towards the negative end. The sum of all vectors in a compound is called the molecular dipole moment. It can be given by considering both magnitude and the direction of each individual dipole moment involved in that compound.
If dipole moments of the individual bonds are equal in magnitude but in opposite direction, there is no net molecular dipole moment. If dipole moments of the individual bonds aren’t in opposite direction, there is a net molecular dipole moment.
According to VSEPR (Valence Shell Electron Pair Repulsion) theory, each molecule gets a unique structure. That structure is explained by considering steric number of that molecule. The steric number is the combination of both number of σ-bonds and number of lone pairs involved in a particular molecule.
σ-bonds are formed by the mutual sharing of electrons between the two atoms. As a result, bond between two atoms is formed. This type of bond is called covalent bond. In this process, bonding electron pairs are involved. Non-bonding electrons are not involved in the bond formation. They are called lone pairs.
The geometry of the central atom will be determined by counting the steric number followed by the hybridization state of that central atom and finally electronic arrangement of atoms in space.
If the steric number is 4, the central atom has sp3 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be tetrahedral. If the steric number is 3, the central atom has sp2 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be trigonal planar. If the steric number is 2, the central atom has sp hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be linear.
To find: Indicate the direction of the net molecular dipole moment for the compound (f)
(g)
Interpretation: For the given set of compounds, the net molecular dipole moment has to be indicated.
Concept Introduction: Dipole moment is the measure of net molecular polarity. Dipole moment can be determined experimentally and its value can give an idea of the polar character of a molecule. It is a vector quantity as it has a direction as well as magnitude.
The direction of dipole moment is usually represented by an arrow pointing from positive end towards the negative end. The sum of all vectors in a compound is called the molecular dipole moment. It can be given by considering both magnitude and the direction of each individual dipole moment involved in that compound.
If dipole moments of the individual bonds are equal in magnitude but in opposite direction, there is no net molecular dipole moment. If dipole moments of the individual bonds aren’t in opposite direction, there is a net molecular dipole moment.
According to VSEPR (Valence Shell Electron Pair Repulsion) theory, each molecule gets a unique structure. That structure is explained by considering steric number of that molecule. The steric number is the combination of both number of σ-bonds and number of lone pairs involved in a particular molecule.
σ-bonds are formed by the mutual sharing of electrons between the two atoms. As a result, bond between two atoms is formed. This type of bond is called covalent bond. In this process, bonding electron pairs are involved. Non-bonding electrons are not involved in the bond formation. They are called lone pairs.
The geometry of the central atom will be determined by counting the steric number followed by the hybridization state of that central atom and finally electronic arrangement of atoms in space.
If the steric number is 4, the central atom has sp3 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be tetrahedral. If the steric number is 3, the central atom has sp2 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be trigonal planar. If the steric number is 2, the central atom has sp hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be linear.
To find: Indicate the direction of the net molecular dipole moment for the compound (g)
(h)
Interpretation: For the given set of compounds, the net molecular dipole moment has to be indicated.
Concept Introduction: Dipole moment is the measure of net molecular polarity. Dipole moment can be determined experimentally and its value can give an idea of the polar character of a molecule. It is a vector quantity as it has a direction as well as magnitude.
The direction of dipole moment is usually represented by an arrow pointing from positive end towards the negative end. The sum of all vectors in a compound is called the molecular dipole moment. It can be given by considering both magnitude and the direction of each individual dipole moment involved in that compound.
If dipole moments of the individual bonds are equal in magnitude but in opposite direction, there is no net molecular dipole moment. If dipole moments of the individual bonds aren’t in opposite direction, there is a net molecular dipole moment.
According to VSEPR (Valence Shell Electron Pair Repulsion) theory, each molecule gets a unique structure. That structure is explained by considering steric number of that molecule. The steric number is the combination of both number of σ-bonds and number of lone pairs involved in a particular molecule.
σ-bonds are formed by the mutual sharing of electrons between the two atoms. As a result, bond between two atoms is formed. This type of bond is called covalent bond. In this process, bonding electron pairs are involved. Non-bonding electrons are not involved in the bond formation. They are called lone pairs.
The geometry of the central atom will be determined by counting the steric number followed by the hybridization state of that central atom and finally electronic arrangement of atoms in space.
If the steric number is 4, the central atom has sp3 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be tetrahedral. If the steric number is 3, the central atom has sp2 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be trigonal planar. If the steric number is 2, the central atom has sp hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be linear.
To find: Indicate the direction of the net molecular dipole moment for the compound (h)
(i)
Interpretation: For the given set of compounds, the net molecular dipole moment has to be indicated.
Concept Introduction: Dipole moment is the measure of net molecular polarity. Dipole moment can be determined experimentally and its value can give an idea of the polar character of a molecule. It is a vector quantity as it has a direction as well as magnitude.
The direction of dipole moment is usually represented by an arrow pointing from positive end towards the negative end. The sum of all vectors in a compound is called the molecular dipole moment. It can be given by considering both magnitude and the direction of each individual dipole moment involved in that compound.
If dipole moments of the individual bonds are equal in magnitude but in opposite direction, there is no net molecular dipole moment. If dipole moments of the individual bonds aren’t in opposite direction, there is a net molecular dipole moment.
According to VSEPR (Valence Shell Electron Pair Repulsion) theory, each molecule gets a unique structure. That structure is explained by considering steric number of that molecule. The steric number is the combination of both number of σ-bonds and number of lone pairs involved in a particular molecule.
σ-bonds are formed by the mutual sharing of electrons between the two atoms. As a result, bond between two atoms is formed. This type of bond is called covalent bond. In this process, bonding electron pairs are involved. Non-bonding electrons are not involved in the bond formation. They are called lone pairs.
The geometry of the central atom will be determined by counting the steric number followed by the hybridization state of that central atom and finally electronic arrangement of atoms in space.
If the steric number is 4, the central atom has sp3 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be tetrahedral. If the steric number is 3, the central atom has sp2 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be trigonal planar. If the steric number is 2, the central atom has sp hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be linear.
To find: Indicate the direction of the net molecular dipole moment for the compound (i)
(j)
Interpretation: For the given set of compounds, the net molecular dipole moment has to be indicated.
Concept Introduction: Dipole moment is the measure of net molecular polarity. Dipole moment can be determined experimentally and its value can give an idea of the polar character of a molecule. It is a vector quantity as it has a direction as well as magnitude.
The direction of dipole moment is usually represented by an arrow pointing from positive end towards the negative end. The sum of all vectors in a compound is called the molecular dipole moment. It can be given by considering both magnitude and the direction of each individual dipole moment involved in that compound.
If dipole moments of the individual bonds are equal in magnitude but in opposite direction, there is no net molecular dipole moment. If dipole moments of the individual bonds aren’t in opposite direction, there is a net molecular dipole moment.
According to VSEPR (Valence Shell Electron Pair Repulsion) theory, each molecule gets a unique structure. That structure is explained by considering steric number of that molecule. The steric number is the combination of both number of σ-bonds and number of lone pairs involved in a particular molecule.
σ-bonds are formed by the mutual sharing of electrons between the two atoms. As a result, bond between two atoms is formed. This type of bond is called covalent bond. In this process, bonding electron pairs are involved. Non-bonding electrons are not involved in the bond formation. They are called lone pairs.
The geometry of the central atom will be determined by counting the steric number followed by the hybridization state of that central atom and finally electronic arrangement of atoms in space.
If the steric number is 4, the central atom has sp3 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be tetrahedral. If the steric number is 3, the central atom has sp2 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be trigonal planar. If the steric number is 2, the central atom has sp hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be linear.
To find: Indicate the direction of the net molecular dipole moment for the compound (j)
(k)
Interpretation: For the given set of compounds, the net molecular dipole moment has to be indicated.
Concept Introduction: Dipole moment is the measure of net molecular polarity. Dipole moment can be determined experimentally and its value can give an idea of the polar character of a molecule. It is a vector quantity as it has a direction as well as magnitude.
The direction of dipole moment is usually represented by an arrow pointing from positive end towards the negative end. The sum of all vectors in a compound is called the molecular dipole moment. It can be given by considering both magnitude and the direction of each individual dipole moment involved in that compound.
If dipole moments of the individual bonds are equal in magnitude but in opposite direction, there is no net molecular dipole moment. If dipole moments of the individual bonds aren’t in opposite direction, there is a net molecular dipole moment.
According to VSEPR (Valence Shell Electron Pair Repulsion) theory, each molecule gets a unique structure. That structure is explained by considering steric number of that molecule. The steric number is the combination of both number of σ-bonds and number of lone pairs involved in a particular molecule.
σ-bonds are formed by the mutual sharing of electrons between the two atoms. As a result, bond between two atoms is formed. This type of bond is called covalent bond. In this process, bonding electron pairs are involved. Non-bonding electrons are not involved in the bond formation. They are called lone pairs.
The geometry of the central atom will be determined by counting the steric number followed by the hybridization state of that central atom and finally electronic arrangement of atoms in space.
If the steric number is 4, the central atom has sp3 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be tetrahedral. If the steric number is 3, the central atom has sp2 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be trigonal planar. If the steric number is 2, the central atom has sp hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be linear.
To find: Indicate the direction of the net molecular dipole moment for the compound (k)
(l)
Interpretation: For the given set of compounds, the net molecular dipole moment has to be indicated.
Concept Introduction: Dipole moment is the measure of net molecular polarity. Dipole moment can be determined experimentally and its value can give an idea of the polar character of a molecule. It is a vector quantity as it has a direction as well as magnitude.
The direction of dipole moment is usually represented by an arrow pointing from positive end towards the negative end. The sum of all vectors in a compound is called the molecular dipole moment. It can be given by considering both magnitude and the direction of each individual dipole moment involved in that compound.
If dipole moments of the individual bonds are equal in magnitude but in opposite direction, there is no net molecular dipole moment. If dipole moments of the individual bonds aren’t in opposite direction, there is a net molecular dipole moment.
According to VSEPR (Valence Shell Electron Pair Repulsion) theory, each molecule gets a unique structure. That structure is explained by considering steric number of that molecule. The steric number is the combination of both number of σ-bonds and number of lone pairs involved in a particular molecule.
σ-bonds are formed by the mutual sharing of electrons between the two atoms. As a result, bond between two atoms is formed. This type of bond is called covalent bond. In this process, bonding electron pairs are involved. Non-bonding electrons are not involved in the bond formation. They are called lone pairs.
The geometry of the central atom will be determined by counting the steric number followed by the hybridization state of that central atom and finally electronic arrangement of atoms in space.
If the steric number is 4, the central atom has sp3 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be tetrahedral. If the steric number is 3, the central atom has sp2 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be trigonal planar. If the steric number is 2, the central atom has sp hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be linear.
To find: Indicate the direction of the net molecular dipole moment for the compound (l)
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Chapter 1 Solutions
Organic Chemistry
- Nonearrow_forwardIndicate which option is false(A). Resistivity has a residual component and a thermal component.(B). In some materials resistivity increases with T and in others it decreases.(C). In insulating materials, resistivity is very low.arrow_forwardIn ceramic materials, in relation to polymorphism, the same substance crystallizes differently when external conditions vary. Is this correct?arrow_forward
- Indicate the type of bond that is considered to be a hydrogen bond.(A). Permanent dipole-dipole interaction between polar molecules.(B). Mixed ionic-covalent bond.(C). Principal interatomic bond(D). Van del Waals forces.arrow_forwardRetro aldol: NaOH H₂O H NaOH & d H₂O Harrow_forwardDraw the product of the reaction shown below. Ignore inorganic byproducts. H conc. HBr Drawing Qarrow_forward
- Calculate the atomic packing factor of diamond knowing that the number of Si atoms per cm3 is 2.66·1022 and that the atomic radii of silicon and oxygen are, respectively, 0.038 and 0.117 nm.arrow_forwardA pdf file of your hand drawn, stepwise mechanisms for the reactions. For each reaction in the assignment, you must write each mechanism three times (there are 10 reactions, so 30 mechanisms). (A) do the work on a tablet and save as a pdf., it is expected to write each mechanism out and NOT copy and paste the mechanism after writing it just once. Everything should be drawn out stepwise and every bond that is formed and broken in the process of the reaction, and is expected to see all relevant lone pair electrons and curved arrows. Aldol: NaOH HO H Δ NaOH Δarrow_forwardNonearrow_forward
- Draw structures corresponding to the following names and give IUPAC names for the following compounds: (8 Point) a) b) c) CH3 CH2CH3 CH3CHCH2CH2CH CH3 C=C H3C H H2C=C=CHCH3 d) CI e) (3E,5Z)-2,6-Dimethyl-1,3,5,7-octatetraene f) (Z)-4-bromo-3-methyl-3-penten-1-yne g) cis-1-Bromo-2-ethylcyclopentane h) (5R)-4,4,5-trichloro-3,3-dimethyldecanearrow_forwardNonearrow_forwardReview: Design a total total synthesis synthesis of the following compound using methyloxacyclopropane and any other necessary reagents.arrow_forward
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